Direct introduction of a naphthalene-1,8-diamino boryl [B(dan)] group by a Pd-catalysed selective boryl transfer reaction

Mixed diboration of alkenes in a metal-free context

(2015) Nuria Miralles et al.   CHEMICAL COMMUNICATIONS

Site-Differentiated Polyboron Arenes Prepared by Direct CH Borylation and Their Highly Selective Suzuki-Miyaura Cross-Coupling Reactions

(2014) Liang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons

(2014) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

A Clear-Cut Example of Selective BpinBdan Activation and Precise Bdan Transfer on Boron Conjugate Addition

(2014) Jessica Cid et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of most polyene natural product motifs using just 12 building blocks and one coupling reaction

(2014) Eric M. Woerly et al.   Nature Chemistry

Practical and Convenient Synthesis of 1,6-Di- or 1,2,5,6-Tetra-arylhexa-1,3,5-trienes by the Dimerization of Pd(0)-Complexed Alkenylcarbenes Generated from π-Allylpalladium Intermediates

(2014) Yoshikazu Horino et al.   ORGANIC LETTERS

Efficient Synthesis of Aryl Boronates via Zinc-Catalyzed Cross-Coupling of Alkoxy Diboron Reagents with Aryl Halides at Room Temperature

(2014) Shubhankar Kumar Bose et al.   ORGANIC LETTERS

Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes

(2014) Hiroto Yoshida et al.   Asian Journal of Organic Chemistry

Regio- and Enantioselective Copper(I)-Catalyzed Hydroboration of Borylalkenes: Asymmetric Synthesis of 1,1-Diborylalkanes

(2013) Xinhui Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B2(OH)4]

(2013) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY

Design, Generation, and Synthetic Application of Borylzincate: Borylation of Aryl Halides and Borylzincation of Benzynes/Terminal Alkyne

(2013) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diborylation of Alkynyl MIDA Boronates and Sequential Chemoselective Suzuki–Miyaura Couplings: A Formal Carboborylation of Alkynes

(2013) Keita Hyodo et al.   ORGANIC LETTERS

Scope of the Two-Step, One-Pot Palladium-Catalyzed Borylation/Suzuki Cross-Coupling Reaction Utilizing Bis-Boronic Acid

(2012) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener

(2012) Gary A. Molander et al.   ORGANIC LETTERS

Total Synthesis of Synechoxanthin through Iterative Cross-Coupling

(2011) Seiko Fujii et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with a Silica-Supported Compact Phosphane Ligand

(2011) Soichiro Kawamorita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkynylboronates and -boramides in CoI- and RhI-Catalyzed [2+2+2] Cycloadditions: Construction of Oligoaryls through Selective Suzuki Couplings

(2011) Laura Iannazzo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Structure and Reactivity of a Preactivated sp2–sp3Diboron Reagent: Catalytic Regioselective Boration of α,β-Unsaturated Conjugated Compounds

(2011) Ming Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Pinene-Derived Iminodiacetic Acid (PIDA): A Powerful Ligand for Stereoselective Synthesis and Iterative Cross-Coupling of C(sp3) Boronate Building Blocks

(2011) Junqi Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Borylation of Nitriles through the Cleavage of Carbon–Cyano Bonds

(2011) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

NiCl2(PMe3)2-Catalyzed Borylation of Aryl Chlorides

(2011) Tetsuya Yamamoto et al.   ORGANIC LETTERS

A Simple and General Platform for Generating Stereochemically Complex Polyene Frameworks by Iterative Cross-Coupling

(2010) Suk Joong Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboroxines to Borylalkenes: Asymmetric Synthesis of β-Arylalkylboranes

(2010) Keigo Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron

(2010) Steven B. Thorpe et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules

(2010) Noriyuki Iwadate et al.   CHEMISTRY LETTERS

Borylation of Aryl and Alkenyl Carbamates through Ni-Catalyzed CO Activation

(2010) Kun Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereoretentive Suzuki−Miyaura Coupling of Haloallenes Enables Fully Stereocontrolled Access to (−)-Peridinin

(2010) Eric M. Woerly et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Boronate Derivatives via Catalytic Enantioselective Conjugate Addition of Grignard Reagents on 3-Boronyl Unsaturated Esters and Thioesters

(2010) Jack Chang Hung Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

(2010) Noriyuki Iwadate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed, Direct Boronic Acid Synthesis from Aryl Chlorides: A Simplified Route to Diverse Boronate Ester Derivatives

(2010) Gary A. Molander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Iterative Synthesis of Biphenyl Dendrons with a Functionalized Focus

(2010) Ellen J. Wren et al.   ORGANIC LETTERS

Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

(2010) David S. Surry et al.   Chemical Science

Devising Boron Reagents for Orthogonal Functionalization through Suzuki-Miyaura Cross-Coupling

(2009) Mamoru Tobisu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Controlled Iterative Cross-Coupling: On the Way to the Automation of Organic Synthesis

(2009) Congyang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

(2009) Noriyuki Iwadate et al.   ORGANIC LETTERS

sp2−sp3Hybridized Mixed Diboron: Synthesis, Characterization, and Copper-Catalyzed β-Boration of α,β-Unsaturated Conjugated Compounds

(2009) Ming Gao et al.   ORGANIC LETTERS

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Biaryl Phosphane Ligands in Palladium-Catalyzed Amination

(2008) David S. Surry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C–H borylation with 1,8-naphthalenediaminatoborane (danBH)

(2008) Noriyuki Iwadate et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Orthogonal Reactivity in Boryl-Substituted Organotrifluoroborates

(2008) Gary A. Molander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multistep Synthesis of Complex Boronic Acids from Simple MIDA Boronates

(2008) Eric P. Gillis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentially Protected Benzenediboronic Acids:  Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

(2008) Hiroyoshi Noguchi et al.   ORGANIC LETTERS

Development of the first and practical method for enantioselective synthesis of 10B-enriched p-borono-l-phenylalanine

(2008) Yoshihide Hattori et al.   TETRAHEDRON LETTERS

Simple, Efficient, and Modular Syntheses of Polyene Natural Products via Iterative Cross-Coupling

(2007) Suk Joong Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY