Recent Advances in Nonprecious Metal Catalysis

Design and Synthesis of Tunable Chiral 2,2'‐Bipyridine Ligands: Application to the Enantioselective Nickel‐Catalyzed Reductive Arylation of Aldehydes

(2022) Shuai Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modular and Facile Access to Chiral α-Aryl Phosphates via Dual Nickel- and Photoredox-Catalyzed Reductive Cross-Coupling

(2022) Hepan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of an Operationally Simple, Scalable, and HCN-Free Transfer Hydrocyanation Protocol Using an Air-Stable Nickel Precatalyst

(2022) Julia C. Reisenbauer et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Nickel-Catalyzed Defluorinative Coupling of Aliphatic Aldehydes with Trifluoromethyl Alkenes

(2022) Jichao Xiao et al.   ACS Catalysis

Manganese‐Catalyzed Asymmetric Hydrogenation of 3H ‐Indoles

(2022) Chenguang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel/Copper‐Cocatalyzed Asymmetric Benzylation of Aldimine Esters for the Enantioselective Synthesis of α‐Quaternary Amino Acids

(2022) Youbin Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio‐ and Diastereoselective Copper‐Catalyzed Allylboration of Alkynes with Allylic gem ‐Dichlorides

(2022) Andrea Chaves‐Pouso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel‐Catalyzed Reductive C(sp 2 )−Si Coupling of Chlorohydrosilanes via Si−Cl Cleavage

(2022) Zhen‐Zhen Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel‐Catalyzed Intermolecular Asymmetric Addition of Aryl Iodides across Aldehydes

(2022) Ziqi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese‐Catalyzed Asymmetric Formal Hydroamination of Allylic Alcohols: A Remarkable Macrocyclic Ligand Effect

(2022) Faju Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt‐Catalyzed Asymmetric Alkylation of (Hetero)Arenes with Styrenes

(2022) Tao Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to 4-Trifluoromethyl Quinolines via Cu-Catalyzed Annulation Reaction of Ketone Oxime Acetates with ortho-Trifluoroacetyl Anilines under Redox-Neutral Conditions

(2022) Zhen-Hua Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Accelerated Copper-Catalyzed [3 + 2] Cycloaddition of N-Tosylcyclopropylamines with Alkynes/Alkenes

(2022) Manoj Kumar et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Asymmetric Oxidative Desymmetrization of 2-Substituted 1,2,3-Triols

(2022) Kosuke Yamamoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed C–N Cross-Coupling of 4-Chloro-1,8-naphthalimides and Bulky, Primary Alkylamines at Room Temperature

(2022) Joseph P. Tassone et al.   JOURNAL OF ORGANIC CHEMISTRY

Three-Component Coupling of Arenes, Ethylene, and Alkynes Catalyzed by a Cationic Bis(phosphine) Cobalt Complex: Intercepting Metallacyclopentenes for C–H Functionalization

(2022) William G. Whitehurst et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Regiodivergent and Enantioselective Hydrosilylation of Allenes

(2022) Jian-Lin Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Regio- and Enantioselective Hydroamination of Unactivated Alkenes Using Carbonyl Directing Groups

(2022) Changseok Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Nickel-Catalyzed Reductive Aryl/Alkenyl–Cyano Cyclization Coupling to All-Carbon Quaternary Stereocenters

(2022) Zi-Hao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Secondary β-Trifluoromethyl Alcohols via Catalytic Asymmetric Reductive Trifluoroalkylation and Diastereoselective Reduction

(2022) Bing-Bing Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoassisted Cobalt-Catalyzed Asymmetric Reductive Grignard-Type Addition of Aryl Iodides

(2022) Xuan Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Unified Approach to Decarboxylative Halogenation of (Hetero)aryl Carboxylic Acids

(2022) Tiffany Q. Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced, Copper-Catalyzed Enantioconvergent Alkylations of Anilines by Racemic Tertiary Electrophiles: Synthesis and Mechanism

(2022) Hyungdo Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-electrocatalytic Csp3–Csp3 doubly decarboxylative coupling

(2022) Benxiang Zhang et al.   NATURE

Stereocontrolled 1,3-nitrogen migration to access chiral α-amino acids

(2022) Chen-Xi Ye et al.   Nature Chemistry

Diverse Synthesis of Chiral Trifluoromethylated Alkanes via Nickel-Catalyzed Enantioconvergent Reductive Hydroalkylation of Unactivated Olefins

(2022) Wenqing Guo et al.   ORGANIC LETTERS

Nickel-Catalyzed Carbonylation of Cyclopropanol with Benzyl Bromide for Multisubstituted Cyclopentenone Synthesis

(2022) Liting Hou et al.   ORGANIC LETTERS

Nickel-Catalyzed Three-Component Alkylacylation of Alkenes Enabled by a Photoactive Electron Donor–Acceptor Complex

(2022) Xiaoxiang Xi et al.   ORGANIC LETTERS

Iron-Catalyzed Allylic Defluorinative Ketone Olefin Coupling

(2022) Chang Zhang et al.   ORGANIC LETTERS

Photochemically Enabled, Ni-Catalyzed Cyanation of Aryl Halides

(2022) Yonggang Yan et al.   ORGANIC LETTERS

Ni-Catalyzed Asymmetric Reductive Alkenylation of α-Chlorosulfones with Vinyl Bromides

(2022) Jingjing Geng et al.   ORGANIC LETTERS

Ni-Catalyzed Asymmetric Hydrogenation of Aromatic Ketoacids for the Synthesis of Chiral Lactones

(2022) Chen-Qiang Deng et al.   ORGANIC LETTERS

Nickel-Catalyzed Asymmetric Hydrogenation of γ-Keto Acids, Esters, and Amides to Chiral γ-Lactones and γ-Hydroxy Acid Derivatives

(2022) Guiying Xiao et al.   ORGANIC LETTERS

Photochemical Nozaki–Hiyama–Kishi Coupling Enabled by Excited Hantzsch Ester

(2022) Yonghong Liu et al.   ORGANIC LETTERS

Copper-Catalyzed anti-Selective Radical 1,2-Alkylarylation of Terminal Alkynes

(2022) Jun-Bin Tang et al.   ORGANIC LETTERS

Ni-Catalyzed Reductive 1,2-Cross-Dialkylation of Unactivated Alkenes with Two Alkyl Bromides

(2022) Jian-Xin Zhang et al.   ORGANIC LETTERS

Stereoselective Nickel(II)-Catalyzed Addition of Aryl Grignards to Diphenylacetylene in the Synthesis of Zuclomiphene

(2022) Avedis Karadeolian et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

(CAAC)Copper Catalysis Enables Regioselective Three-Component Carboboration of Terminal Alkynes

(2022) Yang Gao et al.   ACS Catalysis

Cobalt-Catalyzed Carbo- and Hydrocyanation of Alkynes via C–CN Bond Activation

(2022) Chang-Sheng Wang et al.   ACS Catalysis

Ni-Catalyzed Enantioselective Dialkyl Carbinol Synthesis via Decarboxylative Cross-Coupling: Development, Scope, and Applications

(2022) Yang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Acyl Chloride with Racemic α-Trifluoromethyl Bromide to Access Chiral α-Trifluoromethyl Ketones

(2022) Juanjuan Wu et al.   ORGANIC LETTERS

Recent Advances in Non-Precious Metal Catalysis

(2022) Hao Wu et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Recent Advances in Nonprecious Metal Catalysis

(2022) Robert A. Singer et al.   Organic Process Research & Development

Chiral Alkyl Amine Synthesis via Catalytic Enantioselective Hydroalkylation of Enecarbamates

(2021) Deyun Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Formal Hydroamination of Allylic Alcohols using Manganese PNP‐Pincer Complexes

(2021) Leandro Duarte et al.   ADVANCED SYNTHESIS & CATALYSIS

Cyclic (Alkyl)(amino)carbene Ligands Enable Cu‐Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes**

(2021) Yang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chromium-Catalyzed Allylic Defluorinative Ketyl Olefin Coupling

(2021) Chang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Advancing Base-Metal Catalysis: Development of a Screening Method for Nickel-Catalyzed Suzuki–Miyaura Reactions of Pharmaceutically Relevant Heterocycles

(2021) Matthew J. Goldfogel et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Manganese-Catalyzed Anti-Markovnikov Hydroamination of Allyl Alcohols via Hydrogen-Borrowing Catalysis

(2021) Kuhali Das et al.   ACS Catalysis

Mechanistic Study of Ni and Cu Dual Catalyst for Asymmetric C–C Bond Formation; Asymmetric Coupling of 1,3-Dienes with C-nucleophiles to Construct Vicinal Stereocenters

(2021) Jingzhao Xia et al.   ACS Catalysis

Recent Advances in Nonprecious Metal Catalysis

(2021) Shashank Shekhar et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

N-Heterocyclic Carbene–Nickel-Catalyzed Regioselective Diarylation of Aliphatic-1,3-Dienes

(2021) Hongyu Wang et al.   ACS Catalysis

Where does the Fluorine come from? A review on the challenges associated with the synthesis of organofluorine compounds.

(2020) Stephane Caron   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Cooperative Ni/Cu‐Catalyzed Asymmetric Propargylic Alkylation of Aldimine Esters

(2020) Lingzi Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Three-Component Fluoroalkylarylation of Unactivated Olefins through Nickel-Catalyzed Cross-Electrophile Coupling

(2020) Hai-Yong Tu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective Union of Olefins, Organohalides, and Redox-Active Esters Enables Regioselective Alkene Dialkylation

(2020) Tao Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Regioselective 1,2-Dialkylation of Alkenes Enabled by the Formation of Two C(sp3)–C(sp3) Bonds

(2020) Roshan K. Dhungana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Addition of Aryl Bromides to Aldehydes To Form Hindered Secondary Alcohols

(2019) Kevin J. Garcia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Anti-Markovnikov Hydroamination and Hydroamidation of Allylic Alcohols

(2019) Wei Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Access to Multifunctionalized Benzofurans by Aryl Nickelation of Alkynes: Efficient Synthesis of the Anti-Arrhythmic Drug Amiodarone

(2019) Naeem Iqbal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Allylboration of Alkynes: Synthesis of Highly Versatile Multifunctional Building Blocks

(2019) Eva Rivera-Chao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki−Miyaura Cross-Coupling of Boronic Esters

(2019) Connor P. Delaney et al.   ACS Catalysis

Copper-Catalyzed Tandem Hydrocupration and Diastereo- and Enantioselective Borylalkyl Addition to Aldehydes

(2018) Jaesook Yun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Arylative Carboxylation of Alkynes with Arylmagnesium Reagents and Carbon Dioxide Leading to Trisubstituted Acrylic Acids

(2018) Sheng Wang et al.   ORGANIC LETTERS

Directed nickel-catalyzed 1,2-dialkylation of alkenyl carbonyl compounds

(2018) Joseph Derosa et al.   Chemical Science

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki–Miyaura Reaction

(2017) Andy A. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Pincer Carbodicarbene Ligands for Enantioselective Rhodium-Catalyzed Hydroarylation of Terminal and Internal 1,3-Dienes with Indoles

(2017) Justin S. Marcum et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Synthesis of Indolines: Asymmetric Hydrogenation at Ambient Temperature and Pressure with Cationic Ruthenium Diamine Catalysts

(2016) Zhusheng Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids

(2016) Jeffrey S. Bandar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Unactivated Terminal Alkynes

(2016) Wei Su et al.   ACS Catalysis

Nickel-Catalyzed Three-Component Domino Reactions of Aryl Grignard Reagents, Alkynes, and Aryl Halides Producing Tetrasubstituted Alkenes

(2015) Fei Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines

(2015) Y. Yang et al.   SCIENCE

Photocatalytic C–F alkylation; facile access to multifluorinated arenes

(2015) A. Singh et al.   Chemical Science

Intermolecular [3+2] Annulation of Cyclopropylanilines with Alkynes, Enynes, and DiynesviaVisible Light Photocatalysis

(2014) Theresa H. Nguyen et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent advances in the trifluoromethylation methodology and new CF3-containing drugs

(2014) Wei Zhu et al.   JOURNAL OF FLUORINE CHEMISTRY

Ambient arylmagnesiation of alkynes catalysed by ligandless nickel(ii)

(2013) Fei Xue et al.   CHEMICAL COMMUNICATIONS

Catalytic Asymmetric Reductive Acyl Cross-Coupling: Synthesis of Enantioenriched Acyclic α,α-Disubstituted Ketones

(2013) Alan H. Cherney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

(2012) Ricardo Alfaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular [3+2] Cycloaddition of Cyclopropylamines with Olefins by Visible-Light Photocatalysis

(2011) Soumitra Maity et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION