Direct functionalization of unactivated C–H bonds catalyzed by group 3–5 metal alkyl complexes

Yttrium-Catalyzed Addition of Benzylic CH Bonds of Alkyl Pyridines to Olefins

(2013) Bing-Tao Guan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

σ-Bond Metathesis: A 30-Year Retrospective

(2013) Rory Waterman   ORGANOMETALLICS

Aminopyridinato Titanium Catalysts for the Hydroaminoalkylation of Alkenes and Styrenes

(2012) Jaika Dörfler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective CH Alkylation of Anisoles with Olefins Catalyzed by Cationic Half-Sandwich Rare Earth Alkyl Complexes

(2012) Juzo Oyamada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

CH Activation: A Complementary Tool in the Total Synthesis of Complex Natural Products

(2012) David Y.-K. Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct α-Functionalization of Saturated Cyclic Amines

(2012) Emily A. Mitchell et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Mechanism of Hydroaminoalkylation Catalyzed by Group 5 Metal Binaphtholate Complexes

(2012) Alexander L. Reznichenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigation on Scandium-Catalyzed C–H Addition of Pyridines to Olefins

(2012) Gen Luo et al.   ORGANOMETALLICS

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Scandium-Catalyzed Silylation of Aromatic CH Bonds

(2011) Juzo Oyamada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Mechanism of the Titanium-Catalyzed Hydroaminoalkylation of Alkenes

(2011) Insa Prochnow et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Synthesis and catalytic activity of group 5 metal amides with chiral biaryldiamine-based ligands

(2011) Furen Zhang et al.   DALTON TRANSACTIONS

Rare-Earth-Catalyzed C–H Bond Addition of Pyridines to Olefins

(2011) Bing-Tao Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

End-Functionalized Polymerization of 2-Vinylpyridine through Initial C–H Bond Activation ofN-Heteroaromatics and Internal Alkynes by Yttrium Ene–Diamido Complexes

(2011) Hiroshi Kaneko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electronic Selectivity Tuning in Titanium(III)-Catalyzed Acetylene Cross-Dimerization Reactions

(2011) Gennady V. Oshovsky et al.   ORGANOMETALLICS

Atom-Economical Route to Substituted Pyridines via a Scandium Imide

(2011) Benjamin F. Wicker et al.   ORGANOMETALLICS

Group 5 Metal Binaphtholate Complexes for Catalytic Asymmetric Hydroaminoalkylation and Hydroamination/Cyclization

(2011) Alexander L. Reznichenko et al.   ORGANOMETALLICS

[Ind2TiMe2]: A Catalyst for the Hydroaminomethylation of Alkenes and Styrenes

(2010) Raphael Kubiak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective hydroaminoalkylation of secondary amines catalyzed by group 5 metal amides with chiral biarylamidate ligands

(2010) Guofu Zi et al.   CHEMICAL COMMUNICATIONS

Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis

(2010) Petr Sehnal et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Organic Reactions Catalyzed by Rhenium Carbonyl Complexes

(2010) Yoichiro Kuninobu et al.   CHEMICAL REVIEWS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidant-Free Direct Coupling of Internal Alkynes and 2-Alkylpyridine via Double C−H Activations by Alkylhafnium Complexes

(2010) Hayato Tsurugi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions

(2010) Patrick Eisenberger et al.   PURE AND APPLIED CHEMISTRY

Tantalum-Amidate Complexes for the Hydroaminoalkylation of Secondary Amines: Enhanced Substrate Scope and Enantioselective Chiral Amine Synthesis

(2009) Patrick Eisenberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hydroaminoalkylation

(2009) Peter W. Roesky   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tetrabenzyltitanium: An Improved Catalyst for the Activation of sp3CH Bonds Adjacent to Nitrogen Atoms

(2009) Insa Prochnow et al.   ChemCatChem

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Organopalladium(iv) chemistry

(2009) Ling-Min Xu et al.   CHEMICAL SOCIETY REVIEWS

Selective C−H Activation α to Primary Amines. Bridging Metallaaziridines for Catalytic, Intramolecular α-Alkylation

(2009) Jason A. Bexrud et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Reactive Metal−Nitrogen Bond Induced C−H Bond Activation and Azametallacycle Formation

(2009) Tarun K. Panda et al.   ORGANOMETALLICS

Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes

(2008) Wen-Xiong Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Neutral Group-IV Metal Catalysts for the Intramolecular Hydroamination of Alkenes

(2008) Carsten Müller et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Hydroaminoalkylation of Unactivated Olefins with Dialkylamines

(2008) Seth B. Herzon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DFT Investigation of the Catalytic Hydromethylation of Olefins by Scandocenes. 2. Influence of the Ansa Ligand on Propene and Isobutene Hydromethylation

(2008) Noémi Barros et al.   ORGANOMETALLICS

Mechanism of the Reaction of Alkynes with a “Constrained Geometry” Zirconaaziridine. PMe3Dissociates More Rapidly from the Constrained Geometry Complex than from its Cp2Analogue

(2008) Kathleen E. Kristian et al.   ORGANOMETALLICS