Development of a Rhodium(II)-Catalyzed Chemoselective C(sp3)H Oxygenation

Intramolecular Cyclopropanation and C–H Insertion Reactions with Metal Carbenoids Generated from Cyclopropenes

(2015) Alexis Archambeau et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rh2(esp)2-catalyzed allylic and benzylic oxidations

(2015) Yi Wang et al.   CHEMICAL COMMUNICATIONS

Solvent and Ligand Effects Associated with the Rh(II)-Catalyzed Reactions of α-Diazo-Substituted Amido Esters

(2015) Albert Padwa et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds: Highly Enantioselective Access to Functionalized Organoboranes

(2015) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(II)-Catalyzed Nondirected Oxidative Alkenylation of Arenes: Arene Loading at One Equivalent

(2014) Harit U. Vora et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Investigation of Dirhodium-Catalyzed Intramolecular Allylic C–H Amination versus Alkene Aziridination

(2014) Xuepeng Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Analyzing Site Selectivity in Rh2(esp)2-Catalyzed Intermolecular C–H Amination Reactions

(2014) Elizabeth N. Bess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene Dirhodium(II) Complexes as Catalysts for Allylic and Benzylic Oxidations

(2013) Jaime A. S. Coelho et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Oxidative Acetoxylation of Benzylic C–H Bond Using Bidentate Auxiliary

(2013) Long Ju et al.   JOURNAL OF ORGANIC CHEMISTRY

Sequential C–H Functionalization Reactions for the Enantioselective Synthesis of Highly Functionalized 2,3-Dihydrobenzofurans

(2013) Hengbin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation of Rhodium(I) Carbenes from Ynamides and Their Reactions with Alkynes and Alkenes

(2013) Renhe Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Broadening the catalyst and reaction scope of regio- and chemoselective C–H oxygenation: a convenient and scalable approach to 2-acylphenols by intriguing Rh(ii) and Ru(ii) catalysis

(2013) Gang Shan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium catalyzed acetoxylation of benzylic C–H bonds using a bidentate picolinamide directing group

(2013) Tao Cheng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct Arylation of Primary and Secondary sp3 C–H Bonds with Diarylhyperiodonium Salts via Pd Catalysis

(2013) Fei Pan et al.   ORGANIC LETTERS

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Polycomponent Metal-Catalyzed Aliphatic, Allylic, and Benzylic Fluorination

(2012) Steven Bloom et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Intermolecular C(sp3)H Amidation

(2012) Álvaro Iglesias et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exchange–Correlation Functional with Good Accuracy for Both Structural and Energetic Properties while Depending Only on the Density and Its Gradient

(2012) Roberto Peverati et al.   Journal of Chemical Theory and Computation

C–H Bond Functionalization via Hydride Transfer: Formation of α-Arylated Piperidines and 1,2,3,4-Tetrahydroisoquinolines via Stereoselective Intramolecular Amination of Benzylic C–H Bonds

(2012) Paul A. Vadola et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh-Catalyzed Intermolecular Reactions of Cyclic α-Diazocarbonyl Compounds with Selectivity over Tertiary C–H Bond Migration

(2012) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Alkyl Ether Synthesis via Palladium-Catalyzed, Picolinamide-Directed Alkoxylation of Unactivated C(sp3)–H and C(sp2)–H Bonds at Remote Positions

(2012) Shu-Yu Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Intramolecular Allylic C–H Amination

(2012) Shauna M. Paradine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Primary-C(sp3)–H Acyloxylation at Room Temperature

(2012) Raja K. Rit et al.   ORGANIC LETTERS

Pd-Catalyzed C–H Fluorination with Nucleophilic Fluoride

(2012) Kate B. McMurtrey et al.   ORGANIC LETTERS

Palladium-catalyzed N-(2-pyridyl)sulfonyl-directed C(sp3)–H γ-arylation of amino acid derivatives

(2012) Nuria Rodríguez et al.   Chemical Science

Ruthenium-catalyzed direct arylation of C–H bonds in aromatic amides containing a bidentate directing group: significant electronic effects on arylation

(2012) Yoshinori Aihara et al.   Chemical Science

Fine Tuning of Dirhodium(II) Complexes: Exploring the Axial Modification

(2012) Alexandre F. Trindade et al.   ACS Catalysis

Highly Regioselective Copper-Catalyzed Benzylic CH Amination by N-Fluorobenzenesulfonimide

(2011) Zhikun Ni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Direct Ethynylation of C(sp3)–H Bonds in Aliphatic Carboxylic Acid Derivatives

(2011) Yusuke Ano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp2and Benzylic sp3C–H Bond Imidation

(2011) Hyun Jin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterocycle Synthesis via Direct C–H/N–H Coupling

(2011) Enrico T. Nadres et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(NHC)-Catalyzed Direct and Selective Arylation of Quinolines at the 8-Position

(2011) Jaesung Kwak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Syntheses of Azetidines, Pyrrolidines, and Indolines via Palladium Catalyzed Intramolecular Amination of C(sp3)–H and C(sp2)–H Bonds at γ and δ Positions

(2011) Gang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols

(2011) Jessica M. Hoover et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Diruthenium Catalyst for Selective, Intramolecular Allylic C–H Amination: Reaction Development and Mechanistic Insight Gained through Experiment and Theory

(2011) Mark Edwin Harvey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of Unique Heterocyclic Structures en Route to Substituted Diamines

(2011) David E. Olson et al.   ORGANIC LETTERS

Chemoselective Aromatic C–H Insertion of α-Diazo-β-ketoesters Catalyzed by Dirhodium(II) Carboxylates

(2011) Esdrey Rodriguez-Cárdenas et al.   ORGANIC LETTERS

Rhodium-Catalyzed C–H Amination. An Enabling Method for Chemical Synthesis

(2011) J. Du Bois   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Site-Directed Anchoring of an N-Heterocyclic Carbene on a Dimetal Platform: Evaluation of a Pair of Diruthenium(I) Catalysts for Carbene-Transfer Reactions from Ethyl Diazoacetate

(2011) Biswajit Saha et al.   ORGANOMETALLICS

Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2and sp3Carbon−Hydrogen Bonds

(2010) Dmitry Shabashov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Method for the Synthesis of Carbazoles via Tandem C−H Functionalization and C−N Bond Formation

(2008) W. C. Peter Tsang et al.   JOURNAL OF ORGANIC CHEMISTRY

Site-Selective sp2and Benzylic sp3Palladium-Catalyzed Direct Arylation

(2008) Louis-Charles Campeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One-Pot Synthesis of Highly Functionalized Pyridines via a Rhodium Carbenoid Induced Ring Expansion of Isoxazoles

(2008) James R. Manning et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Chiral Rhodium Carboxamidate Catalyst for Enantioselective C−H Amination

(2008) David N. Zalatan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–heteroatom bond formation catalysed by organometallic complexes

(2008) John F. Hartwig   NATURE

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Efficient route to 2H-1,3-oxazines through ring expansion of isoxazoles by rhodium carbenoids

(2008) James R. Manning et al.   TETRAHEDRON

A mechanistic analysis of the Rh-catalyzed intramolecular C–H amination reaction

(2008) Kristin Williams Fiori et al.   TETRAHEDRON

Toward a Synthetically Useful Stereoselective C−H Amination of Hydrocarbons

(2007) Chungen Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY