Mechanistic view of Ru-catalyzed C–H bond activation and functionalization: computational advances

Ruthenium(II)-Catalyzed C−H Difluoromethylation of Ketoximes: Tuning the Regioselectivity from the meta to the para Position

(2018) Chunchen Yuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arene-Ligand-Free Ruthenium(II/III) Manifold for meta -C−H Alkylation: Remote Purine Diversification

(2018) Fernando Fumagalli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Counterion effect and directing group effect in Rh-mediated C H bond activation processes: A theoretical study

(2018) Yixin Luo et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Ruthenium(II)-Catalyzed Cyclization of Aromatic Acids with Allylic Acetates via Redox-Free Two-Fold Aromatic/Allylic C–H Activations: Combined Experimental and DFT Studies

(2018) Subramanian Jambu et al.   ORGANIC LETTERS

Ruthenium(II)-enabled para-selective C–H difluoromethylation of anilides and their derivatives

(2018) Chunchen Yuan et al.   Nature Communications

Regioselective Palladium-Catalyzed C-H Bond Trifluoroethylation of Indoles: Exploration and Mechanistic Insight

(2018) Hao Zhang et al.   ACS Catalysis

Sequential meta-/ortho-C–H Functionalizations by One-Pot Ruthenium(II/III) Catalysis

(2018) Korkit Korvorapun et al.   ACS Catalysis

C–H bond cleavage occurring on a Rh(v) intermediate: a theoretical study of Rh-catalyzed arene azidation

(2018) Song Liu et al.   Catalysis Science & Technology

Ni(i)–Ni(iii) vs. Ni(ii)–Ni(iv): mechanistic study of Ni-catalyzed alkylation of benzamides with alkyl halides

(2018) Yingzi Li et al.   Organic Chemistry Frontiers

Experimental and Theoretical Studies on Ru(II)-Catalyzed Oxidative C–H/C–H Coupling of Phenols with Aromatic Amides Using Air as Oxidant: Scope, Synthetic Applications, and Mechanistic Insights

(2018) Luoqiang Zhang et al.   ACS Catalysis

Rhodium/Copper Cocatalyzed Highly trans-Selective 1,2-Diheteroarylation of Alkynes with Azoles via C–H Addition/Oxidative Cross-Coupling: A Combined Experimental and Theoretical Study

(2017) Guangying Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanisms and Origins of Chemo- and Regioselectivities of Ru(II)-Catalyzed Decarboxylative C–H Alkenylation of Aryl Carboxylic Acids with Alkynes: A Computational Study

(2017) Jing-Lu Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium(ii)-catalyzed ortho-C–H arylation of diverse N-heterocycles with aryl silanes by exploiting solvent-controlled N-coordination

(2017) Pradeep Nareddy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ruthenium(II)-Catalyzed Direct C–H Arylation of Indoles with Arylsilanes in Water

(2017) Pradeep Nareddy et al.   ORGANIC LETTERS

DFT Studies of Ru-Catalyzed C–O versus C–H Bond Functionalization of Aryl Ethers with Organoboronates

(2017) Zheng Wang et al.   ORGANOMETALLICS

Intramolecular C–H Activation Reactions of Ru(NHC) Complexes Combined with H2 Transfer to Alkenes: A Theoretical Elucidation of Mechanisms and Effects of Ligands on Reactivities

(2017) Katharina Marie Wenz et al.   ORGANOMETALLICS

Ru-catalyzed ortho -oxidative alkenylation of 2-arylbenzo[ d ]thiazoles in aqueous solution of anionic surfactant sodium dodecylbenzenesulfonate (SDBS)

(2017) Yuanyuan Ping et al.   TETRAHEDRON

Highly chemoselective ruthenium(ii)-catalyzed direct arylation of cyclic and N,N-dialkyl benzamides with aryl silanes

(2017) Pradeep Nareddy et al.   Chemical Science

Recent Developments in Ruthenium-Catalyzed C–H Arylation: Array of Mechanistic Manifolds

(2017) Pradeep Nareddy et al.   ACS Catalysis

A theoretical study on the mechanism of ruthenium(ii)-catalyzed phosphoryl-directed ortho-selective C–H bond activations: the phosphoryl hydroxy group triggered Ru(ii)/Ru(0) catalytic cycle

(2017) Peng Chen et al.   Organic Chemistry Frontiers

Manganese(I)-Catalyzed Substitutive C−H Allylation

(2016) Weiping Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed Decarboxylative C−H Activation: Versatile Routes tometa-Alkenylated Arenes

(2016) N. Y. Phani Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ortho -C−H Arylation of Benzoic Acids with Aryl Bromides and Chlorides Catalyzed by Ruthenium

(2016) Agostino Biafora et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp3)−H and C(sp2)−H under Rhodium(III) Catalysis

(2016) Songjie Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(ii)-catalyzed C–H functionalizations on benzoic acids with aryl, alkenyl and alkynyl halides by weak-O-coordination

(2016) Ruhuai Mei et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Ruthenium-Catalyzed C−H Arylation of Benzoic Acids and Indole Carboxylic Acids with Aryl Halides

(2016) Marco Simonetti et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism and Selectivity of RuII- and RhIII-Catalyzed Oxidative Spiroannulation of Naphthols and Phenols with Alkynes through a C−H Activation/Dearomatization Strategy

(2016) Mei Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Ortho C–H Arylation of Aromatic Nitriles with Arylboronates and Observation of Partial Para Arylation

(2016) Yuta Koseki et al.   JOURNAL OF ORGANIC CHEMISTRY

Ru-Catalyzed C–H Arylation of Fluoroarenes with Aryl Halides

(2016) Marco Simonetti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unveiling Secrets of Overcoming the “Heteroatom Problem” in Palladium-Catalyzed Aerobic C–H Functionalization of Heterocycles: A DFT Mechanistic Study

(2016) Yanfeng Dang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations

(2016) Drew R. Heitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Meta-Selective CAr–H Nitration of Arenes through a Ru3(CO)12-Catalyzed Ortho-Metalation Strategy

(2016) Zhoulong Fan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Charge-transfer-directed radical substitution enables para-selective C–H functionalization

(2016) Gregory B. Boursalian et al.   Nature Chemistry

Density functional theory investigation on Pd-catalyzed cross-coupling of azoles with aryl thioethers

(2016) Yi-Meng Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regiocontrolled synthesis of (hetero)aryl and alkenyl dehydropyrrolidines, dehydropiperidines and azepenes by Ru-catalyzed, heteroatom-directed α-C–H activation/cross-coupling of cyclic enamides with boronic acids

(2016) Timothy K. Beng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ruthenium(0)-Catalyzed C–H Arylation of Aromatic Imines under Neutral Conditions: Access to Biaryl Aldehydes

(2016) Feng Hu et al.   ORGANIC LETTERS

Ruthenium-Catalyzed C–H Arylation of Diverse Aryl Carboxylic Acids with Aryl and Heteroaryl Halides

(2016) Liangbin Huang et al.   ORGANIC LETTERS

Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C–H Bond Activation

(2016) Bao Gao et al.   ORGANOMETALLICS

Syntheses of RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3 Containing Various Triarylphosphines and Their Use for Arylation of Sterically Congested Aromatic C–H Bonds

(2016) Yohei Ogiwara et al.   ORGANOMETALLICS

Mechanism of Ruthenium-Catalyzed Direct Arylation of C–H Bonds in Aromatic Amides: A Computational Study

(2016) Chunhui Shan et al.   ORGANOMETALLICS

Advances in theoretical study on transition-metal-catalyzed C−H activation

(2016) Yuan-Ye Jiang et al.   Science China-Chemistry

Ru-catalysed C–H functionalisations as a tool for selective organic synthesis

(2016) Sara Ruiz et al.   TETRAHEDRON LETTERS

Ruthenium(II)-Catalyzed C–H Functionalization Using the Oxazolidinone Heterocycle as a Weakly Coordinating Directing Group: Experimental and Computational Insights

(2016) Jamie A. Leitch et al.   ACS Catalysis

Ruthenium(II)-Catalyzed Regioselective C–H Arylation of Cyclic and N,N-Dialkyl Benzamides with Boronic Acids by Weak Coordination

(2016) Pradeep Nareddy et al.   ACS Catalysis

Mild Acylation of C(sp3)–H and C(sp2)–H Bonds under Redox-Neutral Rh(III) Catalysis

(2016) Songjie Yu et al.   ACS Catalysis

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Directedmeta-Selective Bromination of Arenes with Ruthenium Catalysts

(2015) Qingzhen Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium Oxidase Catalysis for Site-Selective C-H Alkenylations with Ambient O2 as the Sole Oxidant

(2015) Alexander Bechtoldt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzedortho-Arylation of Benzoic Acids with Arenediazonium Salts

(2015) Liangbin Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-CatalyzedorthoCH Heteroarylation of (Hetero)aromatic Carboxylic Acids: A Rapid and Concise Access to π-Conjugated Poly-heterocycles

(2015) Xurong Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-catalyzed ortho alkenylation of aromatic nitriles with activated alkenes via C–H bond activation

(2015) Mallu Chenna Reddy et al.   CHEMICAL COMMUNICATIONS

Catalytic meta-selective C–H functionalization to construct quaternary carbon centres

(2015) Andrew J. Paterson et al.   CHEMICAL COMMUNICATIONS

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

(2015) Chao Liu et al.   CHEMICAL REVIEWS

The Mechanism of NO Bond Cleavage in Rhodium-Catalyzed CH Bond Functionalization of QuinolineN-oxides with Alkynes: A Computational Study

(2015) Yingzi Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Combined IM-MS/DFT Study on [Pd(MPAA)]-Catalyzed Enantioselective CH Activation: Relay of Chirality through a Rigid Framework

(2015) Gui-Juan Cheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Oxidative Coupling of Primary Amines with Internal Alkynes through CH Bond Activation: Scope and Mechanistic Studies

(2015) Sara Ruiz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Development of a Rhodium(II)-Catalyzed Chemoselective C(sp3)H Oxygenation

(2015) Yun Lin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Single-Component Phosphinous Acid Ruthenium(II) Catalysts for Versatile C−H Activation by Metal-Ligand Cooperation

(2015) Daniel Zell et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium(II)-Catalyzed C3 Arylation of 2-Aroylbenzofurans with Arylboronic Acids/Aryltrifluoroborates via Carbonyl-Directed C–H Bond Activation

(2015) Dinesh J. Paymode et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Silylation of Aryl C–H Bonds

(2015) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insights into the Palladium-Catalyzed Aziridination of Aliphatic Amines by C–H Activation

(2015) Adam P. Smalley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Formal Dehydrative [4 + 2] Cycloaddition of Enamides and Alkynes for the Synthesis of Highly Substituted Pyridines: Reaction Development and Mechanistic Study

(2015) Jicheng Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Acyl Amino Acid Ligands for Ruthenium(II)-Catalyzed meta-C–H tert-Alkylation with Removable Auxiliaries

(2015) Jie Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

(2015) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in the ruthenium-catalyzed hydroarylation of alkynes with aromatics: synthesis of trisubstituted alkenes

(2015) Rajendran Manikandan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ru (II)-Catalyzed C–H Activation: Ketone-Directed Novel 1,4-Addition of Ortho C–H Bond to Maleimides

(2015) Kiran R. Bettadapur et al.   ORGANIC LETTERS

Highly Stereoselective Ruthenium(II)-Catalyzed Direct C2-syn-Alkenylation of Indoles with Alkynes

(2015) Wei Zhang et al.   ORGANIC LETTERS

Ambient-Temperature Ortho C–H Arylation of Benzoic Acids with Aryl Iodides with Ligand-Supported Palladium Catalyst

(2015) Changlei Zhu et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Heteroatom-Directed Regioselective C–H Arylation of Indoles Using a Removable Tether

(2015) Virendra Kumar Tiwari et al.   ORGANIC LETTERS

Robust Ruthenium(II)-Catalyzed C–H Arylations: Carboxylate Assistance for the Efficient Synthesis of Angiotensin-II-Receptor Blockers

(2015) Lutz Ackermann   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Mechanism of Pd-catalyzed selective C-H activation of aliphatic amines via four-membered-ring cyclometallation pathway

(2015) Qi Zhang et al.   Science China-Chemistry

Carboxylate-assisted C–H activation of phenylpyridines with copper, palladium and ruthenium: a mass spectrometry and DFT study

(2015) A. Gray et al.   Chemical Science

Ruthenium-Catalyzed ortho Alkenylation of Aromatics with Alkenes at Room Temperature with Hydrogen Evolution

(2015) Rajendran Manikandan et al.   ACS Catalysis

Efficient Pd0-Catalyzed Asymmetric Activation of Primary and Secondary C–H Bonds Enabled by Modular Binepine Ligands and Carbonate Bases

(2015) Philipp M. Holstein et al.   ACS Catalysis

Directed Ruthenium-Catalyzed C(sp3)H α-Alkylation of Cyclic Amines Using Dioxolane-Protected Alkenones

(2014) Artem A. Kulago et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-catalysed oxidative C–H/C–H coupling between olefins and simple ethers

(2014) Dong Liu et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed Oxidative CH Alkenylations of Sulfonic Acids, Sulfonyl Chlorides and Sulfonamides

(2014) Wenbo Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triazole-Assisted Ruthenium-Catalyzed CH Arylation of Aromatic Amides

(2014) Hamad H. Al Mamari et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel(II)-Catalyzed Direct Arylation of C–H Bonds in Aromatic Amides Containing an 8-Aminoquinoline Moiety as a Directing Group

(2014) Ayana Yokota et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium(II)-Catalyzed Direct Addition of Indole/Pyrrole C2–H Bonds to Alkynes

(2014) Libo Liang et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed C–H Amination with Anilines at Room Temperature: Compatibility of Iridacycles with External Oxidants

(2014) Hyunwoo Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic Pd/Enamine Catalysis: A Strategy for the C–H/C–H Oxidative Coupling of Allylarenes with Unactivated Ketones

(2014) Shan Tang et al.   ORGANIC LETTERS

Ruthenium(II)-Catalyzed C(sp3)–H α-Alkylation of Pyrrolidines

(2014) Marvin Schinkel et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Hydroarylation of Anilides with Alkynes: An Efficient Route to Ortho-Alkenylated Anilines

(2014) Rajendran Manikandan et al.   ORGANIC LETTERS

Some recent advances in transition-metal-catalyzed ortho SP2 C-H functionalization using Ru, Rh, and Pd

(2014) Yu Rao et al.   Science China-Chemistry

An organic cation as a silver(i) analogue for the arylation of sp2 and sp3 C–H bonds with iodoarenes

(2014) Carlos Arroniz et al.   Chemical Science

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes through C-H Cleavage

(2013) Marvin Schinkel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium/Copper-Catalyzed Oxidative CH Alkenylation/N-Dealkylative Carbonylation of Tertiary Anilines

(2013) Renyi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

8-Aminoquinoline: A Powerful Directing Group in Metal-Catalyzed Direct Functionalization of CH Bonds

(2013) Matthieu Corbet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative cross-coupling/cyclization to build polysubstituted pyrroles from terminal alkynes and β-enamino esters

(2013) Jie Ke et al.   CHEMICAL COMMUNICATIONS

C–H nitrogenation and oxygenation by ruthenium catalysis

(2013) Vedhagiri S. Thirunavukkarasu et al.   CHEMICAL COMMUNICATIONS

Oxidative C–H amination reactions

(2013) Marie-Laure Louillat et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-Catalyzed ortho-Alkenylation of Phenylphosphine Oxides through Regio- and Stereoselective Alkyne Insertion into C–H Bonds

(2013) Masaki Itoh et al.   JOURNAL OF ORGANIC CHEMISTRY

meta-Selective C–H Bond Alkylation with Secondary Alkyl Halides

(2013) Nora Hofmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Direct Arylation of C(sp3)–H Bonds in Aliphatic Amides via Bidentate-Chelation Assistance

(2013) Yoshinori Aihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ortho- and Para-Selective Ruthenium-Catalyzed C(sp2)–H Oxygenations of Phenol Derivatives

(2013) Weiping Liu et al.   ORGANIC LETTERS

Direct ortho-Arylation of ortho-Substituted Benzoic Acids: Overriding Pd-Catalyzed Protodecarboxylation

(2013) Carlos Arroniz et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Regioselective C–H Alkenylation Directed by a Free Amino Group

(2013) Chiharu Suzuki et al.   ORGANIC LETTERS

Catalytic H/D Exchange of Unactivated Aliphatic C–H Bonds

(2013) Sun Hwa Lee et al.   ORGANOMETALLICS

Ruthenium-Catalyzed Ortho-Selective C–H Alkenylation of Aromatic Compounds with Alkenyl Esters and Ethers

(2013) Yohei Ogiwara et al.   ORGANOMETALLICS

On the role of anionic ligands in the site-selectivity of oxidative C–H functionalization reactions of arenes

(2013) Italo A. Sanhueza et al.   Chemical Science

Ruthenium-catalyzed ortho-C–H bond alkylation of aromatic amides with α,β-unsaturated ketones via bidentate-chelation assistance

(2013) Guy Rouquet et al.   Chemical Science

Ruthenium(II)-Catalyzed Chelation-Assisted Arylation of CH Bonds with Diaryliodonium Salts

(2013) Jordan Sun Ho et al.   Asian Journal of Organic Chemistry

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Double CH Functionalization/Carbonylation for the Synthesis of Xanthones

(2012) Hua Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Hydride Ligands Make the Difference: Density Functional Study of the Mechanism of the Murai Reaction Catalyzed by [Ru(H)2(H2)2(PR3)2] (R=cyclohexyl)

(2012) Ulrike Helmstedt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective C–H Bond Cleavage/Alkyne Insertion under Ruthenium Catalysis

(2012) Yuto Hashimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Understanding Reactivity and Stereoselectivity in Palladium-Catalyzed Diastereoselective sp3 C–H Bond Activation: Intermediate Characterization and Computational Studies

(2012) Ramesh Giri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Oxidative C–H/C–H Functionalization: A Strategy To Construct Polysubstituted Furans

(2012) Chuan He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Mediated C–H Functionalization of Pyridine: The Role of Vinylidene and Pyridylidene Ligands

(2012) David G. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium(II)-Catalyzed Regio- and Stereoselective Hydroarylation of Alkynes via Directed C–H Functionalization

(2012) Yuto Hashimoto et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

(2012) Bin Li et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Alkenylations of Anilides and Benzamides in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Ruthenium-catalyzed direct arylation of C–H bonds in aromatic amides containing a bidentate directing group: significant electronic effects on arylation

(2012) Yoshinori Aihara et al.   Chemical Science

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Transition-metal catalyzed oxidative cross-coupling reactions to form C–C bonds involving organometallic reagents as nucleophiles

(2011) Wei Shi et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C–H Bond Cleavage Directed by a Nitrogen-containing Group

(2011) Yuto Hashimoto et al.   CHEMISTRY LETTERS

Nickel-Catalyzed CH Arylation of Azoles with Haloarenes: Scope, Mechanism, and Applications to the Synthesis of Bioactive Molecules

(2011) Takuya Yamamoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed C–H/C–O Coupling of Azoles with Phenol Derivatives

(2011) Kei Muto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Directed C−H Amidation of Aromatic Ketones

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Theoretical Analysis of the Mechanism of Palladium(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of themeta-Regioselectivity

(2011) Songlin Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Meta Sulfonation of 2-Phenylpyridines

(2011) Ourida Saidi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Dibenzofurans via Palladium-Catalyzed Phenol-Directed C–H Activation/C–O Cyclization

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Autocatalysis for C–H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes

(2011) Emmanuel Ferrer Flegeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides

(2010) Lutz Ackermann   CHEMICAL COMMUNICATIONS

C−H Bond Activations by Metal Oxo Compounds

(2010) Ahmet Gunay et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

Control of Product Selectivity by a Styrene Additive in Ruthenium-Catalyzed C−H Arylation

(2010) Shun Hiroshima et al.   ORGANIC LETTERS

Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts

(2010) Lutz Ackermann et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Regioselective Direct Alkylation of Arenes with Unactivated Alkyl Halides through CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Mechanisms of C–H bond activation: rich synergy between computation and experiment

(2009) Youcef Boutadla et al.   DALTON TRANSACTIONS

Cycloruthenated Compounds - Synthesis and Applications

(2009) Jean-Pierre Djukic et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Unique Effect of Coordination of an Alkene Moiety in Products on Ruthenium-Catalyzed Chemoselective C−H Alkenylation

(2009) Satoshi Ueno et al.   ORGANIC LETTERS

Versatile Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Benzoic and Phenyl Acetic Acids

(2008) Dong-Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism

(2008) Ismail Özdemir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrative Direct Arylations of Arenes with Phenols via Ruthenium-Catalyzed C−H and C−OH Bond Functionalizations

(2008) Lutz Ackermann et al.   ORGANIC LETTERS

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

(2008) Lutz Ackermann et al.   ORGANIC LETTERS

Mechanistic Study of Acetate-Assisted C−H Activation of 2-Substituted Pyridines with [MCl2Cp*]2(M = Rh, Ir) and [RuCl2(p-cymene)]2

(2008) Youcef Boutadla et al.   ORGANOMETALLICS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART