Synthesis of (Poly)fluorobiphenyls through Metal-catalyzed CH Bond Activation/Arylation of (Poly)fluorobenzene Derivatives

Cross-Coupling of Heteroarenes by CH Functionalization: Recent Progress towards Direct Arylation and Heteroarylation Reactions Involving Heteroarenes Containing One Heteroatom

(2014) Renzo Rossi et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct (Hetero)Arylation: A New Tool for Polymer Chemists

(2013) Lauren G. Mercier et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Desulfitative Direct CH Arylation of Electron-Deficient Polyfluoroarenes with Sodium Arenesulfinates

(2013) Tao Miao et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct CH bond Arylation in Water Promoted by (O,O)- and (O,N)-Chelate Ruthenium(II) Catalysts

(2013) Keisham S. Singh et al.   ChemCatChem

Access to Alternative Regioisomers for Palladium-Catalysed Direct Arylations of (Benzo)thiophenes

(2013) Kedong Yuan et al.   ChemCatChem

Superhydrophobic perfluorinated metal–organic frameworks

(2013) Teng-Hao Chen et al.   CHEMICAL COMMUNICATIONS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

sp2 C–H bond activation in water and catalytic cross-coupling reactions

(2013) Bin Li et al.   CHEMICAL SOCIETY REVIEWS

Mild Copper-Mediated Direct Oxidative Cross-Coupling of 1,3,4-Oxadiazoles with Polyfluoroarenes by Using Dioxygen as Oxidant

(2013) Liang-Hua Zou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly fluorescent complexes with gold, palladium or platinum linked to perylene through a tetrafluorophenyl group

(2013) Sergio Lentijo et al.   DALTON TRANSACTIONS

Direct functionalization of unactivated C–H bonds catalyzed by group 3–5 metal alkyl complexes

(2013) Hayato Tsurugi et al.   DALTON TRANSACTIONS

Influence of 1,3-Difluorobenzene Substituents for Palladium-Catalyzed Direct Arylations

(2013) Tao Yan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

tBu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complexes as Precatalyst for Pd-Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes by a C-H Activation Strategy

(2013) Hong-Hai Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Preparation of fluorinated biaryls through direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates

(2013) Xin Fang et al.   JOURNAL OF FLUORINE CHEMISTRY

Synthesis of Heteroarylated Polyfluorobiphenyls via Palladium-Catalyzed Sequential sp2 C–H Bonds Functionalizations

(2013) Tao Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Controllable Direct Arylation: Fast Route to Symmetrical and Unsymmetrical 4,7-Diaryl-5,6-difluoro-2,1,3-benzothiadiazole Derivatives for Organic Optoelectronic Materials

(2013) Junxiang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arene–Metal π-Complexation as a Traceless Reactivity Enhancer for C–H Arylation

(2013) Paolo Ricci et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Ortho-Allylation of Aromatic Carboxamides with Allyl Ethers

(2013) Sobi Asako et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Efficient Catalytic System for Polycondensation of 2,7-Dibromo-9,9-dioctylfluorene and 1,2,4,5-Tetrafluorobenzene via Direct Arylation

(2013) Masayuki Wakioka et al.   MACROMOLECULES

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Thioether-Promoted Direct Olefination of Polyfluoroarenes Catalyzed by Palladium

(2013) Cai-Zhi Wu et al.   ORGANIC LETTERS

Direct ortho-Arylation of ortho-Substituted Benzoic Acids: Overriding Pd-Catalyzed Protodecarboxylation

(2013) Carlos Arroniz et al.   ORGANIC LETTERS

Visible-Light Photoredox in Homolytic Aromatic Substitution: Direct Arylation of Arenes with Aryl Halides

(2013) Yannan Cheng et al.   ORGANIC LETTERS

Copper-catalyzed cross-coupling of arenediazonium tetrafluoroborates with polyfluoroarenes

(2013) Xingyi Zhu et al.   TETRAHEDRON LETTERS

Direct C-arylation of polyfluoroarenes with diaryliodonium salts via Pd(OAc)2-catalysis

(2013) Fenglou Guo et al.   RSC Advances

Fluorinated Porous Organic Polymers via Direct C–H Arylation Polycondensation

(2013) De-Peng Liu et al.   ACS Macro Letters

Organometallic Approaches for Direct Modification of Peripheral CH Bonds in Porphyrin Cores

(2013) Hideki Yorimitsu et al.   Asian Journal of Organic Chemistry

Rhodium(III) and Hexabromobenzene-A Catalyst System for the Cross-Dehydrogenative Coupling of Simple Arenes and Heterocycles with Arenes Bearing Directing Groups

(2012) Joanna Wencel-Delord et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of 4-polyfluoroaryl pyrrolo[1,2-a]quinolines via C–H bond activation

(2012) Shengqing Ye et al.   CHEMICAL COMMUNICATIONS

Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance

(2012) Ya-Nong Wang et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed direct arylation of benzoxazoles with unactivated simple arenes

(2012) Ge Wu et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Photoredox functionalization of C–H bonds adjacent to a nitrogen atom

(2012) Lei Shi et al.   CHEMICAL SOCIETY REVIEWS

CH Activation: A Complementary Tool in the Total Synthesis of Complex Natural Products

(2012) David Y.-K. Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper- and Phosphine-Ligand-Free Palladium-Catalyzed Direct Allylation of Electron-Deficient Polyfluoroarenes with Allylic Chlorides

(2012) Yan-Bo Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Origins of regioselectivity of the palladium-catalyzed (aromatic)CH bond metalation–deprotonation

(2012) Serge I. Gorelsky   COORDINATION CHEMISTRY REVIEWS

Copper-Catalyzed Direct Thiolation of Pentafluorobenzene with Diaryl Disulfides or Aryl Thiols by C-H and C-F Bond Activation

(2012) Chuanming Yu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Phosphine-Free Palladium-Catalyzed Direct Arylation of Imidazo[1,2-a]pyridines with Aryl Bromides at Low Catalyst Loading

(2012) Hai Yan Fu et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Direct Arylation of Polyfluoroarenes on Water under Mild Conditions Using PPh3 Ligand

(2012) Fei Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Desulfitative Arylation by C–O Bond Cleavage of Aryl Triflates with Sodium Arylsulfinates

(2012) Chao Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of π-Conjugated Polymers Containing Fluorinated Arylene Units via Direct Arylation: Efficient Synthetic Method of Materials for OLEDs

(2012) Wei Lu et al.   MACROMOLECULES

Scope of direct arylation of fluorinated aromatics with aryl sulfonates

(2012) Joyce Wei Wei Chang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A General Method for the Enantioselective Synthesis of α-Chiral Heterocycles

(2012) Phong Q. Le et al.   ORGANIC LETTERS

Copper-Catalyzed Dehydrogenative Cross-Coupling of Benzothiazoles with Thiazoles and Polyfluoroarene

(2012) Shilu Fan et al.   ORGANIC LETTERS

A Concise Access to (Polyfluoroaryl)allenes by Cu-Catalyzed Direct Coupling with Propargyl Phosphates

(2012) Akihiro Nakatani et al.   ORGANIC LETTERS

Ruthenium-Catalyzed C–H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

A C–H Borylation Approach to Suzuki–Miyaura Coupling of Typically Unstable 2–Heteroaryl and Polyfluorophenyl Boronates

(2012) Daniel W. Robbins et al.   ORGANIC LETTERS

Reactivity and Regioselectivity of Palladium-Catalyzed Direct Arylation in Noncooperative and Cooperative Processes

(2012) Serge I. Gorelsky   ORGANOMETALLICS

Pyrazolin-5-ylidene Palladium(II) Complexes: Synthesis, Characterization, and Application in the Direct Arylation of Pentafluorobenzene

(2012) Jan C. Bernhammer et al.   ORGANOMETALLICS

Regioselective C–S bond formation accomplished by copper-catalyzed regioselective C–F substitution of perfluoroarenes with aryl thioacetates or benzyl thioacetate

(2012) Qizhong Zhou et al.   TETRAHEDRON

A highly efficient palladium-catalyzed desulfitative arylation of azoles with sodium arylsulfinates

(2012) Min Wang et al.   TETRAHEDRON

Challenges in C–C bond formation through direct transformations of sp2 C–H bonds

(2012) Da-Gang Yu et al.   TETRAHEDRON

Ruthenium-catalyzed direct arylation of C–H bonds in aromatic amides containing a bidentate directing group: significant electronic effects on arylation

(2012) Yoshinori Aihara et al.   Chemical Science

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Catalytic Regioselective Oxidative Coupling of Furan-2-Carbonyls with Simple Arenes

(2012) Nur Asyikin Binte Juwaini et al.   ACS Catalysis

Palladium-catalyzed direct arylation of polyfluoroarenes with aryl tosylates and mesylates

(2012) Dong Sheng Lee et al.   RSC Advances

C–H activation: making diketopyrrolopyrrole derivatives easily accessible

(2012) Shi-Yong Liu et al.   Journal of Materials Chemistry A

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Stereospecific Copper-Catalyzed CH Allylation of Electron-Deficient Arenes with Allyl Phosphates

(2011) Tomoyuki Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylic Acids as Traceless Directing Groups for Formal meta-Selective Direct Arylation

(2011) Josep Cornella et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Arylation of 6-Phenylpurine and 6-Arylpurine Nucleosides by Ruthenium-Catalyzed CH Bond Activation

(2011) Mahesh K. Lakshman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Palladium-Catalyzed Intermolecular Allylation of Highly Electron-Deficient Polyfluoroarenes

(2011) Shilu Fan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series

(2011) Cécile Verrier et al.   Beilstein Journal of Organic Chemistry

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Pd-catalyzed Highly Regio- and Stereocontrolled Direct Alkenylation of Electron-deficient Polyfluoroarenes

(2011) Fei Chen et al.   CHEMISTRY LETTERS

Aryl−Perfluoroaryl Substituted Tetracene: Induction of Face-to-Face π−π Stacking and Enhancement of Charge Carrier Properties

(2011) Toshihiro Okamoto et al.   CHEMISTRY OF MATERIALS

The Catalytic Ability of Various Transition Metals in the Direct Functionalization of Aromatic CH Bonds

(2011) Hu Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Desulfitative CH Arylation of Heteroarenes with Sodium Sulfinates

(2011) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Desulfitative Heck-Type Reaction of Aryl Sulfinic Acids with Alkenes

(2011) Guan-Wu Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Greener solvents for ruthenium and palladium-catalysed aromatic C–H bond functionalisation

(2011) Cedric Fischmeister et al.   GREEN CHEMISTRY

Synthesis of Angiotensin II Receptor Blockers by Means of a Catalytic System for C–H Activation

(2011) Masahiko Seki et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd/PR3-Catalyzed Cross-Coupling of Aromatic Carboxylic Acids with Electron-Deficient Polyfluoroarenes via Combination of Decarboxylation with sp2C−H Cleavage

(2011) Huaiqing Zhao et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium(II)-Catalyzed Direct Alkenylation and Arylation of Arenes: Removable 2-Pyridylsulfinyl Group Assisted C–H Bond Activation

(2011) Ming Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

Assessment of the Intermediacy of Arylpalladium Carboxylate Complexes in the Direct Arylation of Benzene: Evidence for C−H Bond Cleavage by “Ligandless” Species

(2011) Yichen Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General Method for Copper-Catalyzed Arene Cross-Dimerization

(2011) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed, Room-Temperature Addition of Aromatic Imines to Alkynes via Directed C–H Bond Activation

(2011) Pin-Sheng Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polycondensation of Dibromofluorene Analogues with Tetrafluorobenzene via Direct Arylation

(2011) Wei Lu et al.   MACROMOLECULES

Palladium-catalyzed desulfitative C–H arylation of azoles with sodium sulfinates

(2011) Ru Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of 2-(Polyfluoroaryl)benzofurans via a Copper(I)-Catalyzed Reaction of 2-(2,2-Dibromovinyl)phenol with Polyfluoroarene

(2011) Shengqing Ye et al.   ORGANIC LETTERS

Copper-Catalyzed Direct Amination of Electron-Deficient Arenes with Hydroxylamines

(2011) Naoki Matsuda et al.   ORGANIC LETTERS

Pd-Catalyzed Direct Cross-Coupling of Electron-Deficient Polyfluoroarenes with Heteroaromatic Tosylates

(2011) Shilu Fan et al.   ORGANIC LETTERS

Pd-Catalyzed Olefination of Perfluoroarenes with Allyl Esters

(2011) Zejiang Li et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Direct C–H Bond Arylations of Heteroarenes

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Hydrofluoroarylation of Alkynes with Ni Catalysts. C–H Activation via Ligand-to-Ligand Hydrogen Transfer, an Alternative to Oxidative Addition

(2011) Julie Guihaumé et al.   ORGANOMETALLICS

1,2,3-Triazolin-5-ylidenes: Synthesis of Hetero-bis(carbene) Pd(II) Complexes, Determination of Donor Strengths, and Catalysis

(2011) Dan Yuan et al.   ORGANOMETALLICS

Palladium-Catalyzed Aerobic Dehydrogenative Cross-Coupling of Polyfluoroarenes with Thiophenes: Facile Access to Polyfluoroarene–Thiophene Structure

(2011) Chun-Yang He et al.   ORGANOMETALLICS

Palladium-catalyzed direct C–H arylation of unactivated arenes with aryl Halides

(2011) WenKun Hong et al.   TETRAHEDRON LETTERS

Pd(OAc)2-catalyzed cross-coupling of polyfluoroarenes with simple aromatics in imidazolium ionic liquids (ILs) without oxidant and additive and with recycling/reuse of the IL

(2011) Rajesh G. Kalkhambkar et al.   TETRAHEDRON LETTERS

Challenge and progress: palladium-catalyzed sp3 C–H activation

(2011) Hu Li et al.   Catalysis Science & Technology

Copper-Catalyzed Intermolecular Amination of Acidic Aryl CH Bonds with Primary Aromatic Amines

(2010) Huaiqing Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct Cross-Coupling of CH Bonds with Grignard Reagents through Cobalt Catalysis

(2010) Bin Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Pd-catalyzed benzylation of highly electron-deficient perfluoroarenes

(2010) Shilu Fan et al.   CHEMICAL COMMUNICATIONS

Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation

(2010) Chang-Liang Sun et al.   CHEMICAL COMMUNICATIONS

Direct arylations of electron-deficient (hetero)arenes with aryl or alkenyl tosylates and mesylates

(2010) Lutz Ackermann et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

Organic Reactions Catalyzed by Rhenium Carbonyl Complexes

(2010) Yoichiro Kuninobu et al.   CHEMICAL REVIEWS

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Recyclable Solid Ruthenium Catalysts for the Direct Arylation of Aromatic CH Bonds

(2010) Hiroki Miura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrofluoroarylation of alkynes with fluoroarenes

(2010) Kyalo Stephen Kanyiva et al.   DALTON TRANSACTIONS

Predictable and Site-Selective Functionalization of Poly(hetero)arene Compounds by Palladium Catalysis

(2010) David Lapointe et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(OAc)2Catalyzed Olefination of Highly Electron-Deficient Perfluoroarenes

(2010) Xingang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Oxidative Cross-Coupling of Perfluoroarenes with Aromatic Heterocycles

(2010) Chun-Yang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Umpolung Direct Arylation Reactions: Facile Process Requiring Only Catalytic Palladium and Substoichiometric Amount of Silver Salts

(2010) James J. Mousseau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism

(2010) Keary M. Engle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(I)-Catalyzed Olefin Hydroarylation with Electron-Deficient Perfluoroarenes

(2010) Zhong-Ming Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Direct Alkynylation of Electron-Deficient Polyfluoroarenes with Terminal Alkynes Using O2as an Oxidant

(2010) Ye Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(OAc)2-Catalyzed Oxidative C−H/C−H Cross-Coupling of Electron-Deficient Polyfluoroarenes with Simple Arenes

(2010) Ye Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible light photocatalysis as a greener approach to photochemical synthesis

(2010) Tehshik P. Yoon et al.   Nature Chemistry

Room-Temperature Direct Arylation of Polyfluorinated Arenes under Biphasic Conditions

(2010) Olivier René et al.   ORGANIC LETTERS

Pd-Catalyzed Decarboxylative Arylation of Thiazole, Benzoxazole, and Polyfluorobenzene with Substituted Benzoic Acids

(2010) Kai Xie et al.   ORGANIC LETTERS

Palladium-Catalyzed Cross-Coupling of Polyfluoroarenes with Simple Arenes

(2010) Hu Li et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Regioselective Arylation and Vinylation of Carboxylic Acids

(2010) Tetsuya Satoh et al.   SYNTHESIS-STUTTGART

Transition-Metal-Catalyzed Oxidative Heck Reactions

(2010) Babak Karimi et al.   SYNTHESIS-STUTTGART

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Regioselective C-2 or C-5 Direct Arylation of Pyrroles with Aryl Bromides using a Ligand-Free Palladium Catalyst

(2009) Julien Roger et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition Metal-Catalysed, Direct and Site-Selective N1-, C2- or C3-Arylation of the Indole Nucleus: 20 Years of Improvements

(2009) Lionel Joucla et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox Catalysis with Visible Light

(2009) Kirsten Zeitler   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation

(2009) Julien Roger et al.   ChemCatChem

Copper-catalyzed arene C–H bond cross-coupling

(2009) Hien-Quang Do et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides

(2009) Fabio Bellina et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

Low catalyst loading ligand-free palladium-catalyzed direct arylation of furans: an economically and environmentally attractive access to 5-arylfurans

(2009) Jia Jia Dong et al.   GREEN CHEMISTRY

Ligand-Free Palladium-Catalyzed Direct Arylation of Thiazoles at Low Catalyst Loadings

(2009) Julien Roger et al.   JOURNAL OF ORGANIC CHEMISTRY

Energy- and Electron-Transfer Processes in Corrole−Perylenebisimide−Triphenylamine Array

(2009) Mariusz Tasior et al.   Journal of Physical Chemistry C

Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Phenol Esters

(2009) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cp2Ni-KOt-Bu-BEt3(or PPh3) Catalyst System for Direct C−H Arylation of Benzene, Naphthalene, and Pyridine

(2009) Osamu Kobayashi et al.   ORGANIC LETTERS

Nickel-Catalyzed Biaryl Coupling of Heteroarenes and Aryl Halides/Triflates

(2009) Jérôme Canivet et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct Arylation of Electron-Deficient Polyfluoroarenes with Arylboronic Acids

(2009) Ye Wei et al.   ORGANIC LETTERS

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

(2009) Fabio Bellina et al.   TETRAHEDRON

Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery

(2008) Young Jun Park et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Domino Iron Catalysis: Direct Aryl-Alkyl Cross-Coupling

(2008) Waldemar Maximilian Czaplik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed CH Arylation and Dehydrogenative Homocoupling of Heteroaromatic Compounds and Application to the Design of Advanced Organic Materials

(2008) Atsunori Mori et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Development and Application of Effective Protocols for the Synthesis of Arylheteroarenes and Biheteroaryls, Including Bioactive Derivatives, by Highly Regioselective Transition Metal-Catalyzed Direct Intermolecular Arylation Reactions of Five-Membered Heteroarenes with (Hetero)aryl Halides

(2008) Fabio Bellina et al.   CURRENT ORGANIC CHEMISTRY

Nickel-Catalyzed Alkenylation and Alkylation of Fluoroarenes via Activation of C−H Bond over C−F Bond

(2008) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Arylation and Alkenylation of Polyfluoroarene C−H Bonds

(2008) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General Method for Copper-Catalyzed Arylation of Arene C−H Bonds

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Iron-Catalyzed Direct Arylation through Directed C−H Bond Activation

(2008) Jakob Norinder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism

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Thin-film transistors based on liquid-crystalline tetrafluorophenylter thiophene derivatives: thin-film structure and carrier transport

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Potassiumt-Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes

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Meso-Disubstituted Anthracenes with Fluorine-Containing Groups: Synthesis, Light-Emitting Characteristics, and Photostability

(2008) Yoshio Matsubara et al.   ORGANIC LETTERS

Twofold C−H Functionalization: Palladium-CatalyzedOrthoArylation of Anilides

(2008) Gordon Brasche et al.   ORGANIC LETTERS

Functionalized Dibenzo[g,p]chrysenes: Variable Photophysical and Electronic Properties and Liquid−Crystal Chemistry

(2008) Rupsha Chaudhuri et al.   ORGANIC LETTERS

Recent Advances in Direct Arylation via Palladium-Catalyzed Aromatic C-H Activation

(2008) Zhang-Jie Shi et al.   SYNLETT

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART

Intramolecular direct arylation in the synthesis of fluorinated carbazoles

(2008) Robin B. Bedford et al.   TETRAHEDRON

Mild and efficient palladium-catalyzed intramolecular direct arylation reactions

(2008) Marc Lafrance et al.   TETRAHEDRON

Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components

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