A theoretical study on the mechanism of ruthenium(ii)-catalyzed phosphoryl-directed ortho-selective C–H bond activations: the phosphoryl hydroxy group triggered Ru(ii)/Ru(0) catalytic cycle

Recent progress toward organophosphorus compounds based on phosphorus-centered radical difunctionalizations

(2017) Yuzhen Gao et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

Rhodium(III)-Catalyzed Enantiotopic C−H Activation Enables Access to P -Chiral Cyclic Phosphinamides

(2016) Yang Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π-Conjugated phospholes and their incorporation into devices: components with a great deal of potential

(2016) M. P. Duffy et al.   CHEMICAL SOCIETY REVIEWS

Origins of Stereoselectivity of Chiral Vicinal Diamine-Catalyzed Aldol Reactions

(2016) Adam Simon et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism of Nickel-Catalyzed Selective C–N Bond Activation in Suzuki-Miyaura Cross-Coupling of Amides: A Theoretical Investigation

(2016) Liu (Leo) Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Computational Revisit to the β-Carbon Elimination Step in Rh(III)-Catalyzed C–H Activation/Cycloaddition Reactions of N-Phenoxyacetamide and Cyclopropenes

(2016) Jiajia Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Origins of Selectivity and General Model for Chiral Phosphoric Acid-Catalyzed Oxetane Desymmetrizations

(2016) Pier Alexandre Champagne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Exploration of RhIII/RhV and RhIII/RhI Catalysis in Rhodium(III)-Catalyzed C–H Activation Reactions of N-Phenoxyacetamides with Alkynes

(2016) Yun-Fang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Direct C6-Arylation of Indoles

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Synthesis of Benzo[b]phosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides

(2016) Yuto Unoh et al.   ORGANIC LETTERS

Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations

(2016) Meera Mehta et al.   ORGANOMETALLICS

Mechanism, catalysis and predictions of 1,3,2-diazaphospholenes: theoretical insight into highly polarized P–X bonds

(2016) Liu Liu et al.   Organic Chemistry Frontiers

Ru-Catalyzed selective C–H oxidative olefination with N-heteroarenes directed by pivaloyl amide

(2016) Li Zhang et al.   Organic Chemistry Frontiers

Cationic Two-Coordinate Complexes of Pd(I) and Pt(I) Have Longer Metal-Ligand Bonds Than Their Neutral Counterparts

(2016) Morgan C. MacInnis et al.   Chem

Exploration of New Chemical Reactivities for Sustainable Molecular Transformations

(2016) Chao-Jun Li   Chem

Catalytic Asymmetric Dearomatization by Transition-Metal Catalysis: A Method for Transformations of Aromatic Compounds

(2016) Chao Zheng et al.   Chem

A Singlet Phosphinidene Stable at Room Temperature

(2016) Liu Liu et al.   Chem

Phosphaannulation of Aryl- and Benzylphosphonic Acids with Unactivated AlkenesviaPalladium-Catalyzed CH Activation/Oxidative Cyclization Reaction

(2015) Woo Hyung Jeon et al.   ADVANCED SYNTHESIS & CATALYSIS

The Mechanism of NO Bond Cleavage in Rhodium-Catalyzed CH Bond Functionalization of QuinolineN-oxides with Alkynes: A Computational Study

(2015) Yingzi Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Suzuki-Miyaura Cross-Coupling for the Synthesis of Chiral Biaryl Compounds as Potential Monophosphine Ligands

(2015) Yan-Na Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

RhV-Nitrenoid as a Key Intermediate in RhIII-Catalyzed Heterocyclization by CH Activation: A Computational Perspective on the Cycloaddition of Benzamide and Diazo Compounds

(2015) Tao Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Insights into the Palladium-Catalyzed Aziridination of Aliphatic Amines by C–H Activation

(2015) Adam P. Smalley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Formal Dehydrative [4 + 2] Cycloaddition of Enamides and Alkynes for the Synthesis of Highly Substituted Pyridines: Reaction Development and Mechanistic Study

(2015) Jicheng Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Enantioselective Synthesis of P-Stereogenic Phosphinamides via Desymmetric C–H Arylation

(2015) Zhi-Jun Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and DFT Studies Explain Solvent Control of C–H Activation and Product Selectivity in the Rh(III)-Catalyzed Formation of Neutral and Cationic Heterocycles

(2015) David L. Davies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in the ruthenium-catalyzed hydroarylation of alkynes with aromatics: synthesis of trisubstituted alkenes

(2015) Rajendran Manikandan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Alkenylation of Phosphacoumarins via Aerobic Oxidative Heck Reactions and Their Synthetic Application to Fluorescent Benzophosphacoumarins

(2015) Cheol-Eui Kim et al.   ORGANIC LETTERS

Pd(II)-Catalyzed P(O)R1R2-Directed Asymmetric C–H Activation and Dynamic Kinetic Resolution for the Synthesis of Chiral Biaryl Phosphates

(2015) Yan-Na Ma et al.   ORGANIC LETTERS

N-phosphoryl amino acid models for P-N bonds in prebiotic chemical evolution

(2015) Feng Ni et al.   Science China-Chemistry

Palladium-catalyzed R2(O)P-directed C(sp2)-H activation

(2015) Hongyu Zhang et al.   Science China-Chemistry

Recent advances in sulfur- and phosphorous-centered radical reactions for the formation of S–C and P–C bonds

(2015) Xiang-Qiang Pan et al.   TETRAHEDRON

Silver Migration Facilitates Isocyanide-Alkyne [3 + 2] Cycloaddition Reactions: Combined Experimental and Theoretical Study

(2015) Xiaotian Qi et al.   ACS Catalysis

Cobalt-Catalyzed, Aminoquinoline-Directed Functionalization of Phosphinic Amide sp2 C–H Bonds

(2015) Tung Thanh Nguyen et al.   ACS Catalysis

Rhodium(III)-Catalyzed Direct Coupling of Arylphosphine Derivatives with Heterobicyclic Alkenes: A Concise Route to Biarylphosphines and Dibenzophosphole Derivatives

(2015) Yuto Unoh et al.   ACS Catalysis

Palladacycles derived from arylphosphinamides for mild Suzuki–Miyaura cross-couplings

(2015) Guo-Jie Wu et al.   RSC Advances

Weakly Coordinating Directing Groups for Ruthenium(II)- Catalyzed CH Activation

(2014) Suman De Sarkar et al.   ADVANCED SYNTHESIS & CATALYSIS

AgSbF6-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes

(2014) Minsik Min et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed R2(O)P directed C(sp2)–H acetoxylation

(2014) Heng Zhang et al.   CHEMICAL COMMUNICATIONS

PdII-Catalyzed Mild CHorthoArylation and Intramolecular Amination Oriented by a Phosphinamide Group

(2014) Jing Guan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Regioselective C–H Alkenylation of Phenylphosphine Sulfides

(2014) Yuki Yokoyama et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism, Reactivity, and Selectivity in Rh(III)-Catalyzed Phosphoryl-Directed Oxidative C–H Activation/Cyclization: A DFT Study

(2014) Liu Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

P(O)R2 directed Pd(ii)-catalyzed C(sp2)–H acylation

(2014) Yan-Na Ma et al.   Organic Chemistry Frontiers

Phosphinate Chemistry in the 21st Century: A Viable Alternative to the Use of Phosphorus Trichloride in Organophosphorus Synthesis.

(2013) Jean-Luc Montchamp   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-catalyzed direct C-3 oxidative alkenylation of phosphachromones

(2013) Dongjin Kang et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed oxidative coupling through C–H activation and annulation directed by phosphonamide and phosphinamide groups

(2013) Sangjune Park et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed P(O)R2 directed C–H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

(2013) Rong-Bin Hu et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Oxidative C-H Activation/Cyclization for the Synthesis of Phosphaisocoumarins and Phosphorous 2-Pyrones

(2013) Youngchul Park et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Insight into the Nickel-Catalyzed Cross-Coupling of Aryl Phosphates with Arylboronic Acids: Potassium Phosphate is Not a Spectator Base but is Involved in the Transmetalation Step in the Suzuki-Miyaura Reaction

(2013) Liu Liu et al.   Chemistry-An Asian Journal

Double Role of the Hydroxy Group of Phosphoryl in Palladium(II)-Catalyzed ortho-Olefination: A Combined Experimental and Theoretical Investigation

(2013) Liu Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed C–H Activation/Cyclization for the Synthesis of Phosphaisocoumarins

(2013) Youngchul Park et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium(II)-Catalyzed Ortho-Arylation of Benzylic Phosphonic Monoesters Using Potassium Aryltrifluoroborates

(2013) Xiangjian Meng et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed ortho-Alkenylation of Phenylphosphine Oxides through Regio- and Stereoselective Alkyne Insertion into C–H Bonds

(2013) Masaki Itoh et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Meta-Selective C–H Bond Activation with a Nitrile-Containing Template: Computational Study on Mechanism and Origins of Selectivity

(2013) Yun-Fang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Role of N-Acyl Amino Acid Ligands in Pd(II)-Catalyzed Remote C–H Activation of Tethered Arenes

(2013) Gui-Juan Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal-Catalyzed Efficient and Green Transformations of P(O)-H Compounds to Functional Organophosphorus Compounds

(2013) Qing Xu et al.   MINI-REVIEWS IN MEDICINAL CHEMISTRY

Rhodium(III)-catalyzed Oxidative Coupling through C–H Bond Cleavage Directed by Phosphinoxy Groups

(2013) Yuto Unoh et al.   ORGANIC LETTERS

Palladium-Catalyzed C(sp2 and sp3)–H Activation/C–O Bond Formation: Synthesis of Benzoxaphosphole 1- and 2-Oxides

(2013) Dahan Eom et al.   ORGANIC LETTERS

Pd(II)-Catalyzed ortho-Arylation of Aryl Phosphates and Aryl Hydrogen Phosphates with Diaryliodonium Triflates

(2013) Li Yan Chan et al.   ORGANIC LETTERS

Synthesis of Phosphaisocoumarins through Rhodium-Catalyzed Cyclization Using Alkynes and Arylphosphonic Acid Monoesters

(2013) Jungmin Seo et al.   ORGANIC LETTERS

Pd(II)-Catalyzed C(sp2)–H Hydroxylation with R2(O)P-Coordinating Group

(2013) Hong-Yu Zhang et al.   ORGANIC LETTERS

Phosphoryl-Related Directing Groups in Rhodium(III) Catalysis: A General Strategy to Diverse P-Containing Frameworks

(2013) Dongbing Zhao et al.   ORGANIC LETTERS

Oxidative ortho-alkenylation of arylphosphine oxides by rhodium-catalyzed C–H bond twofold cleavage

(2013) Juntae Mo et al.   RSC Advances

Surface Modification Using Phosphonic Acids and Esters

(2012) Clémence Queffélec et al.   CHEMICAL REVIEWS

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Convergent Modulation of Singlet and Triplet Excited States of Phosphine-Oxide Hosts through the Management of Molecular Structure and Functional-Group Linkages for Low-Voltage-Driven Electrophosphorescence

(2012) Chunmiao Han et al.   CHEMISTRY-A EUROPEAN JOURNAL

Short-Axis Substitution Approach Selectively Optimizes Electrical Properties of Dibenzothiophene-Based Phosphine Oxide Hosts

(2012) Chunmiao Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Ir(cod)2]BARF-Catalyzed C–H Bond Alkenylation and Alkylation of Ferrocenes

(2012) Satoshi Takebayashi et al.   ORGANOMETALLICS

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Review on Modern Advances of Chemical Methods for the Introduction of a Phosphonic Acid Group

(2011) Charles S. Demmer et al.   CHEMICAL REVIEWS

Recent developments in metal catalyzed asymmetric addition of phosphorus nucleophiles

(2011) Depeng Zhao et al.   CHEMICAL SOCIETY REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Direct Phosphonylation of Aromatic Azaheterocycles

(2009) Sarah Van der Jeught et al.   CHEMICAL REVIEWS

Mechanisms of C–H bond activation: rich synergy between computation and experiment

(2009) Youcef Boutadla et al.   DALTON TRANSACTIONS

Reduction of Tertiary Phosphine Oxides with DIBAL-H

(2008) Carl A. Busacca et al.   JOURNAL OF ORGANIC CHEMISTRY