Synthesis, Structure, and Reactivity of Anionic sp2-sp3Diboron Compounds: Readily Accessible Boryl Nucleophiles

CuIIand Cu0Catalyzed Mono Borylation of Unsaturated Hydrocarbons with B2pin2: Entering into the Water

(2015) Gaj Stavber et al.   ChemCatChem

Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen

(2014) Nicole Dettenrieder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones

(2014) Suttipol Radomkit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Face to face activation of a phenylselenium borane with α,β-unsaturated carbonyl substrates: facile synthesis of C–Se bonds

(2014) Xavier Sanz et al.   CHEMICAL COMMUNICATIONS

Functional group directed C–H borylation

(2014) A. Ros et al.   CHEMICAL SOCIETY REVIEWS

A Clear-Cut Example of Selective BpinBdan Activation and Precise Bdan Transfer on Boron Conjugate Addition

(2014) Jessica Cid et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Easy Route to (Hetero)arylboronic Acids

(2014) William Erb et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective Synthesis of Unsymmetrical Diboryl PtIIand Diaminoboryl CuIComplexes by B-B Activation of Unsymmetrical Diboranes(4) {pinB-B[(NR)2C6H4]}

(2014) Corinna Borner et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of Trimethylstannyl Arylboronate Compounds by Sandmeyer-Type Transformations and Their Applications in Chemoselective Cross-Coupling Reactions

(2014) Di Qiu et al.   JOURNAL OF ORGANIC CHEMISTRY

Sequential One-Pot Access to Molecular Diversity through Aniline Aqueous Borylation

(2014) William Erb et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Arylboronic Pinacol Esters from Corresponding Arylamines

(2014)   ORGANIC SYNTHESES

Regioselective Synthesis of Substituted Tetrahydrofurans through Prins Cyclization

(2014) Li-Ming Zhao et al.   SYNLETT

Direct synthesis of arylboronic pinacol esters from arylamines

(2014) Di Qiu et al.   Organic Chemistry Frontiers

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkoxide Activation of Aminoboranes towards Selective Amination

(2013) Cristina Solé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a bicyclic diborane by selective boron carbon bond formation

(2013) Holger Braunschweig et al.   CHEMICAL COMMUNICATIONS

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the Reactivity of Silylboranes toward Lewis Bases: Heterolytic B-Si Cleavage vs. Adduct Formation

(2013) Christian Kleeberg et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cesium Carbonate Mediated Borylation of Aryl Iodides with Diboron in Methanol

(2013) Jieming Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

(2013) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quaternizing Diboranes(4): Highly Divergent Outcomes and an Inorganic Wagner–Meerwein Rearrangement

(2013) Holger Braunschweig et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free borylative ring-opening of vinyl epoxides and aziridines

(2013) Xavier Sanz et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

NHC–Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism

(2013) Fanke Meng et al.   ORGANIC LETTERS

A decade advancement of transition metal-catalyzed borylation of aryl halides and sulfonates

(2013) Wing Kin Chow et al.   RSC Advances

Metal-Mediated Synthesis of 1,4-Di-tert-butyl-1,4-azaborine

(2012) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An inorganic propellane with central B–B bond

(2012) Steffen Pospiech et al.   CHEMICAL COMMUNICATIONS

Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

(2012) Kazuyuki Oshima et al.   CHEMICAL COMMUNICATIONS

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

(2012) Hajime Ito et al.   CHEMICAL COMMUNICATIONS

Asymmetric synthesis of α-amino boronate esters via organocatalytic pinacolboryl addition to tosylaldimines

(2012) Cristina Solé et al.   CHEMICAL COMMUNICATIONS

Trivalent boron nucleophile as a new tool in organic synthesis: reactivity and asymmetric induction

(2012) Jessica Cid et al.   CHEMICAL SOCIETY REVIEWS

Disclosing the Structure/Activity Correlation in Trivalent Boron-Containing Compounds: A Tendency Map

(2012) Jessica Cid et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation

(2012) Di Qiu et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems

(2012) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric organocatalytic diboration of alkenes

(2012) Amadeu Bonet et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Essential role of phosphines in organocatalytic β-boration reaction

(2012) Cristina Pubill-Ulldemolins et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper(II)-Catalyzed Silyl Conjugate Addition to α,β-Unsaturated Conjugated Compounds: Brønsted Base-Assisted Activation of Si–B Bond in Water

(2012) Joseph A. Calderone et al.   ORGANIC LETTERS

Transition-Metal-Free Borylation of Aryltriazene Mediated by BF3·OEt2

(2012) Chuan Zhu et al.   ORGANIC LETTERS

Copper-Catalyzed Double Borylation of Silylacetylenes: Highly Regio- and Stereoselective Synthesis of Syn-Vicinal Diboronates

(2012) Ho-Young Jung et al.   ORGANIC LETTERS

Nucleophilic boron strikes back

(2012) Henrik Gulyás et al.   PURE AND APPLIED CHEMISTRY

Four-coordinate organoboron compounds from β-enaminonitriles and diazonium salts

(2012) Markéta Svobodová et al.   TETRAHEDRON

Catalytic, Direct Synthesis of Bis(boronate) Compounds

(2012) Jun Takaya et al.   ACS Catalysis

Transition-Metal-Free Diboration Reaction by Activation of Diboron Compounds with Simple Lewis Bases

(2011) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Syntheses and properties of triborane(5)s possessing bulky diamino substituents on terminal boron atoms

(2011) Yumi Hayashi et al.   CHEMICAL COMMUNICATIONS

Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes

(2011) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Activation of Diboron Reagents with Brønsted Bases and Alcohols: An Experimental and Theoretical Perspective of the Organocatalytic Boron Conjugate Addition Reaction

(2011) Cristina Pubill-Ulldemolins  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic versus Iron-Assisted β-Boration of Electron-Deficient Olefins

(2011) Amadeu Bonet et al.   Chemistry-An Asian Journal

One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling of the Resulting Tetrasubstituted Alkenylborane

(2011) Yuri Okuno et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Spectroscopic and Structural Characterization of the CyNHC Adduct of B2pin2 in Solution and in the Solid State

(2011) Christian Kleeberg et al.   JOURNAL OF ORGANIC CHEMISTRY

Structure and Reactivity of a Preactivated sp2–sp3Diboron Reagent: Catalytic Regioselective Boration of α,β-Unsaturated Conjugated Compounds

(2011) Ming Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Catalytic C–Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2011) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C–H Bond

(2011) Philipp Bissinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Reduction of CO2with pinB-SiMe2Ph via CO2Insertion into a Copper–Silicon Bond

(2011) Christian Kleeberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanisms of Reactions of a Lithium Boryl with Organohalides

(2011) Man Sing Cheung et al.   ORGANOMETALLICS

Copper-catalyzed boration of activated alkynes. Chiral boranes via a one-pot copper-catalyzed boration and reduction protocol

(2011) Ho-Young Jung et al.   TETRAHEDRON

Nucleophilicity of a Base-Stabilized Borole Anion at the Boron Center

(2010) Makoto Yamashita   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structure of a Carbene-Stabilized π-Boryl Anion

(2010) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Conversion of Arylamines to Pinacol Boronates: A Metal-Free Borylation Process

(2010) Fanyang Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron

(2010) Steven B. Thorpe et al.   CHEMICAL COMMUNICATIONS

Conjugate Boration of β,β-Disubstituted Unsaturated Esters: Asymmetric Synthesis of Functionalized Chiral Tertiary Organoboronic Esters

(2010) Xinhui Feng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions

(2010) Kyoko Nozaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origins of the Selectivity for Borylation of Primary over Secondary C−H Bonds Catalyzed by Cp*-Rhodium Complexes

(2010) Carolyn S. Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters

(2010) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Selective Ni-Catalyzed Hydroalumination of Aryl- and Alkyl-Substituted Terminal Alkynes: Practical Syntheses of Internal Vinyl Aluminums, Halides, or Boronates

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Not just any old anion

(2010) Kyoko Nozaki   NATURE

Room-Temperature Copper-Catalyzed Carbon-Nitrogen Coupling of Aryl Iodides and Bromides Promoted by Organic Ionic Bases

(2009) Chu-Ting Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene

(2009) Thomas Braun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

(2009) Xinhui Feng et al.   CHEMICAL COMMUNICATIONS

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Copper-Catalyzed Enantioselective β-Boration of Acyclic Enones

(2009) Hak-Suk Sim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric induction on β-boration of α,β-unsaturated compounds: an inexpensive approach

(2009) Vanesa Lillo et al.   DALTON TRANSACTIONS

Facile entry to 3d late transition metal boryl complexes

(2009) Ba L. Tran et al.   DALTON TRANSACTIONS

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2009) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

sp2−sp3Hybridized Mixed Diboron: Synthesis, Characterization, and Copper-Catalyzed β-Boration of α,β-Unsaturated Conjugated Compounds

(2009) Ming Gao et al.   ORGANIC LETTERS

Et-duphos-nickel-catalyzed asymmetric arylation of benzaldehyde derivatives bearing an ortho-Me2PhSi group with potassium aryltriolborates

(2009) Fumie Sakurai et al.   TETRAHEDRON LETTERS

Syntheses, Structures, and Reactivities of Borylcopper and -zinc Compounds: 1,4-Silaboration of an α,β-Unsaturated Ketone to Form a γ-Siloxyallylborane

(2008) Takashi Kajiwara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Coupling of Nitrogen Heteroaromatics and Alkanes without Transition Metals: A New Oxidative Cross-Coupling at CH/CH Bonds

(2008) Guojun Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aryl Triolborates: Novel Reagent for Copper-Catalyzed N Arylation of Amines, Anilines, and Imidazoles

(2008) Xiao-Qiang Yu et al.   Chemistry-An Asian Journal

Mercury CSD 2.0– new features for the visualization and investigation of crystal structures

(2008) Clare F. Macrae et al.   JOURNAL OF APPLIED CRYSTALLOGRAPHY

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

(2008) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DFT Studies on the Mechanism of the Diboration of Aldehydes Catalyzed by Copper(I) Boryl Complexes

(2008) Haitao Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassiumt-Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes

(2008) Shuichi Yanagisawa et al.   ORGANIC LETTERS

Understanding the Higher Reactivity of B2cat2versus B2pin2in Copper(I)-Catalyzed Alkene Diboration Reactions

(2008) Li Dang et al.   ORGANOMETALLICS

DFT Studies on the Borylation of α,β-Unsaturated Carbonyl Compounds Catalyzed by Phosphine Copper(I) Boryl Complexes and Observations on the Interconversions between O- and C-Bound Enolates of Cu, B, and Si

(2008) Li Dang et al.   ORGANOMETALLICS

Asymmetric β-Boration of α,β-Unsaturated Esters with Chiral (NHC)Cu Catalysts

(2008) Vanesa Lillo et al.   ORGANOMETALLICS

Boryllithium: A novel boron nucleophile and its application in the synthesis of borylmetal complexes

(2008) Makoto Yamashita et al.   PURE AND APPLIED CHEMISTRY

Cyclic Triolborates: Air- and Water-Stable Ate Complexes of Organoboronic Acids

(2007) Yasunori Yamamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION