Cyclic (Alkyl)(amino)carbene Ligands Enable Cu‐Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes**

Cyclic (Alkyl)(amino)carbenes (CAACs) in Ruthenium Olefin Metathesis

(2021) Jennifer Morvan et al.   ACS Catalysis

Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications

(2020) Rodolphe Jazzar et al.   CHEMICAL REVIEWS

Influence of Carbene and Phosphine Ligands on the Catalytic Activity of Gold Complexes in the Hydroamination and Hydrohydrazination of Alkynes

(2020) Sima Yazdani et al.   ACS Catalysis

Synthesis of 1,3‐Bis‐(boryl)alkanes through Boronic Ester Induced Consecutive Double 1,2‐Migration

(2020) Cai You et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High Reactivity of α-Boryl Radical of Potassium Alkyltrifluoroborate in Atom-Transfer Radical Addition

(2020) Mitsuhiro Ueda et al.   ORGANIC LETTERS

Cycloadditions of Alkenylboronic Derivatives

(2020) Oleksandr O. Grygorenko et al.   SYNTHESIS-STUTTGART

The Influence of C(sp 3 )H–Selenium Interactions on the 77 Se NMR Quantification of the π‐Accepting Properties of Carbenes

(2020) Glen P. Junor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt‐Catalyzed Markovnikov‐Type Selective Hydroboration of Terminal Alkynes

(2020) Jieping Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Borylative Difunctionalization of π-Systems

(2020) Andrew Whyte et al.   ACS Catalysis

Synthesis of Bisheteroarylalkanes by Heteroarylboration: Development and Application of a Pyridylidene-Copper Complex

(2019) Yuan Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed anti-Markovnikov Hydroboration of C–C Multiple Bonds

(2019) Yan Wang et al.   ORGANIC LETTERS

Carboallylation of Electron-Deficient Alkenes with Organoboron Compounds and Allylic Carbonates by Cooperative Palladium/Copper Catalysis

(2019) Kazuhiko Semba et al.   ORGANIC LETTERS

Regioselective Arylboration of 1,3‐Butadiene

(2019) Allison M. Bergmann et al.   ISRAEL JOURNAL OF CHEMISTRY

Towards the online computer-aided design of catalytic pockets

(2019) Laura Falivene et al.   Nature Chemistry

Copper-Catalyzed Carbon–Silicon Bond Formation

(2019) Jake R. Wilkinson et al.   ACS Catalysis

Electronic Properties of N-Heterocyclic Carbenes and Their Experimental Determination

(2018) Han Vinh Huynh   CHEMICAL REVIEWS

Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes

(2018) Cory M. Weinstein et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboallylation of electron-deficient alkenes by palladium/copper catalysis

(2018) Kazuhiko Semba et al.   CHEMICAL COMMUNICATIONS

Copper-boryl mediated organic synthesis

(2018) David Hemming et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of a Copper Silyl Complex by Disilane Activation

(2018) Bethany J. McCarty et al.   ORGANOMETALLICS

Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes

(2018) Allison M. Bergmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

What Wanzlick Did Not Dare To Dream: Cyclic (Alkyl)(amino)carbenes (cAACs) as New Key Players in Transition-Metal Chemistry

(2017) Ursula S. D. Paul et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs

(2017) Eder Tomás-Mendivil et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst Controlled Regiodivergent Arylboration of Dienes

(2017) Stephen R. Sardini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fe-Catalyzed C–C Bond Construction from Olefins via Radicals

(2017) Julian C. Lo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[(NHC)CuI–ER3] Complexes (ER3 = SiMe2Ph, SiPh3, SnMe3): From Linear, Mononuclear Complexes to Polynuclear Complexes with Ultrashort CuI···CuI Distances

(2016) Jacqueline Plotzitzka et al.   INORGANIC CHEMISTRY

Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry

(2016) Jiaxiang Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Hydroborylation of Alkynes: A Ligand Controlled Regioselectivity Switch for the Synthesis of α- or β-Vinylboronates

(2016) Devi Prasan Ojha et al.   ORGANIC LETTERS

Arylboration of 1-Arylalkenes by Cooperative Nickel/Copper Catalysis

(2016) Kazuhiko Semba et al.   ORGANIC LETTERS

Copper-Catalyzed trans-Hydroboration of Terminal Aryl Alkynes: Stereodivergent Synthesis of Alkenylboron Compounds

(2016) Won Jun Jang et al.   ORGANIC LETTERS

SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric Maps

(2016) Laura Falivene et al.   ORGANOMETALLICS

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Copper/Palladium Synergistic Catalysis for thesyn- andanti-Selective Carboboration of Alkenes

(2015) Kaitlyn M. Logan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic conjunctive cross-coupling enabled by metal-induced metallate rearrangement

(2015) L. Zhang et al.   SCIENCE

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons

(2014) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Arylboration of Alkenes by Cooperative Palladium/Copper Catalysis

(2014) Kazuhiko Semba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formal Regiocontrolled Hydroboration of Unbiased Internal Alkynes via Borylation/Allylic Alkylation of Terminal Alkynes

(2013) Abraham L. Moure et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Boron Addition Reactions of Alkynes with Diboron Reagents

(2013) Jaesook Yun   Asian Journal of Organic Chemistry

Copper-Mediated Reduction of CO2with pinB-SiMe2Ph via CO2Insertion into a Copper–Silicon Bond

(2011) Christian Kleeberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Highly Regioselective Silylcupration of Terminal Alkynes to Form α-Vinylsilanes

(2011) Peng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed β-Boration of α,β-Unsaturated Carbonyl Compounds with Tetrahydroxydiborane

(2011) Gary A. Molander et al.   ORGANIC LETTERS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Devising Boron Reagents for Orthogonal Functionalization through Suzuki-Miyaura Cross-Coupling

(2009) Mamoru Tobisu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

(2009) Noriyuki Iwadate et al.   ORGANIC LETTERS

Vinyl MIDA boronate: a readily accessible and highly versatile building block for small molecule synthesis

(2008) Brice E. Uno et al.   TETRAHEDRON