Formal nucleophilic borylation and borylative cyclization of organic halides

Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenes to Cyclobutenes

(2016) Youai Qiu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

(2016) Emily C. Neeve et al.   CHEMICAL REVIEWS

Iridium(I)-catalyzed C−H Borylation of α,β-Unsaturated Esters with Bis(pinacolato)diboron

(2016) Ikuo Sasaki et al.   Chemistry-An Asian Journal

Borylative Cyclization Reactions

(2016) Elena Buñuel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Manganese-Catalyzed Borylation of Unactivated Alkyl Chlorides

(2016) Thomas C. Atack et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C–H Bonds

(2016) Matthew A. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts

(2016) Adelphe M. Mfuh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Additive- and Metal-Free, Predictably 1,2- and 1,3-Regioselective, Photoinduced Dual C–H/C–X Borylation of Haloarenes

(2016) Adelphe M. Mfuh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light Photoredox Borylation of Aryl Halides and Subsequent Aerobic Oxidative Hydroxylation

(2016) Min Jiang et al.   ORGANIC LETTERS

Efficient metal-free photochemical borylation of aryl halides under batch and continuous-flow conditions

(2016) Kai Chen et al.   Chemical Science

Zinc-Catalyzed Dual C-X and C-H Borylation of Aryl Halides

(2015) Shubhankar Kumar Bose et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(i)-catalyzed carbon–halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties

(2015) Hiroaki Iwamoto et al.   CHEMICAL COMMUNICATIONS

Reaction Mechanism of the Anomalous Formal Nucleophilic Borylation of Organic Halides with Silylborane: Combined Theoretical and Experimental Studies

(2015) Ryohei Uematsu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

para-C–H Borylation of Benzene Derivatives by a Bulky Iridium Catalyst

(2015) Yutaro Saito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regiodivergent Cu-Catalyzed Aminoboration of Unactivated Terminal Alkenes

(2015) Ryosuke Sakae et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Borylation of Aryl Fluorides via C–F Cleavage

(2015) Xiang-Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silicon-Tethered Strategy for Copper(I)-Catalyzed Stereo- and Regioselective Alkylboration of Alkynes

(2015) Koji Kubota et al.   ORGANIC LETTERS

Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies

(2015) Eiji Yamamoto et al.   Chemical Science

Zinc-Catalyzed Borylation of Primary, Secondary and Tertiary Alkyl Halides with Alkoxy Diboron Reagents at Room Temperature

(2014) Shubhankar Kumar Bose et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed C–H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism

(2014) Matthew A. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Borylation of Alkyl Electrophiles

(2014) Thomas C. Atack et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis

(2014) Behnaz Ghaffari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Borylation of Alkyl, Allyl, and Aryl Halides: Isolation of an Iron(I) Boryl Complex

(2014) Robin B. Bedford et al.   ORGANOMETALLICS

Iridium(i)-catalyzed vinylic C–H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

(2013) Ikuo Sasaki et al.   CHEMICAL COMMUNICATIONS

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cesium Carbonate Mediated Borylation of Aryl Iodides with Diboron in Methanol

(2013) Jieming Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B2(OH)4]

(2013) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu-Catalyzed Asymmetric Borylative Cyclization of Cyclohexadienone-Containing 1,6-Enynes

(2013) Ping Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed C–H Borylation of Cyclopropanes

(2013) Carl W. Liskey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

(2013) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A decade advancement of transition metal-catalyzed borylation of aryl halides and sulfonates

(2013) Wing Kin Chow et al.   RSC Advances

Alkylboronic Esters from Palladium- and Nickel-Catalyzed Borylation of Primary and Secondary Alkyl Bromides

(2012) Jun Yi et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Copper(I)-Catalyzed Borylative Aldol Cyclizations of Enone Diones

(2012) Alan R. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Borylation of Primary Alkyl Bromides

(2012) Amruta Joshi-Pangu et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes

(2012) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Borylation of Secondary C–H Bonds in Cyclic Ethers

(2012) Carl W. Liskey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, To Generate Carbon–Boron Bonds

(2012) Alexander S. Dudnik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Outer-Sphere Direction in Iridium C–H Borylation

(2012) Philipp C. Roosen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Ortho C–H Borylation of 2-Phenoxypyridines under Mild Conditions

(2012) Liting Niu et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Boryl Substitution of Unactivated Alkyl Halides

(2012) Hajime Ito et al.   ORGANIC LETTERS

Transition-Metal-Free Borylation of Aryltriazene Mediated by BF3·OEt2

(2012) Chuan Zhu et al.   ORGANIC LETTERS

Reactivity of Lewis Acid Activated Diaza- and Dithiaboroles in Electrophilic Arene Borylation

(2012) S. A. Solomon et al.   ORGANOMETALLICS

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with a Silica-Supported Compact Phosphane Ligand

(2011) Soichiro Kawamorita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Synthesis of Organoboronic Acids

(2011) Lukasz T. Pilarski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkylboronic Esters from Copper-Catalyzed Borylation of Primary and Secondary Alkyl Halides and Pseudohalides

(2011) Chu-Ting Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pinacol Boronates by Direct Arene Borylation with Borenium Cations

(2011) Alessandro Del Grosso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple inexpensive boron electrophiles for direct arene borylation

(2011) Alessandro Del Grosso et al.   CHEMICAL COMMUNICATIONS

Pd-Catalyzed Borylative Polycyclization of Enediynes to Alkylboronates

(2011) Juan Marco-Martínez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh-CatalyzedOrtho-Selective C–H Borylation ofN-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands

(2011) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoconvergent Amine-Directed Alkyl–Alkyl Suzuki Reactions of Unactivated Secondary Alkyl Chlorides

(2011) Zhe Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of BN-Fused Polycyclic Aromatics via Tandem Intramolecular Electrophilic Arene Borylation

(2011) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NiCl2(PMe3)2-Catalyzed Borylation of Aryl Chlorides

(2011) Tetsuya Yamamoto et al.   ORGANIC LETTERS

Expanding the Limits of Organoboron Chemistry: Synthesis of Functionalized Arylboronates

(2010) Pedro Merino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Conversion of Arylamines to Pinacol Boronates: A Metal-Free Borylation Process

(2010) Fanyang Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 2-Boryl- and Silylindoles by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl Isocyanides

(2010) Mamoru Tobisu et al.   JOURNAL OF ORGANIC CHEMISTRY

Neopentylglycolborylation ofortho-Substituted Aryl Halides Catalyzed by NiCl2-Based Mixed-Ligand Systems

(2010) Costel Moldoveanu et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis oftrans-Aryl- and -Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative

(2010) Chongmin Zhong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative

(2010) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed, Direct Boronic Acid Synthesis from Aryl Chlorides: A Simplified Route to Diverse Boronate Ester Derivatives

(2010) Gary A. Molander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent progress in the synthesis of five-membered heterocycle boronic acids and esters

(2010) Nicolas Primas et al.   TETRAHEDRON

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry of Organomanganese(II) Compounds

(2009) Gérard Cahiez et al.   CHEMICAL REVIEWS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative

(2008) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Rhodium-Catalyzed Borylative Cyclization of 2-Alkynylaryl Isocyanates with Bis(pinacolato)diboron

(2008) Tomoya Miura et al.   ORGANIC LETTERS

Sequential Ni-Catalyzed Borylation and Cross-Coupling of Aryl Halides via in Situ Prepared Neopentylglycolborane

(2008) Brad M. Rosen et al.   ORGANIC LETTERS