Ruthenium-Catalyzed C−H Arylation of Benzoic Acids and Indole Carboxylic Acids with Aryl Halides

A Hydrazone-Based exo -Directing-Group Strategy for β C−H Oxidation of Aliphatic Amines

(2016) Zhongxing Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed Decarboxylative C−H Activation: Versatile Routes tometa-Alkenylated Arenes

(2016) N. Y. Phani Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(0)-catalyzed hydroarylation of alkynes via ketone-directed C–H functionalization using in situ-generated ruthenium complexes

(2016) Feng Hu et al.   CHEMICAL COMMUNICATIONS

Room-Temperature Direct β-Arylation of Thiophenes and Benzo[b]thiophenes and Kinetic Evidence for a Heck-type Pathway

(2016) Chiara Colletto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ru-Catalyzed C–H Arylation of Fluoroarenes with Aryl Halides

(2016) Marco Simonetti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C–H Arylation of Indoles at the C7 Position

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Direct C6-Arylation of Indoles

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal-Catalyzed CH Activation of Indoles

(2015) Alexander H. Sandtorv   ADVANCED SYNTHESIS & CATALYSIS

Carboxylic Acids as Traceless Directing Groups for the Rhodium(III)-Catalyzed Decarboxylative CH Arylation of Thiophenes

(2015) Yuanfei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzedortho-Arylation of Benzoic Acids with Arenediazonium Salts

(2015) Liangbin Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-CatalyzedorthoCH Heteroarylation of (Hetero)aromatic Carboxylic Acids: A Rapid and Concise Access to π-Conjugated Poly-heterocycles

(2015) Xurong Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Salicylic acids as readily available starting materials for the synthesis of meta-substituted biaryls

(2015) Junfei Luo et al.   CHEMICAL COMMUNICATIONS

Direct CH Amidation of Benzoic Acids to Introducemeta- andpara-Amino Groups by Tandem Decarboxylation

(2015) Donggun Lee et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Domino Oxidation/Arylation/Protodecarboxylation Reaction of Salicylaldehydes: Expanded Access tometa-Arylphenols

(2015) Junfei Luo et al.   Chemistry-An Asian Journal

Total Synthesis of Verruculogen and Fumitremorgin A Enabled by Ligand-Controlled C–H Borylation

(2015) Yu Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition metal catalyzed meta-C–H functionalization of aromatic compounds

(2015) Jiong Yang   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh(III)-Catalyzed Decarboxylative ortho-Heteroarylation of Aromatic Carboxylic Acids by Using the Carboxylic Acid as a Traceless Directing Group

(2015) Xurong Qin et al.   ORGANIC LETTERS

Ambient-Temperature Ortho C–H Arylation of Benzoic Acids with Aryl Iodides with Ligand-Supported Palladium Catalyst

(2015) Changlei Zhu et al.   ORGANIC LETTERS

Ru(II)-catalyzed ortho-amidation and decarboxylation of aromatic acids: a versatile route to meta-substituted N-aryl benzamides

(2015) Xian-Ying Shi et al.   Science China-Chemistry

Weakly Coordinating Directing Groups for Ruthenium(II)- Catalyzed CH Activation

(2014) Suman De Sarkar et al.   ADVANCED SYNTHESIS & CATALYSIS

Iridium-Catalyzed Direct CH Amidation with Weakly Coordinating Carbonyl Directing Groups under Mild Conditions

(2014) Jinwoo Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Convenient Synthesis ofN-Aryl Benzamides by Rhodium-Catalyzedortho-Amidation and Decarboxylation of Benzoic Acids

(2014) Xian-Ying Shi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Overriding Ortho–Para Selectivity via a Traceless Directing Group Relay Strategy: The Meta-Selective Arylation of Phenols

(2014) Junfei Luo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chelation-Assisted Regioselective Catalytic Functionalization of C–H, C–O, C–N and C–F Bonds

(2014) Fumitoshi Kakiuchi et al.   SYNLETT

An organic cation as a silver(i) analogue for the arylation of sp2 and sp3 C–H bonds with iodoarenes

(2014) Carlos Arroniz et al.   Chemical Science

Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bonds

(2014) Xi-Sha Zhang et al.   Chemical Science

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Aryl Ethers from Benzoates through Carboxylate-Directed CH-Activating Alkoxylation with Concomitant Protodecarboxylation

(2013) Sukalyan Bhadra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed CHorthoArylation of Benzoic Acids with Diaryliodonium Salts in Water

(2013) Zhiqing Wu et al.   ChemCatChem

Biomedical Importance of Indoles

(2013) Nagendra Kaushik et al.   MOLECULES

Direct ortho-Arylation of ortho-Substituted Benzoic Acids: Overriding Pd-Catalyzed Protodecarboxylation

(2013) Carlos Arroniz et al.   ORGANIC LETTERS

Direct Olefination at the C-4 Position of Tryptophan via C–H Activation: Application to Biomimetic Synthesis of Clavicipitic Acid

(2013) Qiang Liu et al.   ORGANIC LETTERS

Regioselective Synthesis of 4-Substituted Indoles via C–H Activation: A Ruthenium Catalyzed Novel Directing Group Strategy

(2013) Veeranjaneyulu Lanke et al.   ORGANIC LETTERS

Programmed synthesis of arylthiazoles through sequential C–H couplings

(2013) Satoshi Tani et al.   Chemical Science

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Regioselective Ortho-Arylation and Alkenylation of N-Alkyl Benzamides with Boronic Acids via Ruthenium-Catalyzed C–H Bond Activation: An Easy Route to Fluorenones Synthesis

(2012) Ravi Kiran Chinnagolla et al.   ORGANIC LETTERS

Decarboxylative Carbon-Carbon Bond-Forming Transformations of (Hetero)aromatic Carboxylic Acids

(2012) Igor Larrosa et al.   SYNTHESIS-STUTTGART

Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways

(2012) Wojciech I. Dzik et al.   Chemical Science

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Removable Directing Groups in Organic Synthesis and Catalysis

(2011) Géraldine Rousseau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylic Acids as Traceless Directing Groups for Formal meta-Selective Direct Arylation

(2011) Josep Cornella et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

(2011) Nuria Rodríguez et al.   CHEMICAL SOCIETY REVIEWS

Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group

(2011) Satoshi Mochida et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intermolecular Directed C−H Amidation of Aromatic Ketones

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition metal-catalyzed decarboxylative cross-coupling reactions

(2011) Rui Shang et al.   Science China-Chemistry

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Gold-mediated C–H bond functionalisation

(2010) Tanya C. Boorman et al.   CHEMICAL SOCIETY REVIEWS

Decarboxylative Coupling Reactions

(2010) Lukas J. Goossen et al.   ISRAEL JOURNAL OF CHEMISTRY

RuH2(CO)(PPh3)3-catalyzed arylation of aromatic esters using arylboronates via C–H bond cleavages

(2010) Kentaroh Kitazawa et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis of Stilbene and Distyrylbenzene Derivatives through Rhodium-CatalyzedOrtho-Olefination and Decarboxylation of Benzoic Acids

(2010) Satoshi Mochida et al.   ORGANIC LETTERS

Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts

(2010) Lutz Ackermann et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Directed Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine−Iridium System

(2009) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylic Acids as Substrates in Homogeneous Catalysis

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Benzoic and Phenyl Acetic Acids

(2008) Dong-Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism

(2008) Ismail Özdemir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective C−H Functionalization Directed by a Removable Carboxyl Group:  Palladium-Catalyzed Vinylation at the Unusual Position of Indole and Related Heteroaromatic Rings

(2008) Atsushi Maehara et al.   ORGANIC LETTERS

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

(2008) Lutz Ackermann et al.   ORGANIC LETTERS

New catalytic transformations of carboxylic acids

(2008) Lukas J. Gooßen et al.   PURE AND APPLIED CHEMISTRY