Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

Palladium-Catalyzed Dehydrogenative Cross-Couplings of Benzazoles with Azoles

(2011) Wei Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Intramolecular Oxidative C−H Coupling for Medium-Ring Synthesis

(2011) Didier G. Pintori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Intermolecular Direct Biaryl Coupling

(2011) Masanori Kitahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Alkynylation of Heterocycles with Terminal Alkynes under Air Conditions

(2011) Seok Hwan Kim et al.   ORGANIC LETTERS

Cobalt- and Manganese-Catalyzed Direct Amination of Azoles under Mild Reaction Conditions and the Mechanistic Details

(2010) Ji Young Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formal Inverse Sonogashira Reaction: Direct Alkynylation of Arenes and Heterocycles with Alkynyl Halides

(2010) Alexander S. Dudnik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed direct oxidative Heck–Cassar–Sonogashira type alkynylation of indoles with alkynes under oxygen

(2010) Luo Yang et al.   CHEMICAL COMMUNICATIONS

Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation

(2010) Chang-Liang Sun et al.   CHEMICAL COMMUNICATIONS

Oxidative dimerization of N-protected and free indole derivatives toward 3,3′-biindoles via Pd-catalyzed direct C–H transformations

(2010) Yang Li et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Copper-Mediated Direct Cross-Coupling of 1,3,4-Oxadiazoles and Oxazoles with Terminal Alkynes

(2010) Masanori Kitahara et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Alkenylation of 1,2,3-Trizoles with Terminal Conjugated Alkenes by Direct C-H Bond Functionalization

(2010) Huanfeng Jiang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Direct Oxidative Alkenylation of Azoles

(2010) Mitsuru Miyasaka et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Oxidative Cross-Coupling of Perfluoroarenes with Aromatic Heterocycles

(2010) Chun-Yang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative C−H Arylation of 2-Arylpyridine Derivatives via Decarbonylation of Aromatic Aldehydes

(2010) Qi Shuai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed Oxidative C−H/C−H Cross-Coupling of Heteroarenes

(2010) Peihua Xi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Entry of Amination Reagents for Heteroaromatic C−H Bonds: Copper-Catalyzed Direct Amination of Azoles with Chloroamines at Room Temperature

(2010) Tsuyoshi Kawano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel- and Copper-Catalyzed Direct Alkynylation of Azoles and Polyfluoroarenes with Terminal Alkynes under O2or Atmospheric Conditions

(2010) Naoto Matsuyama et al.   ORGANIC LETTERS

Highly Efficient and Versatile Pd-Catalyzed Direct Alkynylation of Both Azoles and Azolines

(2010) Seok Hwan Kim et al.   ORGANIC LETTERS

Nickel, Manganese, Cobalt, and Iron-Catalyzed Deprotonative Arene Dimerization

(2010) Thanh Truong et al.   ORGANIC LETTERS

Palladium-Catalyzed Dehydrogenative Direct Arylations of 1,2,3-Triazoles

(2010) Lutz Ackermann et al.   ORGANIC LETTERS

Copper-Catalyzed Oxidative Amination of Benzoxazoles via C−H and C−N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources

(2010) Shengmei Guo et al.   ORGANIC LETTERS

Alkenylation Reactions of Heteroarenes by Transition-Metal Catalysts

(2010) Renzo Rossi et al.   SYNTHESIS-STUTTGART

Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

(2010) David S. Surry et al.   Chemical Science

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Silver-Mediated Direct Amination of Benzoxazoles: Tuning the Amino Group Source from Formamides to Parent Amines

(2009) Seung���Hwan Cho et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed Regioselective Direct C2 Alkenylation of Indoles and Pyrroles Assisted by theN-(2-Pyridyl)sulfonyl Protecting Group

(2009) Alfonso García-Rubia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper as a Powerful Catalyst in the Direct Alkynylation of Azoles

(2009) François Besselièvre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functional Oligothiophenes: Molecular Design for Multidimensional Nanoarchitectures and Their Applications†

(2009) Amaresh Mishra et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Biogenetically inspired syntheses of alkaloid natural products

(2009) Justin Kim et al.   CHEMICAL SOCIETY REVIEWS

Iron(iii) chloride in oxidative C–C coupling reactions

(2009) Abdelwareth A. O. Sarhan et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Intermolecular oxidative cross-coupling of arenes

(2009) James A. Ashenhurst   CHEMICAL SOCIETY REVIEWS

Construction of Nitrogen-Containing Heterocycles by CH Bond Functionalization

(2009) Praew Thansandote et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Catalyzed Hydroarylation Reactions of Alkynes Through Direct Functionalization of C-H Bonds: A Convenient Tool for Organic Synthesis

(2009) Tsugio Kitamura   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Regioselective Oxidative Coupling of Indoles and One-Pot Synthesis of Acetoxylated Biindolyls

(2009) Zunjun Liang et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed Amination of C−H Bonds Using Single-Electron or Two-electron Oxidants

(2009) Tian-Sheng Mei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Aromatic Glaser−Hay Reaction

(2009) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions

(2009) Junliang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intramolecular Direct Arylation of Benzoic Acids by Tandem Decarboxylation/C−H Activation

(2009) Congyang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Direct Alkynylation of Azoles with Alkynyl Bromides

(2009) Naoto Matsuyama et al.   ORGANIC LETTERS

Copper-Mediated Amidation of Heterocyclic and Aromatic C−H Bonds

(2009) Qiu Wang et al.   ORGANIC LETTERS

Direct Amination of Azoles via Catalytic C−H, N−H Coupling

(2009) Daiki Monguchi et al.   ORGANIC LETTERS

Palladium-Catalyzed Dehydrogenative Coupling of Furans with Styrenes

(2009) Chahinez Aouf et al.   ORGANIC LETTERS

Highly Regioselective Palladium-Catalyzed Oxidative Coupling of Indolizines and Vinylarenes via C−H Bond Cleavage

(2009) Yuzhu Yang et al.   ORGANIC LETTERS

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

(2009) Fabio Bellina et al.   TETRAHEDRON

Oxidative dimerization of azoles via copper(II)/silver(I)-catalyzed CH homocoupling

(2009) Daiki Monguchi et al.   TETRAHEDRON LETTERS

Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides

(2008) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Copper/Amino Acid Catalyzed Cross-Couplings of Aryl and Vinyl Halides with Nucleophiles†

(2008) Dawei Ma et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalysts for the Sonogashira Coupling-The Crownless Again Shall Be King

(2008) Herbert Plenio   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Rhazinicine by a Metal-Catalyzed CH Bond Functionalization Strategy

(2008) Elizabeth M. Beck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Method for Copper-Catalyzed Arylation of Arene C−H Bonds

(2008) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C−H Functionalization of PyridineN-Oxides: Highly Selective Alkenylation and Direct Arylation with Unactivated Arenes

(2008) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Regioselective C−H Functionalization via Decarbonylation of Acid Chlorides and C−H Bond Activation under Phosphine-Free Conditions

(2008) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

(2008) Lutz Ackermann et al.   ORGANIC LETTERS

Direct palladium-catalyzed C-3 alkynylation of indoles

(2008) Yonghong Gu et al.   TETRAHEDRON LETTERS

Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components

(2007) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION