Greener solvents for ruthenium and palladium-catalysed aromatic C–H bond functionalisation

Palladium-Catalysed Direct Arylation of Heteroaromatics Bearing Unprotected Hydroxyalkyl Functions using Aryl Bromides

(2010) Julien Roger et al.   ADVANCED SYNTHESIS & CATALYSIS

“On Water” Direct and Site-Selective Pd-Catalysed CH Arylation of (NH)-Indoles

(2010) Lionel Joucla et al.   ADVANCED SYNTHESIS & CATALYSIS

CH Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems

(2010) Percia B. Arockiam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Corrigendum: CH Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems

(2010) Percia B. Arockiam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Versatile Palladium/Triphosphane System for Direct Arylation of Heteroarenes with Chloroarenes at Low Catalyst Loading

(2010) David Roy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of π-Conjugated Polymers by Organometallic Polycondensation

(2010) Takakazu Yamamoto   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Solvent free catalytic C–H functionalisation

(2010) Robin B. Bedford et al.   CHEMICAL COMMUNICATIONS

Palladium-catalysed direct arylation of thiophenes tolerant to silyl groups

(2010) Lu Chen et al.   CHEMICAL COMMUNICATIONS

Polyphenylene-Based Materials for Organic Photovoltaics

(2010) Chen Li et al.   CHEMICAL REVIEWS

Organic Carbonates as Solvents in Synthesis and Catalysis

(2010) Benjamin Schäffner et al.   CHEMICAL REVIEWS

Water: Nature’s Reaction Enforcer—Comparative Effects for Organic Synthesis “In-Water” and “On-Water”

(2010) Richard N. Butler et al.   CHEMICAL REVIEWS

Improving Sustainability in Ene-Yne Cross-Metathesis for Transformation of Unsaturated Fatty Esters

(2010) Virginie Le Ravalec et al.   ChemSusChem

Carbonates: eco-friendly solvents for palladium-catalysed direct arylation of heteroaromatics

(2010) Jia Jia Dong et al.   GREEN CHEMISTRY

Synthesis of cyclic carbonates from epoxides and CO2

(2010) Michael North et al.   GREEN CHEMISTRY

Cu-Catalyzed N-Alkynylation of Imidazoles, Benzimidazoles, Indazoles, and Pyrazoles Using PEG as Solvent Medium

(2010) Glenn A. Burley et al.   JOURNAL OF ORGANIC CHEMISTRY

Modulating Reactivity and Diverting Selectivity in Palladium-Catalyzed Heteroaromatic Direct Arylation Through the Use of a Chloride Activating/Blocking Group

(2010) Benoît Liégault et al.   JOURNAL OF ORGANIC CHEMISTRY

Room-Temperature Direct Arylation of Polyfluorinated Arenes under Biphasic Conditions

(2010) Olivier René et al.   ORGANIC LETTERS

First Transformation of Unsaturated Fatty Esters Involving Enyne Cross-Metathesis

(2009) Virginie Le Ravalec et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium(II) Acetate Catalyst for Direct Functionalisation of sp2-CH Bonds with Aryl Chlorides and Access to Tris- Heterocyclic Molecules

(2009) Franc Požgan et al.   ADVANCED SYNTHESIS & CATALYSIS

Room Temperature CH Activation and Cross-Coupling of Aryl Ureas in Water

(2009) Takashi Nishikata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

(2009) Florian Monnier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation

(2009) Julien Roger et al.   ChemCatChem

The synthesis of organic carbonates from carbon dioxide

(2009) Toshiyasu Sakakura et al.   CHEMICAL COMMUNICATIONS

Organic Synthesis “On Water”

(2009) Arani Chanda et al.   CHEMICAL REVIEWS

More Sustainable Approaches for the Synthesis of N-Based Heterocycles

(2009) Nuno R. Candeias et al.   CHEMICAL REVIEWS

Hydrophilic Ligands and Their Application in Aqueous-Phase Metal-Catalyzed Reactions

(2009) Kevin H. Shaughnessy   CHEMICAL REVIEWS

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Green Chemistry: Principles and Practice

(2009) Paul Anastas et al.   CHEMICAL SOCIETY REVIEWS

Improved Palladium-Catalyzed Sonogashira Coupling Reactions of Aryl Chlorides

(2009) Christian Torborg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium Catalyzed Direct 3-Arylation of Benzofurans using Low Catalyst Loadings

(2009) Marina Ionita et al.   ChemSusChem

Carbonates: Ecofriendly Solvents for Palladium-Catalyzed Direct 2-Arylation of Oxazole Derivatives

(2009) Julien Roger et al.   ChemSusChem

Palladium-Catalysed Direct 3- or 4-Arylation of 2,5-Disubstituted Pyrrole Derivatives: An Economically and Environmentally Attractive Procedure

(2009) Yacoub Fall et al.   ChemSusChem

Organic carbonates as alternative solvents for asymmetric hydrogenation

(2009) Benjamin Schäffner et al.   CHIRALITY

Catalytic C–C coupling through C–H arylation of arenes or heteroarenes

(2009) Gian Paolo Chiusoli et al.   COORDINATION CHEMISTRY REVIEWS

Ligand-Free-Palladium-Catalyzed Direct 4-Arylation of Isoxazoles Using Aryl Bromides

(2009) Yacoub Fall et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Low catalyst loading ligand-free palladium-catalyzed direct arylation of furans: an economically and environmentally attractive access to 5-arylfurans

(2009) Jia Jia Dong et al.   GREEN CHEMISTRY

Ligand-less palladium-catalyzed direct 5-arylation of thiophenes at low catalyst loadings

(2009) Julien Roger et al.   GREEN CHEMISTRY

Diethyl carbonate as a solvent for ruthenium catalysed C–H bond functionalisation

(2009) Percia Arockiam et al.   GREEN CHEMISTRY

Establishment of Broadly Applicable Reaction Conditions for the Palladium-Catalyzed Direct Arylation of Heteroatom-Containing Aromatic Compounds

(2009) Benoît Liégault et al.   JOURNAL OF ORGANIC CHEMISTRY

Ligand-Free Palladium-Catalyzed Direct Arylation of Thiazoles at Low Catalyst Loadings

(2009) Julien Roger et al.   JOURNAL OF ORGANIC CHEMISTRY

C−C Bond Formation via C−H Bond Activation Under Protic Conditions: On the Role of Phosphane Ligand and Cosolvent

(2009) Marc-Olivier Simon et al.   JOURNAL OF ORGANIC CHEMISTRY

C−C Bond Formation via C−H Bond Activation Using an in Situ-Generated Ruthenium Catalyst

(2009) Rémi Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Programmed Synthesis of Tetraarylthiophenes through Sequential C−H Arylation

(2009) Shuichi Yanagisawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct palladium-catalyzed alkenylation, benzylation and alkylation of ethyl oxazole-4-carboxylate with alkenyl-, benzyl- and alkyl halides

(2009) Cécile Verrier et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-catalysed ortho-arylation of carbamate-protected phenols

(2009) Robin B. Bedford et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Direct Arylations in Polyethylene Glycol (PEG): Recyclable Palladium(0) Catalyst for C−H Bond Cleavages in the Presence of Air

(2009) Lutz Ackermann et al.   ORGANIC LETTERS

Direct Arylations of 2H-Indazoles On Water

(2009) Stephan A. Ohnmacht et al.   ORGANIC LETTERS

Phosphine-free palladium-catalysed direct 5-arylation of imidazole derivatives at low catalyst loading

(2009) Julien Roger et al.   TETRAHEDRON

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

(2009) Fabio Bellina et al.   TETRAHEDRON

Synthesis of 2,5-diaryloxazoles through van Leusen reaction and copper-mediated direct arylation

(2009) Tomoki Yoshizumi et al.   TETRAHEDRON LETTERS

Palladium-catalysed direct 3- or 4-arylation of thiophene derivatives using aryl bromides

(2009) Jia Jia Dong et al.   TETRAHEDRON LETTERS

Green process chemistry in the pharmaceutical industry

(2009) Berkeley W. Cue et al.   Green Chemistry Letters and Reviews

Palladium-Catalyzed Direct Arylations of 1,2,3-Triazoles with Aryl Chlorides using Conventional Heating

(2008) Lutz Ackermann et al.   ADVANCED SYNTHESIS & CATALYSIS

Aerobic Ligand-Free Suzuki Coupling Reaction of Aryl Chlorides Catalyzed byIn Situ Generated Palladium Nanoparticles at Room Temperature

(2008) Wei Han et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Direct C-4 Arylation of 2,5-Disubstituted Furans with Aryl Bromides

(2008) Aditya L. Gottumukkala et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions: Copper Makes a Difference

(2008) Florian Monnier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Practical Imidazole-Based Phosphine Ligands for Selective Palladium-Catalyzed Hydroxylation of Aryl Halides

(2008) Thomas Schulz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct arylations on water: synthesis of 2,5-disubstituted oxazoles balsoxin and texaline

(2008) Stephan A. Ohnmacht et al.   CHEMICAL COMMUNICATIONS

E factors, green chemistry and catalysis: an odyssey

(2008) Roger A. Sheldon   CHEMICAL COMMUNICATIONS

Dimethyl Carbonate: An Eco-Friendly Solvent in Ruthenium-Catalyzed Olefin Metathesis Transformations

(2008) Xiaowei Miao et al.   ChemSusChem

Organic Carbonates as Alternative Solvents for Palladium-Catalyzed Substitution Reactions

(2008) Benjamin Schäffner et al.   ChemSusChem

Recovery of Enlarged Olefin Metathesis Catalysts by Nanofiltration in an Eco-Friendly Solvent

(2008) Adel Keraani et al.   ChemSusChem

Ligand-Free Palladium-Catalysed Direct Arylation of Heteroaromatics Using Low Catalyst Loadings

(2008) Franc Požgan et al.   ChemSusChem

Palladium-Catalysed Direct C-H Activation/Arylation of Heteroaromatics: An Environmentally Attractive Access to Bi- or Polydentate Ligands

(2008) Fazia Derridj et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Regioselective Synthesis of 4,5-Diaryl-1-methyl-1H-imidazoles Including Highly Cytotoxic Derivatives by Pd-Catalyzed Direct C-5 Arylation of 1-Methyl-1H-imidazole with Aryl Bromides

(2008) Fabio Bellina et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Solvents from nature

(2008) István T. Horváth   GREEN CHEMISTRY

Palladium-Catalyzed Direct (Hetero)arylation of Ethyl Oxazole-4-carboxylate: An Efficient Access to (Hetero)aryloxazoles

(2008) Cécile Verrier et al.   JOURNAL OF ORGANIC CHEMISTRY

Ligandless Microwave-Assisted Pd/Cu-Catalyzed Direct Arylation of Oxazoles

(2008) François Besselièvre et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-catalyzed direct heteroarylation of chloropyridines and chloroquinolines

(2008) Fazia Derridj et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

C2, C5, and C4 AzoleN-Oxide Direct Arylation Including Room-Temperature Reactions

(2008) Louis-Charles Campeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism

(2008) Ismail Özdemir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(I)-Catalyzed Direct Arylation of Pyridines and Quinolines

(2008) Ashley M. Berman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles

(2008) Nathalie Lebrasseur et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C-2 Arylation of Alkyl 4-Thiazolecarboxylates: New Insights in Synthesis of Heterocyclic Core of Thiopeptide Antibiotics

(2008) Thibaut Martin et al.   ORGANIC LETTERS

Direct Arylation of Oxazoles at C2. A Concise Approach to Consecutively Linked Oxazoles

(2008) Emmanuel Ferrer Flegeau et al.   ORGANIC LETTERS

Palladium-Catalyzed Perarylation of 3-Thiophene- and 3-Furancarboxylic Acids Accompanied by C−H Bond Cleavage and Decarboxylation

(2008) Masaya Nakano et al.   ORGANIC LETTERS

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

(2008) Lutz Ackermann et al.   ORGANIC LETTERS

Highly selective synthesis of 4(5)-aryl-, 2,4(5)-diaryl-, and 4,5-diaryl-1H-imidazoles via Pd-catalyzed direct C-5 arylation of 1-benzyl-1H-imidazole

(2008) Fabio Bellina et al.   TETRAHEDRON

Green chemistry tools to influence a medicinal chemistry and research chemistry based organisation

(2007) Kim Alfonsi et al.   GREEN CHEMISTRY

Direct arylation of oxazole and benzoxazole with aryl or heteroaryl halides using a palladium–diphosphine catalyst

(2007) Fazia Derridj et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Microwave-Assisted Intramolecular Cyclization of Electron-Rich Heterocycle Derivatives by a Palladium-Catalyzed Coupling Reaction

(2007) Egle Beccalli et al.   SYNTHESIS-STUTTGART