Recent Advances in Nonprecious Metal Catalysis

Taming the Chlorine Radical: Enforcing Steric Control over Chlorine-Radical-Mediated C–H Activation

(2022) Miguel I. Gonzalez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N–O Reagent as the “Amino” Source and “Oxidant”

(2022) Sayanti Chatterjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Access to β-Lactams via Iron-Catalyzed Olefin Oxyamidation Enabled by the π-Accepting Phthalocyanine Ligand

(2022) Jeonguk Kweon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room Temperature Cu-Catalyzed N-Arylation of Oxazolidinones and Amides with (Hetero)Aryl Iodides

(2022) Subhajit Bhunia et al.   ORGANIC LETTERS

Iron-Catalyzed Alkylzincation of Terminal Alkynes

(2022) Qiang Huang et al.   ACS Catalysis

Nontraditional Fragment Couplings of Alcohols and Carboxylic Acids: C(sp3)–C(sp3) Cross-Coupling via Radical Sorting

(2022) Holt A. Sakai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deoxytrifluoromethylation of Alcohols

(2022) Nicholas E. Intermaggio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Chiral Carboxylic Acids from Alkynes and Formic Acid by Nickel‐Catalyzed Cascade Reactions: Facile Synthesis of Profens

(2021) Peng Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselective and Diastereoselective Synthesis of C ‐Aryl Nucleoside Analogues by Nickel‐Catalyzed Cross‐Coupling of Furanosyl Acetates with Aryl Iodides

(2021) Yuxi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crossed Regio‐ and Enantioselective Iron‐Catalyzed [4+2]‐Cycloadditions of Unactivated Dienes

(2021) Elena Braconi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reductive Alkylation of Alkenyl Acetates with Alkyl Bromides by Nickel Catalysis

(2021) Rong‐De He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Synthesis of 3-Methyl-2-arylimidazo[1,2-a]pyridines Using Calcium Carbide as an Alkyne Source

(2021) Wei Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Glycosyl Triazole Ligand for Temperature-Dependent Competitive Reactions of Cu-Catalyzed Sonogashira Coupling and Glaser Coupling

(2021) Nidhi Mishra et al.   JOURNAL OF ORGANIC CHEMISTRY

An Iron–Mesoionic Carbene Complex for Catalytic Intramolecular C–H Amination Utilizing Organic Azides

(2021) Wowa Stroek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Vinylzincation of Terminal Alkynes

(2021) Qiang Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tunable and Practical Homogeneous Organic Reductants for Cross-Electrophile Coupling

(2021) David J. Charboneau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General, Multimetallic Cross-Ullmann Biheteroaryl Synthesis from Heteroaryl Halides and Heteroaryl Triflates

(2021) Kai Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed (4+1) Cascade Annulation of Terminal Alkynes with 2-(Tosylmethyl)anilines: Synthesis of 2,3-Disubstituted Indoles

(2021) Xu Yan et al.   ORGANIC LETTERS

Copper-Catalyzed Construction of Benzo[4,5]imidazo[2,1-a]isoquinolines Using Calcium Carbide as a Solid Alkyne Source

(2021) Haiyan Liu et al.   ORGANIC LETTERS

Copper-Catalyzed Methoxylation of Aryl Bromides with 9-BBN−OMe

(2021) Jing-Ru Wang et al.   ORGANIC LETTERS

Nickel-Catalyzed Reductive Csp2–Csp3 Cross Coupling Using Phosphonium Salts

(2021) Huifei Wang et al.   ORGANIC LETTERS

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent

(2021) Mincong Su et al.   ORGANIC LETTERS

Copper-Catalyzed Ullmann-Type Coupling and Decarboxylation Cascade of Arylhalides with Malonates to Access α-Aryl Esters

(2021) Fei Cheng et al.   ORGANIC LETTERS

General method for iron-catalyzed multicomponent radical cascades–cross-couplings

(2021) Lei Liu et al.   SCIENCE

Nickel-Catalyzed Reductive Deoxygenation of Diverse C–O Bond-Bearing Functional Groups

(2021) Adam Cook et al.   ACS Catalysis

Ni-Catalyzed Formal Cross-Electrophile Coupling of Alcohols with Aryl Halides

(2021) Quan Lin et al.   ACS Catalysis

(PSiP)Ni-Catalyzed (E)-Selective Semihydrogenation of Alkynes with Molecular Hydrogen

(2021) Dylan J. Hale et al.   ACS Catalysis

Origins of Regio- and Chemoselectivity in Iron-PDAI-Catalyzed [2+2+2] Cycloaddition Syntheses of 4,6-Disubstituted 2-Aminopyridines

(2021) Jordan L. Harper et al.   ACS Catalysis

In-Situ Bromination Enables Formal Cross-Electrophile Coupling of Alcohols with Aryl and Alkenyl Halides

(2021) Benjamin K. Chi et al.   ACS Catalysis

Exhaustive Reduction of Esters Enabled by Nickel Catalysis

(2020) Adam Cook et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design and scalable synthesis of novel N‐alkyl‐hydroxylamine reagents for the direct, Fe‐catalyzed installation of medicinally relevant amines

(2020) Eric Falk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfonate Versus Sulfonate: Nickel and Palladium Multimetallic Cross-Electrophile Coupling of Aryl Triflates with Aryl Tosylates

(2020) Kai Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxalohydrazide Ligands for Copper‐Catalyzed C−O Coupling Reactions with High Turnover Numbers

(2020) Ritwika Ray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Assembly of α‐(Hetero)aryl Nitriles via Cu‐Catalyzed Coupling Reactions with (Hetero)aryl Chlorides and Bromides

(2020) Dawei Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of Unprotected 2-Azidoamines from Alkenes via an Iron-Catalyzed Difunctionalization Reaction

(2020) Szabolcs Makai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Aminohydroxylation of Styrenyl Olefins Catalyzed by an Engineered Hemoprotein

(2019) Inha Cho et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction

(2019) Zhixiang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Benz-Fused Azoles via C-Heteroatom Coupling Reactions Catalyzed by Cu(I) in the Presence of Glycosyltriazole Ligands

(2019) Nidhi Mishra et al.   ACS Combinatorial Science

Rhodium-Catalyzed Annulative Coupling Using Vinylene Carbonate as an Oxidizing Acetylene Surrogate

(2019) Koushik Ghosh et al.   ACS Catalysis

Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading

(2018) W. Schutyser et al.   CHEMICAL SOCIETY REVIEWS

A Synthetic Dual Drug Sideromycin Induces Gram-Negative Bacteria To Commit Suicide with a Gram-Positive Antibiotic

(2018) Rui Liu et al.   JOURNAL OF MEDICINAL CHEMISTRY

Application of Virtual Screening to the Identification of New LpxC Inhibitor Chemotypes, Oxazolidinone and Isoxazoline

(2018) Patrick S. Lee et al.   JOURNAL OF MEDICINAL CHEMISTRY

Efficient access to unprotected primary amines by iron-catalyzed aminochlorination of alkenes

(2018) Luca Legnani et al.   SCIENCE

Chemoselective Copper-Catalyzed Ullmann-Type Coupling of Oxazolidinones with Bromoiodoarenes

(2017) Sean M. Kelly et al.   ORGANIC LETTERS

Direct Catalytic Synthesis of Unprotected 2-Amino-1-Phenylethanols from Alkenes by Using Iron(II) Phthalocyanine

(2016) Luca Legnani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Cross-Electrophile Coupling with Organic Reductants in Non-Amide Solvents

(2016) Lukiana L. Anka-Lufford et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective Iron-Catalyzed [2 + 2 + 2] Cycloaddition Reaction Forming 4,6-Disubstituted 2-Aminopyridines from Terminal Alkynes and Cyanamides

(2016) Nathan A. Spahn et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Hydroxylation of (Hetero)aryl Halides under Mild Conditions

(2016) Shanghua Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mild and General Larock Indolization Protocol for the Preparation of Unnatural Tryptophans

(2016) Kangway V. Chuang et al.   ORGANIC LETTERS

Recent advances in the transition metal catalyzed etherification reactions

(2016) K. Keerthi Krishnan et al.   TETRAHEDRON

Palladium-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid

(2015) Jing Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines

(2015) Wei Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multimetallic catalysed cross-coupling of aryl bromides with aryl triflates

(2015) Laura K. G. Ackerman et al.   NATURE

Palladium-Catalyzed Methoxylation of Aromatic Chlorides with Borate Salts

(2014) Gergely L. Tolnai et al.   ADVANCED SYNTHESIS & CATALYSIS

Cross-Electrophile Coupling: Principles of Reactivity and Selectivity

(2014) Daniel A. Everson et al.   JOURNAL OF ORGANIC CHEMISTRY

A Novel Synthesis of the Oxazolidinone Antithrombotic Agent Rivaroxaban

(2014) Jianyong Yuan et al.   MOLECULES

Iron-Catalyzed Cycloaddition Reaction of Diynes and Cyanamides at Room Temperature

(2013) Chunxiang Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of imidazo and benzimidazo[2,1-a]isoquinolines by rhodium-catalyzed intramolecular double C–H bond activation

(2013) Vutukuri Prakash Reddy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Mild and General Palladium-Catalyzed Synthesis of Methyl Aryl Ethers Enabled by the Use of a Palladacycle Precatalyst

(2013) Chi Wai Cheung et al.   ORGANIC LETTERS

Coupling and Cyclization of o-Iodoanilines and Propargylic Bromides via Allenes: An Efficient Entry to Indomethacin

(2013) Can Zhu et al.   ORGANIC LETTERS

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

A Convenient and Practical Synthesis of Anisoles and Deuterated Anisoles by Palladium-Catalyzed Coupling Reactions of Aryl Bromides and Chlorides

(2012) Saravanan Gowrisankar et al.   CHEMISTRY-A EUROPEAN JOURNAL

CuI/N,N-dimethylglycine-catalyzed synthesis of N-aryloxazolidinones from aryl bromides

(2012) Jiaojiao Li et al.   TETRAHEDRON LETTERS

A Single Phosphine Ligand Allows Palladium-Catalyzed Intermolecular CO Bond Formation with Secondary and Primary Alcohols

(2011) Xiaoxing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium on carbon-catalyzed synthesis of 2- and 2,3-substituted indoles under heterogeneous conditions

(2010) Yasunari Monguchi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A ligand-free, copper-catalyzed cascade sequence to indole-2-carboxylic esters

(2010) Stefan G. Koenig et al.   TETRAHEDRON LETTERS

Palladium-catalysed synthesis of aryl-alkyl ethers using alkoxysilanes as nucleophiles

(2009) Edward J. Milton et al.   ORGANIC & BIOMOLECULAR CHEMISTRY