Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile

Enantioselective Conjugate Borylation

(2010) Julia A. Schiffner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions

(2010) Kyoko Nozaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis oftrans-Aryl- and -Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative

(2010) Chongmin Zhong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative

(2010) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes: Synthesis of Enantioenriched Cyclic Homoallyl- and Allylboronates

(2010) Yusuke Sasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

(2010) Hajime Ito et al.   Nature Chemistry

Copper-Catalyzed Conjugate Addition of Diboron Reagents to α,β-Unsaturated Amides: Highly Reactive Copper-1,2- Bis(diphenylphosphino)benzene Catalyst System

(2009) Heesung Chea et al.   ADVANCED SYNTHESIS & CATALYSIS

Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes

(2009) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

(2009) Xinhui Feng et al.   CHEMICAL COMMUNICATIONS

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

Bis(imidazoline-2-thione)–copper(i) catalyzed regioselective boron addition to internal alkynes

(2009) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Enantioselective β-Boration of Acyclic Enones

(2009) Hak-Suk Sim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric induction on β-boration of α,β-unsaturated compounds: an inexpensive approach

(2009) Vanesa Lillo et al.   DALTON TRANSACTIONS

Facile entry to 3d late transition metal boryl complexes

(2009) Ba L. Tran et al.   DALTON TRANSACTIONS

Group-4 Transition-Metal Boryl Complexes: Syntheses, Structures, Boron−Metal Bonding Properties, and Application as a Polymerization Catalyst

(2009) Tomomi Terabayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand

(2009) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones

(2009) I-Hon Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The selective catalytic formation of β-boryl aldehydes through a base-free approach

(2009) Amadeu Bonet et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Axially chiral P-N ligands for the copper catalyzed β-borylation of α,β-unsaturated esters

(2009) William J. Fleming et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium−Ethylene Complexes

(2009) Yasutomo Segawa et al.   ORGANOMETALLICS

A Bromide-bridged Platinum(II) Complex as Precursor to a Neutral Platinum Compound with a Base-Stabilized Borylene Ligand

(2009) Holger Braunschweig et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Synthesis of Chloro Boryl Complexes by Oxidative Addition of B-Cl Bonds

(2009) Holger Braunschweig et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Syntheses, Structures, and Reactivities of Borylcopper and -zinc Compounds: 1,4-Silaboration of an α,β-Unsaturated Ketone to Form a γ-Siloxyallylborane

(2008) Takashi Kajiwara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative

(2008) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents

(2008) Masaki Daini et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters: efficient synthesis of β-boryl-α,β-ethylenic esters

(2008) Ji-Eon Lee et al.   CHEMICAL COMMUNICATIONS

Crystal Structure of Boryllithium with Two THF Molecules and DFT Analysis of Its Property as a Boryl Anion

(2008) Makoto Yamashita et al.   CHEMISTRY LETTERS

T-Shaped Platinum Boryl Complexes: Synthesis and Structure

(2008) Holger Braunschweig et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of η1-borazine complexes of palladium and platinum

(2008) Holger Braunschweig et al.   DALTON TRANSACTIONS

Oxidative Addition of B–Br Bonds to Pd0: Synthesis and Structure oftrans-Bromo(boryl)palladium Complexes

(2008) Holger Braunschweig et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

On the origin of the trans-influence in square planar d8-complexes: A theoretical study

(2008) Mariusz P. Mitoraj et al.   INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY

Palladium-Catalyzedtrans- andcis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents:  Ligand-Dependent Complementary Stereoselectivity

(2008) Masaki Daini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

(2008) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DFT Studies on the Mechanism of the Diboration of Aldehydes Catalyzed by Copper(I) Boryl Complexes

(2008) Haitao Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper-Catalyzed Synthesis of α-Amino Boronate Esters fromN-tert-Butanesulfinyl Aldimines

(2008) Melissa A. Beenen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates

(2008) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion oftrans-Bromoboryl Platinum Complexes into theircis-Analogues upon Treatment with Chelating Bisphosphines

(2008) Holger Braunschweig et al.   ORGANOMETALLICS

Understanding the Higher Reactivity of B2cat2versus B2pin2in Copper(I)-Catalyzed Alkene Diboration Reactions

(2008) Li Dang et al.   ORGANOMETALLICS

DFT Studies on the Borylation of α,β-Unsaturated Carbonyl Compounds Catalyzed by Phosphine Copper(I) Boryl Complexes and Observations on the Interconversions between O- and C-Bound Enolates of Cu, B, and Si

(2008) Li Dang et al.   ORGANOMETALLICS

Asymmetric β-Boration of α,β-Unsaturated Esters with Chiral (NHC)Cu Catalysts

(2008) Vanesa Lillo et al.   ORGANOMETALLICS

Catalytic Asymmetric Boration of Acyclic α,β-Unsaturated Esters and Nitriles

(2007) Ji-Eon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION