Copper-Catalyzed Stereoselective Defluorinative Borylation and Silylation of gem -Difluoroalkenes

Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes

(2017) Hironobu Sakaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mild and Ligand-Free Ni-Catalyzed Silylation via C–OMe Cleavage

(2017) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Theoretical Studies on Rhodium-Catalyzed Coupling of Benzamides with 2,2-Difluorovinyl Tosylate: Diverse Synthesis of Fluorinated Heterocycles

(2017) Jia-Qiang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal nucleophilic borylation and borylative cyclization of organic halides

(2017) K. Kubota et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Base Catalysis Enables Access to α,α-Difluoroalkylthioethers

(2017) Douglas L. Orsi et al.   ORGANIC LETTERS

Cu-Catalyzed Stereoselective Borylation of gem-Difluoroalkenes with B2pin2

(2017) Juan Zhang et al.   ORGANIC LETTERS

Copper-Catalyzed ipso-Borylation of Fluoroarenes

(2017) Takashi Niwa et al.   ACS Catalysis

C–F/C–H Functionalization by Manganese(I) Catalysis: Expedient (Per)Fluoro-Allylations and Alkenylations

(2017) Daniel Zell et al.   ACS Catalysis

Synthesis of Exocyclic Trisubstituted AlkenesviaNickel- Catalyzed Kumada-Type Cross-Coupling Reaction ofgem- Difluoroalkenes with Di-Grignard Reagents

(2016) Wenpeng Dai et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Defluorinative Coupling of 1-Aryl-2,2-Difluoroalkenes and Boronic Acids: Stereoselective Synthesis of Monofluorostilbenes

(2016) Richard T. Thornbury et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Cyclobutylboronates via a Copper-Catalyzed Desymmetrization Approach

(2016) Manuel Guisán-Ceinos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of β-Boryl-α-Aminosilanes by Copper-Catalyzed Aminoboration of Vinylsilanes

(2016) Kodai Kato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Carbonyl Olefination with Fluorosulfoximines: Facile Access toZorETerminal Monofluoroalkenes

(2016) Qinghe Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes

(2016) Lin Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Monofluoroalkenylation of Dimethylamino Compounds through Radical-Radical Cross-Coupling

(2016) Jin Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and Copper-Free Stereoselective Cyanation of gem -Difluoroalkenes by Using Benzyl Nitrile as a Cyanating Reagent

(2016) Juan Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereospecific Synthesis of Fluoroalkenes by Silver-Mediated Fluorination of Functionalized Alkenylstannanes

(2016) Heiko Sommer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparing (Multi)Fluoroarenes as Building Blocks for Synthesis: Nickel-Catalyzed Borylation of Polyfluoroarenes via C–F Bond Cleavage

(2016) Jing Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkyl Bromides as Mild Hydride Sources in Ni-Catalyzed Hydroamidation of Alkynes with Isocyanates

(2016) Xueqiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New one-pot synthesis of N-fused isoquinoline derivatives by palladium-catalyzed C–H arylation: potent inhibitors of nucleotide pyrophosphatase-1 and -3

(2016) Elina Ausekle et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Sterically Controlled Cu-Catalyzed or Transition-Metal-Free Cross-Coupling of gem-Difluoroalkenes with Tertiary, Secondary, and Primary Alkyl Grignard Reagents

(2016) Wenpeng Dai et al.   ORGANIC LETTERS

Cobalt(III)-Catalyzed Regio- and Stereoselective α-Fluoroalkenylation of Arenes with gem-Difluorostyrenes

(2016) Lingheng Kong et al.   ORGANIC LETTERS

Peroxide-Free Co(OAc)2-Catalyzed Radical Addition of sp3 C–H Bonds to Alkynes

(2016) Wanzhi Chen et al.   SYNTHESIS-STUTTGART

Dehydrogenative Borylation and Silylation of Styrenes Catalyzed by Copper-Carbenes

(2016) Thomas J. Mazzacano et al.   ACS Catalysis

Metal-free borylation of electron-rich aryl (pseudo)halides under continuous-flow photolytic conditions

(2016) Kai Chen et al.   Organic Chemistry Frontiers

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Alkenes

(2015) Wei Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Reaction of Trifluoromethylketones with Aldehydes via a Copper Difluoroenolate

(2015) Ryohei Doi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzedortho-Selective CF Bond Borylation of Polyfluoroarenes with BpinBpin

(2015) Wen-Hao Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Borylative Dearomatization of Indoles through Copper(I) Catalysis

(2015) Koji Kubota et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

(2015) Aurora López et al.   CHEMICAL COMMUNICATIONS

Making Dimethylamino a Transformable Directing Group by Nickel-Catalyzed CN Borylation

(2015) Hua Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes

(2015) Yanchuan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)-2-Alken-4-ynoates with Silylboronate

(2015) Min Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni/Cu-Catalyzed Defluoroborylation of Fluoroarenes for Diverse C–F Bond Functionalizations

(2015) Takashi Niwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Borylation of Aryl Fluorides via C–F Cleavage

(2015) Xiang-Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pinpoint-Fluorinated Phenacenes: New Synthesis and Solubility Enhancement Strategies

(2015) Kohei Fuchibe et al.   ORGANIC LETTERS

Cu(I)-Catalyzed Cross-Coupling of Terminal Alkynes with Trifluoromethyl Ketone N-Tosylhydrazones: Access to 1,1-Difluoro-1,3-enynes

(2015) Zhikun Zhang et al.   ORGANIC LETTERS

C–H and C–F Bond Activations at a Rhodium(I) Boryl Complex: Reaction Steps for the Catalytic Borylation of Fluorinated Aromatics

(2015) Sabrina I. Kalläne et al.   ORGANOMETALLICS

Rhodium-catalysed C(sp2)–C(sp2) bond formation via C–H/C–F activation

(2015) Panpan Tian et al.   Nature Communications

Copper-Catalyzed Borylative Aromatization of p-Quinone Methides: Enantioselective Synthesis of Dibenzylic Boronates

(2015) Carlos Jarava-Barrera et al.   ACS Catalysis

Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

(2014) Theresia Ahrens et al.   CHEMICAL REVIEWS

A Mild Ni/Cu-Catalyzed Silylation via C–O Cleavage

(2014) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Borylation of α-Alkoxy Allenes with Bis(pinacolato)diboron: Efficient Synthesis of 2-Boryl 1,3-Butadienes

(2013) Kazuhiko Semba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-CatalyzedOrtho-Selective CF Activation of Polyfluoroarenes with Triethylsilane: A Facile Access to Partially Fluorinated Aromatics

(2013) Zhao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of α-Tri- and α-Tetrasubstituted Allylsilanes by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Silylboronates

(2013) Momotaro Takeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselective and Stereospecific Copper-Catalyzed Aminoboration of Styrenes with Bis(pinacolato)diboron and O-Benzoyl-N,N-dialkylhydroxylamines

(2013) Naoki Matsuda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed gem-Difluoroolefination of Diazo Compounds with TMSCF3 via C–F Bond Cleavage

(2013) Mingyou Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(I)–NHC Catalyzed Asymmetric Silyl Transfer to Unsaturated Lactams and Amides

(2013) Vittorio Pace et al.   ORGANIC LETTERS

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

(2011) Eric Clot et al.   ACCOUNTS OF CHEMICAL RESEARCH

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

The Use of Fluoride as a Leaving Group: SN2′ Displacement of a CF Bond on 3,3-Difluoropropenes with Organolithium Reagents To Give Direct Access to Monofluoroalkenes

(2011) Maxime Bergeron et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic approaches to monofluoroalkenes

(2011) Grégory Landelle et al.   CHEMICAL SOCIETY REVIEWS

Synthetic Methods for Fluorinated Olefins

(2011) Hikaru Yanai et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Reactions of fluoroalk-1-en-1-yltrifluoroborate and perfluoroalk-1-yn-1-yltrifluoroborate salts and selected hydrocarbon analogues with hydrogen fluoride and with halogenating agents in aHF and in basic solvents

(2011) Vadim V. Bardin et al.   JOURNAL OF FLUORINE CHEMISTRY

Acid-catalyzed reactions of (3-(naphthalen-2-yl)-2,2-bis(trimethylsilyl)oxiran. A new synthesis of functional-group-substituted vinylsilanes

(2011) Kazem D. Safa et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Palladium-Catalyzed Hydrometalation and Bismetalation of Biphenylene

(2011) Takanori Matsuda et al.   ORGANOMETALLICS

Reactions of Perfluorinated Alkenyl-, Alkynyl-, Alkyltrifluoroborates, and Selected Hydrocarbon Analogues with the Halogenating Agents Hal2 (Hal = F, Cl, Br), “BrF” (BrF3-Br2 1:1), and ICl

(2011) Vadim V. Bardin et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

A Highly Reactive Rhodium(I)-Boryl Complex as a Useful Tool for CH Bond Activation and Catalytic CF Bond Borylation

(2010) Michael Teltewskoi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyanation of Arenes via Iridium-Catalyzed Borylation

(2010) Carl W. Liskey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Stereoselective Synthesis of Monofluoroalkenes from α-Fluorosulfoximines and Nitrones

(2009) Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene

(2009) Thomas Braun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluoroalkene modification of mercaptoacetamide-based histone deacetylase inhibitors

(2009) Satoshi Osada et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Functional Analysis of an Aspartate-Based Epoxidation Catalyst with Amide-to-Alkene Peptidomimetic Catalyst Analogues

(2008) Charles E. Jakobsche et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Convenient Method for the Synthesis of (Z)-α-Fluoroacrylates: Lewis Base-catalyzed Carbonyl Fluoroolefination Using Fluoro(trimethylsilyl)ketene Ethyl Trimethylsilyl Acetal

(2008) Makoto Michida et al.   CHEMISTRY LETTERS

Highly Stereoselective Synthesis ofcis-Alkenyl Pinacolboronates and Potassiumcis-Alkenyltrifluoroborates via a Hydroboration/ Protodeboronation Approach

(2008) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY