Highly Enantioselective Synthesis of Tertiary Boronic Esters and their Stereospecific Conversion to other Functional Groups and Quaternary Stereocentres

Enantioselective Construction of Quaternary Stereogenic Centers from Tertiary Boronic Esters: Methodology and Applications

(2011) Ravindra P. Sonawane et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Synthesis of Highly Enantioenriched C-Tertiary Amines From Boronic Esters: Application to the Synthesis of Igmesine

(2010) Viktor Bagutski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Full Chirality Transfer in the Conversion of Secondary Alcohols into Tertiary Boronic Esters and Alcohols Using Lithiation-Borylation Reactions

(2010) Viktor Bagutski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conjugate Boration of β,β-Disubstituted Unsaturated Esters: Asymmetric Synthesis of Functionalized Chiral Tertiary Organoboronic Esters

(2010) Xinhui Feng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Protodeboronation of Tertiary Boronic Esters: Asymmetric Synthesis of Tertiary Alkyl Stereogenic Centers

(2010) Stefan Nave et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters

(2010) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)−Secondary Diamine Complex-Catalyzed Enantioselective Conjugate Boration of Linear β,β-Disubstituted Enones

(2010) I-Hon Chen et al.   ORGANIC LETTERS

Complete Stereoretention in the Rhodium-Catalyzed 1,2-Addition of Chiral Secondary and Tertiary Alkyl Potassium Trifluoroborate Salts to Aldehydes

(2009) Abel Ros et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile and Efficient Enantioselective Strecker Reaction of Ketimines by Chiral Sodium Phosphate

(2009) Ke Shen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Cyanation of Aldehydes, Ketones, Aldimines, and Ketimines Catalyzed by a Versatile Catalyst Generated from Cinchona Alkaloid, Achiral Substituted 2,2′-Biphenol and Tetraisopropyl Titanate

(2009) Jun Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Improved method for the conversion of pinacolboronic esters into trifluoroborate salts: facile synthesis of chiral secondary and tertiary trifluoroborates

(2009) Viktor Bagutski et al.   TETRAHEDRON

The Catalytic Asymmetric Strecker Reaction: Ketimines Continue to Join the Fold

(2008) Stephen J. Connon   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines

(2008) Masakatsu Shibasaki et al.   CHEMICAL REVIEWS

Asymmetric Reductive Mannich Reaction to Ketimines Catalyzed by a Cu(I) Complex

(2008) Yao Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Addition of Allylic Cyanides to Ketoimines

(2008) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Alkylations of Ketoimines. Enantioselective Synthesis ofN-Substituted Quaternary Carbon Stereogenic Centers by Zr-Catalyzed Additions of Dialkylzinc Reagents to Aryl-, Alkyl-, and Trifluoroalkyl-Substituted Ketoimines

(2008) Peng Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Silicon Lewis Acid for Highly Enantioselective Mannich Reactions of Aliphatic Ketone-Derived Hydrazones

(2008) Gregory T. Notte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borabicyclo[3.3.2]decanes and the Stereoselective Asymmetric Synthesis of 1,3-Diol Stereotriads from 1,3-Diborylpropenes

(2008) Ana Z. González et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols

(2008) Jake L. Stymiest et al.   NATURE

Asymmetric Synthesis of Homoallylic Amines Bearing Adjacent Stereogenic Centers by Addition of Substituted Allylic Zinc Reagents to N-tert-Butanesulfinylimines†

(2008) Leleti Rajender Reddy et al.   ORGANIC LETTERS

Stereoselective Monofluoromethylation ofN-tert-Butylsulfinyl Ketimines Using Pregenerated Fluoro(phenylsulfonyl)methyl Anion

(2008) Jun Liu et al.   ORGANIC LETTERS

Synthesis of Optically Active Arylaziridines by Regio- and Stereospecific Lithiation ofN-Bus-Phenylaziridine

(2008) Biagia Musio et al.   ORGANIC LETTERS