Copper‐Catalyzed Preparation of Alkenylboronates and Arylboronates

The amine-catalysed Suzuki–Miyaura-type coupling of aryl halides and arylboronic acids

(2021) Lei Xu et al.   Nature Catalysis

Photoinduced Borylation for the Synthesis of Organoboron Compounds

(2021) Ya-Ming Tian et al.   CHEMICAL REVIEWS

Synthesis and Reactivity of Allenylboron Compounds

(2021) Samir Manna et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper‐Photocatalyzed Hydroboration of Alkynes and Alkenes

(2021) Mingbing Zhong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper‐Catalyzed Synthesis of Tetrasubstituted Alkenes via Regio‐ and anti ‐Selective Addition of Silylboronates to Internal Alkynes

(2021) Hirokazu Moniwa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed 1,1-Boroalkylation of Terminal Alkynes: Access to Alkenylboronates via a Three-Component Reaction

(2021) Ziyong Li et al.   ORGANIC LETTERS

Dynamic multiligand catalysis: A polar to radical crossover strategy expands alkyne carboboration to unactivated secondary alkyl halides

(2021) Shin-Ho Kim-Lee et al.   Chem

Visible Light-Induced Borylation of C–O, C–N, and C–X Bonds

(2020) Shengfei Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transmetalation as Key Step in the Diastereo- and Enantioselective Synergistic Cu/Pd-Catalyzed Allylboration of Alkynes with Racemic Allylic Carbonates

(2020) Jaime Mateos et al.   ORGANOMETALLICS

Recent advances in Cu-catalyzed C(sp3)–Si and C(sp3)–B bond formation

(2020) Balaram S Takale et al.   Beilstein Journal of Organic Chemistry

Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates

(2020) Weichao Xue et al.   ACS Central Science

Visible-Light-Induced Ni-Catalyzed Radical Borylation of Chloroarenes

(2020) Ya-Ming Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper Photocatalyzed Borylation of Organic Halides under Batch and Continuous Flow Conditions

(2019) Antoine Nitelet et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carboboration of Alkynes with Cyclodextrin-Encapsulated N-Heterocyclic Carbene Copper Complexes

(2019) Zhonghang Wen et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Activation of Cis-Vicinal Diols by Boronic Acids: Site-Selective Acylation of Carbohydrates

(2019) Naoyuki Shimada et al.   ORGANIC LETTERS

trans ‐Hydroboration of Propargyl Alcohol Derivatives and Related Substrates

(2019) Lauren E. Longobardi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Dependent-Controlled Copper-Catalyzed Regio- and Stereoselective Silaboration of Alkynes

(2019) Meng Zhao et al.   ORGANIC LETTERS

Mild and Efficient Synthesis of Functionalized Carbazoles via a DBU‐Assisted Sequence Involving Cu‐ and Pd‐Catalyzed Coupling Reactions

(2019) Aminur Khan et al.   ChemistrySelect

2,2-Difluorovinyl Pinacolborane - A New Versatile Reagent for the Suzuki-Miyaura Reaction

(2019) Oleksandr P. Blahun et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Triboration of Terminal Alkynes Using B2 pin2 : Efficient Synthesis of 1,1,2-Triborylalkenes

(2019) Xiaocui Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Allylboration of Alkynes: Synthesis of Highly Versatile Multifunctional Building Blocks

(2019) Eva Rivera-Chao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal Free Synthesis of Heterobiaryls Through 1,2‐Migration of Boronate Complex

(2019) Santanu Panda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cross-Coupling of Aryl Trifluoromethyl Sulfones with Arylboronates by Cooperative Palladium/Rhodium Catalysis

(2019) Jun-ichi Fukuda et al.   ORGANIC LETTERS

Para-selective borylation of monosubstituted benzenes using a transient mediator

(2019) Jie Wu et al.   Science China-Chemistry

Transition-metal-free stereoselective borylation of allenamides

(2018) Elena Fernández et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Free Suzuki-Type Cross-Coupling Reaction of Benzyl Halides and Boronic Acids via 1,2-Metalate Shift

(2018) Zhiqi He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Synthesis of Tetrasubstituted Enynylboronates via Chemo-, Regio-, and Stereoselective Borylalkynylation

(2018) Jung Tae Han et al.   ORGANIC LETTERS

Synthesis of biologically active boron-containing compounds

(2018) Fei Yang et al.   MedChemComm

Ligandless Copper-Catalyzed Carboborylation of Heteroatom-Substituted Alkynes

(2018) Shiwen Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Bora-Acylation and Bora-Alkoxyoxalylation of Allenes

(2018) Ayumi Sawada et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-boryl mediated organic synthesis

(2018) David Hemming et al.   CHEMICAL SOCIETY REVIEWS

Copper(I)-catalyzed Stereoselective Defluoroborylation of Aliphatic Gem-Difluoroalkenes

(2018) Hajime Ito et al.   CHEMISTRY LETTERS

Copper(i)-catalysed stereoselective debromoborylation of aliphatic 1,1-dibromo-1-alkenes with bis(pinacolato)diboron

(2018) Yadong Pang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

2,6-Bis(trifluoromethyl)phenylboronic Esters as Protective Groups for Diols: A Protection/Deprotection Protocol for Use under Mild Conditions

(2018) Naoyuki Shimada et al.   ORGANIC LETTERS

Recent Advances in Copper-Catalyzed Asymmetric Hydroboration of Electron-Deficient Alkenes: Methodologies and Mechanism

(2018) Andrew Whiting et al.   SYNTHESIS-STUTTGART

Synergistic Bimetallic Catalysis for Carboboration of Unsaturated Hydrocarbons

(2018) Martín Fañanás-Mastral et al.   SYNTHESIS-STUTTGART

Recent development of boronic acid-based fluorescent sensors

(2018) Guiqian Fang et al.   RSC Advances

Alkenylboronates: synthesis and applications

(2018) Pedro J. Pérez et al.   Chemistry-An Asian Journal

Direct Synthesis of Alkenylboronates from Alkenes and Pinacol Diboron via Copper Catalysis

(2018) Wenkui Lu et al.   ORGANIC LETTERS

(CAAC)CuX-catalyzed hydroboration of terminal alkynes with pinacolborane directed by the X-ligand

(2017) Erik A. Romero et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes

(2017) Hironobu Sakaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The versatility of boron in biological target engagement

(2017) Diego B. Diaz et al.   Nature Chemistry

Formal nucleophilic borylation and borylative cyclization of organic halides

(2017) K. Kubota et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Vinyl-, Allyl-, and 2-Boryl Allylboronates via a Highly Selective Copper-Catalyzed Borylation of Propargylic Alcohols

(2017) Lujia Mao et al.   ORGANIC LETTERS

Cu-Catalyzed Stereoselective Borylation of gem-Difluoroalkenes with B2pin2

(2017) Juan Zhang et al.   ORGANIC LETTERS

Elusive Phosphine Copper(I) Boryl Complexes: Synthesis, Structures, and Reactivity

(2017) Corinna Borner et al.   ORGANOMETALLICS

Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides

(2017) Hiroto Yoshida et al.   ORGANOMETALLICS

Transition-Metal-Free Reactions Between Boronic Acids and N-Sulfonylhydrazones or Diazo Compounds: Reductive Coupling Processes and Beyond

(2017) Carlos Valdés et al.   SYNLETT

Recent advances in catalytic C−H borylation reactions

(2017) Liang Xu et al.   TETRAHEDRON

Isolation and characterization of hydrocarbon soluble NHC copper(I) phosphoranimide complex and catalytic application for alkyne hydroboration reaction

(2017) Tao Bai et al.   TETRAHEDRON LETTERS

Recent advances in the synthesis and CF functionalization of gem-difluoroalkenes

(2017) Xuxue Zhang et al.   TETRAHEDRON LETTERS

Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane

(2017) Erik A. Romero et al.   Chemical Science

Acyl Fluorides as Efficient Electrophiles for the Copper-Catalyzed Boroacylation of Allenes

(2017) Arnaud Boreux et al.   ACS Catalysis

Copper-Catalyzed ipso-Borylation of Fluoroarenes

(2017) Takashi Niwa et al.   ACS Catalysis

Stereoselective Synthesis of Trisubstituted Alkenes via Cobalt-Catalyzed Double Dehydrogenative Borylations of 1-Alkenes

(2017) Huanan Wen et al.   ACS Catalysis

Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)

(2017) Hiroto Yoshida et al.   Organic Chemistry Frontiers

Recent Developments in Organoboron Chemistry: Old Dogs, New Tricks

(2017) James W.B. Fyfe et al.   Chem

Copper-Catalyzed Stereoselective Defluorinative Borylation and Silylation of gem -Difluoroalkenes

(2017) Dong-Hang Tan et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Generation of Adjacent Stereocenters in a Copper-Catalyzed Three-Component Coupling of Imines, Allenes, and Diboranes

(2016) Kay Yeung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

(2016) Emily C. Neeve et al.   CHEMICAL REVIEWS

Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity

(2016) Abraham J. Jordan et al.   CHEMICAL REVIEWS

Iridium(I)-catalyzed C−H Borylation of α,β-Unsaturated Esters with Bis(pinacolato)diboron

(2016) Ikuo Sasaki et al.   Chemistry-An Asian Journal

Chemo-, Regio-, and Stereoselective Copper(II)-Catalyzed Boron Addition to Acetylenic Esters and Amides in Aqueous Media

(2016) Amanda K. Nelson et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Synthesis of Alkenyl Boronic Esters from Unfunctionalized Alkenes: A Boryl-Heck Reaction

(2016) William B. Reid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled, Copper-Catalyzed Regio- and Stereoselective Synthesis of Trialkylsubstituted Alkenylboronates from Unactivated Internal Alkynes

(2016) Taisuke Itoh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cascade Copper-Catalyzed 1,2,3-Trifunctionalization of Terminal Allenes

(2016) Wanxiang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts

(2016) Adelphe M. Mfuh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed ipso-Borylation of Aryl Sulfides with Diborons

(2016) M. Bhanuchandra et al.   ORGANIC LETTERS

Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C–S Bond Cleavage

(2016) Yuta Uetake et al.   ORGANIC LETTERS

Copper-Catalyzed trans-Hydroboration of Terminal Aryl Alkynes: Stereodivergent Synthesis of Alkenylboron Compounds

(2016) Won Jun Jang et al.   ORGANIC LETTERS

Copper-catalyzed regioselective hydroboration of terminal alkynes in aqueous medium

(2016) Zi-Jian Yao et al.   TETRAHEDRON LETTERS

Cu II -catalyzed regioselective borylation of alkynes and alkenes

(2016) Shiwen Liu et al.   TETRAHEDRON LETTERS

Efficient metal-free photochemical borylation of aryl halides under batch and continuous-flow conditions

(2016) Kai Chen et al.   Chemical Science

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Unactivated Terminal Alkynes

(2016) Wei Su et al.   ACS Catalysis

Dehydrogenative Borylation and Silylation of Styrenes Catalyzed by Copper-Carbenes

(2016) Thomas J. Mazzacano et al.   ACS Catalysis

Iron-Catalyzed E-Selective Dehydrogenative Borylation of Vinylarenes with Pinacolborane

(2016) Chao Wang et al.   ACS Catalysis

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Copper-catalyzed hydroboration of propargyl-functionalized alkynes in water

(2016) Jessie S. da Costa et al.   RSC Advances

Boronic Acid for the Traceless Delivery of Proteins into Cells

(2015) Kristen A. Andersen et al.   ACS Chemical Biology

Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine, and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates

(2015) Jian Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Ni(cod)2 ][Al(ORF )4 ], a Source for Naked Nickel(I) Chemistry

(2015) Miriam M. Schwab et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Borylative Cross-Coupling of Allenes and Imines: Selective Three-Component Assembly of Branched Homoallyl Amines

(2015) James Rae et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Relay and Cooperative Palladium(0)N-Heterocyclic Carbene/Copper(I)N-Heterocyclic Carbene Catalysis for the Synthesis of Tri- and Tetrasubstituted Alkenes

(2015) Mathieu Lesieur et al.   ChemCatChem

Direct introduction of a naphthalene-1,8-diamino boryl [B(dan)] group by a Pd-catalysed selective boryl transfer reaction

(2015) Liang Xu et al.   CHEMICAL COMMUNICATIONS

sp2–sp3 diboranes: astounding structural variability and mild sources of nucleophilic boron for organic synthesis

(2015) Rian D. Dewhurst et al.   CHEMICAL COMMUNICATIONS

Synthesis, Structure, and Reactivity of Anionic sp2-sp3Diboron Compounds: Readily Accessible Boryl Nucleophiles

(2015) Sabrina Pietsch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective synthesis of highly functionalized alkenylboronates by Cu-catalyzed borylation of propargylic silylalkynes

(2015) Yeong Eun Kim et al.   DALTON TRANSACTIONS

A Bicyclic N-Heterocyclic Carbene as a Bulky but Accessible Ligand: Application to the Copper-Catalyzed Borylations of Aryl Halides

(2015) Shin Ando et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed C–H Borylation of Arenes

(2015) Thomas Dombray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of Copper(I)-Catalyzed 1,3-Halogen Migration

(2015) Ryan Van Hoveln et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni/Cu-Catalyzed Defluoroborylation of Fluoroarenes for Diverse C–F Bond Functionalizations

(2015) Takashi Niwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Borylation of Aryl Fluorides via C–F Cleavage

(2015) Xiang-Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Rh-catalyzed C–H borylation of arene derivatives under photochemical conditions

(2015) Charles Beromeo Bheeter et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Regio- and Stereoselective Synthesis of Boron-Substituted Enynes via Copper-Catalyzed Borylation of Conjugated Diynes

(2015) DingXi Li et al.   ORGANIC LETTERS

Silicon-Tethered Strategy for Copper(I)-Catalyzed Stereo- and Regioselective Alkylboration of Alkynes

(2015) Koji Kubota et al.   ORGANIC LETTERS

Synthesis of Vinyl Boronates from Aldehydes by a Practical Boron–Wittig Reaction

(2015) John R. Coombs et al.   ORGANIC LETTERS

Development of N-Heterocyclic Carbene–Copper Complexes for 1,3-Halogen Migration

(2015) Steven C. Schmid et al.   ORGANOMETALLICS

Origin of Regioselectivity in the Copper-Catalyzed Borylation Reactions of Internal Aryl Alkynes with Bis(pinacolato)diboron

(2015) Jong Hun Moon et al.   ORGANOMETALLICS

Copper(II)-Catalyzed β-Borylation of Acetylenic Esters in Water

(2015) Webster Santos et al.   SYNTHESIS-STUTTGART

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

A Heterobimetallic Mechanism for C–H Borylation Elucidated from Experimental and Computational Data

(2015) Sean R. Parmelee et al.   ACS Catalysis

Site- and Regioselective Silaborative C–C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester

(2015) Toshimichi Ohmura et al.   ACS Catalysis

Substrate-Controlled Regio- and Stereoselective Synthesis of Boron-Substituted 1,4-Dienes via Copper-Catalyzed Boryl–Allylation of Alkynes with Allyl Phosphates and Bis(pinacolato)diboron

(2015) Huai-Yu Bin et al.   ACS Catalysis

Copper-Catalyzed β-Selective Hydroborylation of Ynamides: A Facile Access to (E)-β-Alkenylamide Boronates

(2015) Yihui Bai et al.   Asian Journal of Organic Chemistry

CuIIand Cu0Catalyzed Mono Borylation of Unsaturated Hydrocarbons with B2pin2: Entering into the Water

(2015) Gaj Stavber et al.   ChemCatChem

Copper-Catalyzed Monoborylation of Silylalkynes; Regio- and Stereoselective Synthesis of (Z)-β-(Borylvinyl)silanes

(2014) Yeong Mi Chae et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Borylative Allyl-Allyl Coupling Reaction

(2014) Kazuhiko Semba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Cross-Coupling of Boronic Esters with Aryl Iodides and Application to the Carboboration of Alkynes and Allenes

(2014) Yiqing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed RegioselectiveorthoCH Cyanation of Vinylarenes

(2014) Yang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a guanidine NHC complex and its application in borylation reactions

(2014) Chia-Cheng Tai et al.   CHEMICAL COMMUNICATIONS

A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons

(2014) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Functional group directed C–H borylation

(2014) A. Ros et al.   CHEMICAL SOCIETY REVIEWS

Convenient Synthesis of Arylboronates through a Synergistic Pd/Cu-Catalyzed Miyaura Borylation Reaction under Atmospheric Conditions

(2014) Jadsada Ratniyom et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Formation of Trisubstituted Vinyl Boronate Esters by the Acid-Mediated Elimination of α-Hydroxyboronate Esters

(2014) Weiye Guan et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of (Z)-1-Thio- and (Z)-2-Thio-1-alkenyl Boronates via Copper-Catalyzed Regiodivergent Hydroboration of Thioacetylenes: An Experimental and Theoretical Study

(2014) Gangguo Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Borylation of Propargylic Substrates by Bimetallic Catalysis. Synthesis of Allenyl, Propargylic, and Butadienyl Bpin Derivatives

(2014) Tony S. N. Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed C(sp2)–H Bond Functionalization with Organoboron Compounds

(2014) Rui Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional organoboron compounds for scalable natural product synthesis

(2014) Fanke Meng et al.   NATURE

Studies on copper(i)-catalyzed highly regio- and stereo-selective hydroboration of alkynamides

(2014) Guangke He et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Application of Cooperative Iron/Copper Catalysis to a Palladium-Free Borylation of Aryl Bromides with Pinacolborane

(2014) Flavien Labre et al.   ORGANIC LETTERS

Catalytic Enantioselective Protoboration of Disubstituted Allenes. Access to Alkenylboron Compounds in High Enantiomeric Purity

(2014) Hwanjong Jang et al.   ORGANIC LETTERS

Mechanistic Insight into the (NHC)copper(I)-Catalyzed Hydrosilylation of Ketones

(2014) Thomas Vergote et al.   ORGANOMETALLICS

Non-Precious Metal Catalysts for C–H Borylation Enabled by Metal–Metal Cooperativity

(2014) Neal Mankad   SYNLETT

Formal asymmetric hydrobromination of styrenes via copper-catalyzed 1,3-halogen migration

(2014) R. J. Van Hoveln et al.   Chemical Science

Copper-Catalyzed Regioselective Formation of Tri- and Tetrasubstituted Vinylboronates in Air

(2014) Yannick D. Bidal et al.   ACS Catalysis

Regioselective transformation of alkynes catalyzed by a copper hydride or boryl copper species

(2014) Tetsuaki Fujihara et al.   Catalysis Science & Technology

Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes

(2014) Hiroto Yoshida et al.   Asian Journal of Organic Chemistry

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atrans-Selective Hydroboration of Internal Alkynes

(2013) Basker Sundararaju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Borylation of α-Alkoxy Allenes with Bis(pinacolato)diboron: Efficient Synthesis of 2-Boryl 1,3-Butadienes

(2013) Kazuhiko Semba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium(i)-catalyzed vinylic C–H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

(2013) Ikuo Sasaki et al.   CHEMICAL COMMUNICATIONS

Ligand-free hydroboration of alkynes catalyzed by heterogeneous copper powder with high efficiency

(2013) Jie Zhao et al.   CHEMICAL COMMUNICATIONS

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Amide-Controlled Highly Selective Catalytic Borylcupration of Allenes

(2013) Weiming Yuan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper(I)-Catalyzed Highly Regio- and Stereoselective Boron Addition-Protonolysis of Alkynamides to give Alkenamides

(2013) Guangke He et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cu-Catalyzed Asymmetric Borylative Cyclization of Cyclohexadienone-Containing 1,6-Enynes

(2013) Ping Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design, Generation, and Synthetic Application of Borylzincate: Borylation of Aryl Halides and Borylzincation of Benzynes/Terminal Alkyne

(2013) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base Metal Catalysts for Photochemical C–H Borylation That Utilize Metal–Metal Cooperativity

(2013) Thomas J. Mazzacano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

In Situ Assembled Boronate Ester Assisted Chiral Carboxylic Acid Catalyzed Asymmetric Trans-Aziridinations

(2013) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal Regiocontrolled Hydroboration of Unbiased Internal Alkynes via Borylation/Allylic Alkylation of Terminal Alkynes

(2013) Abraham L. Moure et al.   ORGANIC LETTERS

Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes

(2013) Hiroto Yoshida et al.   ORGANIC LETTERS

NHC–Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism

(2013) Fanke Meng et al.   ORGANIC LETTERS

A decade advancement of transition metal-catalyzed borylation of aryl halides and sulfonates

(2013) Wing Kin Chow et al.   RSC Advances

Copper(I)-Catalyzed Boron Addition Reactions of Alkynes with Diboron Reagents

(2013) Jaesook Yun   Asian Journal of Organic Chemistry

Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron

(2012) Weiming Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Organoindium Reagents: The Preparation and Application in Organic Synthesis

(2012) Zhi-Liang Shen et al.   CHEMICAL REVIEWS

Copper-Catalyzed Highly Regio- and Stereoselective Directed Hydroboration of Unsymmetrical Internal Alkynes: Controlling Regioselectivity by Choice of Catalytic Species

(2012) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiocontrolled CuI-Catalyzed Borylation of Propargylic-Functionalized Internal Alkynes

(2012) Abraham L. Moure et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

(2012) Ricardo Alfaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Recycling of Halogen Activating Groups via 1,3-Halogen Migration

(2012) R. David Grigg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst

(2012) Liang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Catalyzed Hydroboration of Terminal Alkynes to Z-Vinylboronates

(2012) Chidambaram Gunanathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Free Copper-Catalyzed Borylation of Aryl and Benzyl Halides with Bis(pinacolato)diboron

(2012) Guobing Yan et al.   LETTERS IN ORGANIC CHEMISTRY

CuCl–K2CO3-catalyzed highly selective borylcupration of internal alkynes – ligand effect

(2012) Weiming Yuan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regioselective Catalytic Hydroboration of Propargylic Species Using Cu(I)-NHC Complexes

(2012) Jin Kyoon Park et al.   ORGANIC LETTERS

Unexpected Copper(II) Catalysis: Catalytic Amine Base Promoted β-Borylation of α,β-Unsaturated Carbonyl Compounds in Water

(2012) Steven B. Thorpe et al.   ORGANIC LETTERS

Sandmeyer-Type Reaction to Pinacol Arylboronates in Water Phase: A Green Borylation Process

(2012) Haitao Yu et al.   SYNLETT

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Borylation Reactions of Alkynes and Arynes

(2011) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes

(2011) Rosa Corberán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

(2011) Yusuke Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes

(2011) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Regioselectivity of the borylation of alkanes and arenes

(2011) John F. Hartwig   CHEMICAL SOCIETY REVIEWS

Highly Enantioselective Synthesis of Tertiary Boronic Esters and their Stereospecific Conversion to other Functional Groups and Quaternary Stereocentres

(2011) Helen K. Scott et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereoselective Single (Copper) or Double (Platinum) Boronation of Alkynes Catalyzed by Magnesia-Supported Copper Oxide or Platinum Nanoparticles

(2011) Abdessamad Grirrane et al.   CHEMISTRY-A EUROPEAN JOURNAL

First Evidence of the Oxidative Addition of Fe0(N,N)2 to Aryl Halides: This Precondition Is Not a Guarantee of Efficient Iron-Catalysed C-N Cross-Coupling Reactions

(2011) Guillaume Lefèvre et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Efficient Synthesis of Diborylalkenes from Alkenes and Diboron by a New PSiP-Pincer Palladium-Catalyzed Dehydrogenative Borylation

(2011) Jun Takaya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

SCYX-7158, an Orally-Active Benzoxaborole for the Treatment of Stage 2 Human African Trypanosomiasis

(2011) Robert T. Jacobs et al.   PLoS Neglected Tropical Diseases

Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile

(2010) Yuri Okuno et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes

(2010) Azusa Kondoh et al.   CHEMICAL COMMUNICATIONS

Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron

(2010) Steven B. Thorpe et al.   CHEMICAL COMMUNICATIONS

Boronic acid building blocks: tools for sensing and separation

(2010) Ryuhei Nishiyabu et al.   CHEMICAL COMMUNICATIONS

Growth of Crystalline Polyaminoborane through Catalytic Dehydrogenation of Ammonia Borane on FeB Nanoalloy

(2010) Teng He et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rate-Determining Factors in Nucleophilic Aromatic Substitution Reactions

(2010) Israel Fernández et al.   JOURNAL OF ORGANIC CHEMISTRY

Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions

(2010) Gavin O. Jones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of the Palladium-Catalyzed Borylation of Aryl Halides with Pinacolborane

(2010) King Chung Lam et al.   ORGANOMETALLICS

Highly Regio- and Enantioselective Copper-Catalyzed Hydroboration of Styrenes

(2009) Dongwan Noh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation

(2009) Toshimichi Ohmura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene

(2009) Thomas Braun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bis(imidazoline-2-thione)–copper(i) catalyzed regioselective boron addition to internal alkynes

(2009) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

sp2−sp3Hybridized Mixed Diboron: Synthesis, Characterization, and Copper-Catalyzed β-Boration of α,β-Unsaturated Conjugated Compounds

(2009) Ming Gao et al.   ORGANIC LETTERS

Layer-by-layer multilayer films linked with reversible boronate ester bonds with glucose-sensitivity under physiological conditions

(2009) Zhibo Ding et al.   Soft Matter

Syntheses, Structures, and Reactivities of Borylcopper and -zinc Compounds: 1,4-Silaboration of an α,β-Unsaturated Ketone to Form a γ-Siloxyallylborane

(2008) Takashi Kajiwara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Activated Alkenylboronates from Acetylenic Esters by CuH-Catalyzed 1,2-Addition/Transmetalation

(2008) Bruce H. Lipshutz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters: efficient synthesis of β-boryl-α,β-ethylenic esters

(2008) Ji-Eon Lee et al.   CHEMICAL COMMUNICATIONS

An Improved System for the Palladium-Catalyzed Borylation of Aryl Halides with Pinacol Borane

(2008) Kelvin L. Billingsley et al.   JOURNAL OF ORGANIC CHEMISTRY

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

(2008) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DFT Studies on the Borylation of α,β-Unsaturated Carbonyl Compounds Catalyzed by Phosphine Copper(I) Boryl Complexes and Observations on the Interconversions between O- and C-Bound Enolates of Cu, B, and Si

(2008) Li Dang et al.   ORGANOMETALLICS