tBu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complexes as Precatalyst for Pd-Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes by a C-H Activation Strategy

A Highly Efficient Catalytic System for Polycondensation of 2,7-Dibromo-9,9-dioctylfluorene and 1,2,4,5-Tetrafluorobenzene via Direct Arylation

(2013) Masayuki Wakioka et al.   MACROMOLECULES

Pd-Catalyzed Direct Arylation of Polyfluoroarenes on Water under Mild Conditions Using PPh3 Ligand

(2012) Fei Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies

(2012) Brett VanVeller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope of the Palladium-Catalyzed Aryl Borylation Utilizing Bis-Boronic Acid

(2012) Gary A. Molander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of π-Conjugated Polymers Containing Fluorinated Arylene Units via Direct Arylation: Efficient Synthetic Method of Materials for OLEDs

(2012) Wei Lu et al.   MACROMOLECULES

Pyrazolin-5-ylidene Palladium(II) Complexes: Synthesis, Characterization, and Application in the Direct Arylation of Pentafluorobenzene

(2012) Jan C. Bernhammer et al.   ORGANOMETALLICS

Challenges in C–C bond formation through direct transformations of sp2 C–H bonds

(2012) Da-Gang Yu et al.   TETRAHEDRON

t-Bu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complex as a Precatalyst for the Suzuki Cross-Coupling Polymerization of Aryl Dibromides with Aryldiboronic Acids

(2012) Hong-Hai Zhang et al.   ACS Macro Letters

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes

(2011) Serge I. Gorelsky et al.   JOURNAL OF ORGANIC CHEMISTRY

Concise Total Synthesis and Stereochemical Revision of (+)-Naseseazines A and B: Regioselective Arylative Dimerization of Diketopiperazine Alkaloids

(2011) Justin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversed-Polarity Synthesis of Diaryl Ketones via Palladium-Catalyzed Cross-Coupling of Acylsilanes

(2011) Jason R. Schmink et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polycondensation of Dibromofluorene Analogues with Tetrafluorobenzene via Direct Arylation

(2011) Wei Lu et al.   MACROMOLECULES

Suzuki–Miyaura Cross-Coupling of Heteroaryl Halides and Arylboronic Acids in Continuous Flow

(2011) Timothy Noël et al.   ORGANIC LETTERS

1,2,3-Triazolin-5-ylidenes: Synthesis of Hetero-bis(carbene) Pd(II) Complexes, Determination of Donor Strengths, and Catalysis

(2011) Dan Yuan et al.   ORGANOMETALLICS

Suzuki–Miyaura cross-coupling reaction on copper-trans-A2B corroles with excellent functional group tolerance

(2011) Michael König et al.   TETRAHEDRON

Use of precatalysts greatly facilitate palladium-catalyzed alkynylations in batch and continuous-flow conditions

(2011) Wei Shu et al.   Chemical Science

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Palladium-Catalyzed C−H Functionalization of Heteroarenes with Aryl Bromides and Chlorides

(2010) Shunsuke Tamba et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(OAc)2-Catalyzed Oxidative C−H/C−H Cross-Coupling of Electron-Deficient Polyfluoroarenes with Simple Arenes

(2010) Ye Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids

(2010) Tom Kinzel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature Direct Arylation of Polyfluorinated Arenes under Biphasic Conditions

(2010) Olivier René et al.   ORGANIC LETTERS

Palladium-Catalyzed Cross-Coupling of Polyfluoroarenes with Simple Arenes

(2010) Hu Li et al.   ORGANIC LETTERS

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Phosphine-Free, Palladium-Catalyzed Arylation of Heterocycles through CH Bond Activation with Pivalic Acid as a Cocatalyst

(2009) Dongbing Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Direct Arylation of Electron-Deficient Polyfluoroarenes with Arylboronic Acids

(2009) Ye Wei et al.   ORGANIC LETTERS

The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)3and PCy3as Ligands

(2008) Gregory C. Fu   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Arylation and Alkenylation of Polyfluoroarene C−H Bonds

(2008) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General Method for Copper-Catalyzed Arylation of Arene C−H Bonds

(2008) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Class of Easily Activated Palladium Precatalysts for Facile C−N Cross-Coupling Reactions and the Low Temperature Oxidative Addition of Aryl Chlorides

(2008) Mark R. Biscoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassium Organotrifluoroborates:  New Perspectives in Organic Synthesis

(2007) Sylvain Darses et al.   CHEMICAL REVIEWS