Dynamic multiligand catalysis: A polar to radical crossover strategy expands alkyne carboboration to unactivated secondary alkyl halides

Design of Ru(II)-NHC-Diamine Precatalysts Directed by Ligand Cooperation: Applications and Mechanistic Investigations for Asymmetric Hydrogenation

(2020) Wei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Three-Component Borylallenylation of Alkynes: Access to Densely Boryl-Substituted Ene-allenes

(2020) Shang-Hai Yu et al.   ORGANIC LETTERS

Copper-Catalyzed Borylative Difunctionalization of π-Systems

(2020) Andrew Whyte et al.   ACS Catalysis

Nickel‐Copper‐Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes

(2019) Yusuke Ueda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Intramolecular Amination of Aliphatic C–H Bonds of Sulfamate Esters with High Reactivity and Chemoselectivity

(2019) Wei Liu et al.   ORGANIC LETTERS

Copper’s rapid ascent in visible-light photoredox catalysis

(2019) Asik Hossain et al.   SCIENCE

Gold and Palladium Mediated Bimetallic Catalysis: Mechanistic Investigation through the Isolation of the Organogold(I) Intermediates

(2019) Arno Verlee et al.   ACS Catalysis

A general asymmetric copper-catalysed Sonogashira C(sp3)–C(sp) coupling

(2019) Xiao-Yang Dong et al.   Nature Chemistry

Copper-Catalyzed Borocarbonylative Coupling of Internal Alkynes with Unactivated Alkyl Halides: Modular Synthesis of Tetrasubstituted β-Borylenones

(2018) Li-Jie Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The coordination- and photochemistry of copper(i) complexes: variation of N^N ligands from imidazole to tetrazole

(2018) Larissa Bergmann et al.   DALTON TRANSACTIONS

Decarboxylative Hydroalkylation of Alkynes

(2018) Nicholas A. Till et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed difunctionalization of allyl moieties using organoboronic acids and halides with divergent regioselectivities

(2018) Wanfang Li et al.   Chemical Science

Radical-Organometallic Hybrid Reaction System Enabling Couplings between Tertiary-Alkyl Groups and 1-Alkenyl Groups

(2018) Kimiaki Nakamura et al.   ACS Catalysis

Recent advances in radical transformations of internal alkynes

(2018) Min-Hua Huang et al.   CHEMICAL COMMUNICATIONS

Mechanistic Interrogation of Co/Ni-Dual Catalyzed Hydroarylation

(2018) Sophia L. Shevick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic Bimetallic Catalysis for Carboboration of Unsaturated Hydrocarbons

(2018) Martín Fañanás-Mastral et al.   SYNTHESIS-STUTTGART

Rationalizing the Role of NaOtBu in Copper-Catalyzed Carboboration of Alkynes: Assembly of Allylic All-Carbon Quaternary Stereocenters

(2018) Shin-Ho Kim-Lee et al.   ACS Catalysis

Switchable Synthetic Strategy toward Trisubstituted and Tetrasubstituted Exocyclic Alkenes

(2018) Sen Zhou et al.   ORGANIC LETTERS

Cu/Pd cooperatively catalyzed tandem C–N and C–P bond formation: access to phosphorated 2H-indazoles

(2017) Weiwei Wei et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Combinatorial Nickel-Catalyzed Monofluoroalkylation of Aryl Boronic Acids with Unactivated Fluoroalkyl Iodides

(2017) Jie Sheng et al.   ORGANIC LETTERS

Elusive Phosphine Copper(I) Boryl Complexes: Synthesis, Structures, and Reactivity

(2017) Corinna Borner et al.   ORGANOMETALLICS

Quantitative DFT modeling of product concentration in organometallic reactions: Cu-mediated pentafluoroethylation of benzoic acid chlorides as a case study

(2017) Jesús Jover   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Bimetallic catalysis for C–C and C–X coupling reactions

(2017) Dominic R. Pye et al.   Chemical Science

Synergistic Copper/Palladium Catalysis for the Regio- and Stereoselective Synthesis of Borylated Skipped Dienes

(2017) Jaime Mateos et al.   ACS Catalysis

Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

(2017) Gregory C. Fu   ACS Central Science

1,1-Disubstituted olefin synthesis via Ni-catalyzed Markovnikov hydroalkylation of alkynes with alkyl halides

(2016) Xiao-Yu Lu et al.   CHEMICAL COMMUNICATIONS

Ligand-Enabled, Copper-Catalyzed Regio- and Stereoselective Synthesis of Trialkylsubstituted Alkenylboronates from Unactivated Internal Alkynes

(2016) Taisuke Itoh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Unactivated Terminal Alkynes

(2016) Wei Su et al.   ACS Catalysis

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Cobalt-Catalyzed Allylation of Heterobicyclic Alkenes: Ligand-Induced Divergent Reactivities

(2015) Yuan Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylchlorosulfonylation of Alkenes: Evidence for an Inner-Sphere Mechanism by a Copper Phenanthroline Photoredox Catalyst

(2015) Dattatraya B. Bagal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Diboration and Carboboration of Alkynes

(2015) Naohisa Nakagawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Hydroalkylation of Terminal Alkynes

(2015) Mycah R. Uehling et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silicon-Tethered Strategy for Copper(I)-Catalyzed Stereo- and Regioselective Alkylboration of Alkynes

(2015) Koji Kubota et al.   ORGANIC LETTERS

Copper-Catalyzed 1,2-Addition of α-Carbonyl Iodides to Alkynes

(2014) Tao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural and Electrochemical Studies of Copper(I) Complexes with Diethoxyphosphoryl-1,10-phenanthrolines

(2014) Alexander Mitrofanov et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Copper-Catalyzed Regioselective Formation of Tri- and Tetrasubstituted Vinylboronates in Air

(2014) Yannick D. Bidal et al.   ACS Catalysis

Heteroleptic Copper(I) Complexes Prepared from Phenanthroline and Bis-Phosphine Ligands

(2013) Adrien Kaeser et al.   INORGANIC CHEMISTRY

Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes

(2013) Hiroto Yoshida et al.   ORGANIC LETTERS

The role of organometallic copper(iii) complexes in homogeneous catalysis

(2013) Alicia Casitas et al.   Chemical Science

Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems

(2012) Uta Wille   CHEMICAL REVIEWS

Regiocontrolled CuI-Catalyzed Borylation of Propargylic-Functionalized Internal Alkynes

(2012) Abraham L. Moure et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

(2012) Ricardo Alfaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple, Stable, and Easily Accessible Well-Defined CuCF3 Aromatic Trifluoromethylating Agents

(2011) Olesya A. Tomashenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CuCl-catalyzed aerobic oxidation of 2,3-allenols to 1,2-allenic ketones with 1:1 combination of phenanthroline and bipyridine as ligands

(2011) Shuxu Gao et al.   Beilstein Journal of Organic Chemistry

Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile

(2010) Yuri Okuno et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphoramidites: Privileged Ligands in Asymmetric Catalysis

(2010) Johannes F. Teichert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Multiligand Based Pd Catalyst for C−N Cross-Coupling Reactions

(2010) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A combinatorial approach to the identification of self-assembled ligands for rhodium-catalysed asymmetric hydrogenation

(2010) Joerg Wieland et al.   Nature Chemistry

Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

(2009) Luca Pignataro et al.   CHEMICAL COMMUNICATIONS

Combinatorial Transition-Metal Catalysis: Mixing Monodentate Ligands to Control Enantio-, Diastereo-, and Regioselectivity

(2008) Manfred T. Reetz   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ab Initio Evaluation of the Thermodynamic and Electrochemical Properties of Alkyl Halides and Radicals and Their Mechanistic Implications for Atom Transfer Radical Polymerization

(2008) Ching Yeh Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY