C–H bond cleavage occurring on a Rh(v) intermediate: a theoretical study of Rh-catalyzed arene azidation

Insights into disilylation and distannation: sequence influence and ligand/steric effects on Pd-catalyzed difunctionalization of carbenes

(2018) Xiaoyu Yue et al.   DALTON TRANSACTIONS

Ni(i)–Ni(iii) vs. Ni(ii)–Ni(iv): mechanistic study of Ni-catalyzed alkylation of benzamides with alkyl halides

(2018) Yingzi Li et al.   Organic Chemistry Frontiers

The mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO2: a computational study

(2018) Lei Zhu et al.   Organic Chemistry Frontiers

Mechanistic Study of the Fluoride-Induced Activation of a Kobayashi Precursor: Pseudo-SN 2 Pathway via a Pentacoordinated Silicon Ate Complex

(2017) Song Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Solvent Mediating a Switch in the Mechanism for Rhodium(III)-Catalyzed Carboamination/Cyclopropanation Reactions between N-Enoxyphthalimides and Alkenes

(2017) Yang-Yang Xing et al.   INORGANIC CHEMISTRY

Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C–H activation

(2017) Natthawat Semakul et al.   Chemical Science

Plausible Rh(V) Intermediates in Catalytic C–H Activation Reactions

(2017) Suhelen Vásquez-Céspedes et al.   ACS Catalysis

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C–H activation and ring scission

(2016) Fen Wang et al.   CHEMICAL SOCIETY REVIEWS

Mechanism of the rhodium(iii)-catalyzed alkenylation reaction of N-phenoxyacetamide with styrene or N-tosylhydrazone: a computational study

(2016) Zhiping Qiu et al.   DALTON TRANSACTIONS

Effective Chirality Transfer in [3+2] Reaction between Allenyl-Rhodium and Enal: Mechanistic Study Based on DFT Calculations

(2016) Xiaotian Qi et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism of Rhodium-Catalyzed Formyl Activation: A Computational Study

(2016) Xiaoling Luo et al.   JOURNAL OF ORGANIC CHEMISTRY

Computational Revisit to the β-Carbon Elimination Step in Rh(III)-Catalyzed C–H Activation/Cycloaddition Reactions of N-Phenoxyacetamide and Cyclopropenes

(2016) Jiajia Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Computational Exploration of RhIII/RhV and RhIII/RhI Catalysis in Rhodium(III)-Catalyzed C–H Activation Reactions of N-Phenoxyacetamides with Alkynes

(2016) Yun-Fang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Rh(III)-catalyzed cyclopropanation using N-enoxyphthalimides and alkenes: Insights from DFT calculations

(2016) Jiaojiao Deng et al.   TETRAHEDRON

Rh(iii)-catalyzed diastereoselective C–H bond addition/cyclization cascade of enone tethered aldehydes

(2016) Jeffrey A. Boerth et al.   Chemical Science

Synthesis of Cyclopentadienols by Rhodium-Catalyzed C–H Activation of 8-Formylquinolines and [2+2+1] Carbocyclization with Alkynes

(2016) Xingwei Li et al.   ACS Catalysis

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium(III)-Catalyzed [3+2]/[5+2] Annulation of 4-Aryl 1,2,3-Triazoles with Internal Alkynes through Dual C(sp2)H Functionalization

(2015) Yuan Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

RhV-Nitrenoid as a Key Intermediate in RhIII-Catalyzed Heterocyclization by CH Activation: A Computational Perspective on the Cycloaddition of Benzamide and Diazo Compounds

(2015) Tao Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

DFT Studies on the Mechanism of the Rhodium(III)-Catalyzed C–H Activation of N-Phenoxyacetamide

(2015) Juan Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Understanding of the Divergent Reactivity of Cyclopropenes in Rh(III)-Catalyzed C–H Activation/Cycloaddition Reactions of N-Phenoxyacetamide and N-Pivaloxybenzamide

(2015) Wei Guo et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp2)–H Functionalization/Annulation Reaction

(2015) Jun Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Role of Rh(III) Catalyst Enables Regioselective Halogenation of (Electron-Rich) Heterocycles

(2015) Nils Schröder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalysed syn-carboamination of alkenes via a transient directing group

(2015) Tiffany Piou et al.   NATURE

Mechanistic Understanding of the Aryl-Dependent Ring Formations in Rh(III)-Catalyzed C–H Activation/Cycloaddition of Benzamides and Methylenecyclopropanes by DFT Calculations

(2015) Wei Guo et al.   ORGANOMETALLICS

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Rhodium(III)-Catalyzed Regioselective Direct C-2 Alkenylation of Indoles Assisted by the Removable N-(2-Pyrimidyl) Group

(2014) Binwei Gong et al.   ADVANCED SYNTHESIS & CATALYSIS

An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and AlkenesviaCH Functionalization

(2014) Lei Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Transannulation of Cyclopropenes withN-Phenoxyacetamides through CH Activation

(2014) Hang Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed CH Alkynylation of Arenes at Room Temperature

(2014) Chao Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Extended π-Systems through C-H Activation

(2014) Yasutomo Segawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(iii)-Catalyzed intramolecular redox-neutral cyclization of alkenes via C–H activation

(2014) Zhuangzhi Shi et al.   CHEMICAL COMMUNICATIONS

Rh-Catalyzed oxidative C–H activation/annulation: converting anilines to indoles using molecular oxygen as the sole oxidant

(2014) Guoying Zhang et al.   CHEMICAL COMMUNICATIONS

Metal-Catalyzed Annulation Reactions for π-Conjugated Polycycles

(2014) Tienan Jin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Combined Experimental and Computational Investigations of Rhodium- and Ruthenium-Catalyzed C–H Functionalization of Pyrazoles with Alkynes

(2014) Andrés G. Algarra et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism, Reactivity, and Selectivity in Rh(III)-Catalyzed Phosphoryl-Directed Oxidative C–H Activation/Cyclization: A DFT Study

(2014) Liu Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Reactivity for the Diels–Alder Reaction of Cumulenes: A Distortion-Interaction Analysis along the Reaction Pathway

(2014) Song Liu et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Asymmetric Synthesis of α-Branched Amines via Rh(III)-Catalyzed C–H Bond Functionalization

(2014) Apiwat Wangweerawong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of the Rhodium-Catalyzed Direct C–H Amination Reaction Using Azides as the Nitrogen Source

(2014) Sae Hume Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators

(2014) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal Carbene Insertion into C–C Bond: Rh(I)-Catalyzed Reaction of Benzocyclobutenols with Diazoesters

(2014) Ying Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Regioselective Functionalization of C–H Bonds of Naphthylcarbamates for Oxidative Annulation with Alkynes

(2014) Xuan Zhang et al.   ORGANIC LETTERS

Rh-Catalyzed Sequential Oxidative C–H and N–N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature

(2014) Wenjia Han et al.   ORGANIC LETTERS

Mild Synthesis of Chalcones via Rhodium(III)-Catalyzed C–C Coupling of Arenes and Cyclopropenones

(2014) Songjie Yu et al.   ORGANIC LETTERS

Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bonds

(2014) Xi-Sha Zhang et al.   Chemical Science

Rhodium(III)-Catalyzed Azidation and Nitration of Arenes by CH Activation

(2013) Fang Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computational study on mechanism of Rh(iii)-catalyzed oxidative Heck coupling of phenol carbamates with alkenes

(2013) Qi Zhang et al.   DALTON TRANSACTIONS

Theoretical Studies of Ring-Opening Reactions of Phenylcyclobutabenzenol and Its Reactions with Alkynes Catalyzed by Rhodium Complexes

(2013) Yang Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism of Rhodium-Catalyzed Carbon–Silicon Bond Cleavage for the Synthesis of Benzosilole Derivatives: A Computational Study

(2013) Zhaoyuan Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

sp3–sp2 vs sp3–sp3 C–C Site Selectivity in Rh-Catalyzed Ring Opening of Benzocyclobutenol: A DFT Study

(2013) Lina Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Rh/O2 Catalytic System for Oxidative C–H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen

(2013) Guoying Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DMF as Carbon Source: Rh-Catalyzed α-Methylation of Ketones

(2013) Yang Li et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–H Activation and Amidation of Arenes Using N-Arenesulfonated Imides as Amidating Reagents

(2013) Songjie Yu et al.   ORGANIC LETTERS

Rh[III]-Catalyzed C–H Amidation Using Aroyloxycarbamates To Give N-Boc Protected Arylamines

(2013) Christoph Grohmann et al.   ORGANIC LETTERS

Rh(iii)-catalyzed C–H activation–desymmetrization of diazabicycles with arenes: facile synthesis of functionalized cyclopentenes

(2013) Yan Zhang et al.   Chemical Science

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Long-range corrected hybrid meta-generalized-gradient approximations with dispersion corrections

(2012) You-Sheng Lin et al.   JOURNAL OF CHEMICAL PHYSICS

Benchmark Database for Ylidic Bond Dissociation Energies and Its Use for Assessments of Electronic Structure Methods

(2012) Yan Zhao et al.   Journal of Chemical Theory and Computation

Ab Initio Calculations of the Interaction between CO2 and the Acetate Ion

(2012) Janice A. Steckel   JOURNAL OF PHYSICAL CHEMISTRY A

Rh(III)-Catalyzed Regioselective Synthesis of Pyridines from Alkenes and α,β-Unsaturated Oxime Esters

(2012) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Yielding, Versatile, and Practical [Rh(III)Cp*]-Catalyzed Ortho Bromination and Iodination of Arenes

(2012) Nils Schröder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Performance of the M11 and M11-L density functionals for calculations of electronic excitation energies by adiabatic time-dependent density functional theory

(2012) Roberto Peverati et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C–H Functionalization

(2011) Liang Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Improving the Accuracy of Hybrid Meta-GGA Density Functionals by Range Separation

(2011) Roberto Peverati et al.   Journal of Physical Chemistry Letters

Rhodium(III)-Catalyzed Arylation of Boc-Imines via C−H Bond Functionalization

(2011) Andy S. Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, structure and biological activity of diorganotin derivatives with pyridyl functionalized bis(pyrazol-1-yl)methanes

(2010) Fang-Lin Li et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Continuous surface charge polarizable continuum models of solvation. I. General formalism

(2010) Giovanni Scalmani et al.   JOURNAL OF CHEMICAL PHYSICS

Conjugated Diene-Assisted Allylic C−H Bond Activation: Cationic Rh(I)-Catalyzed Syntheses of Polysubstituted Tetrahydropyrroles, Tetrahydrofurans, and Cyclopentanes from Ene-2-Dienes

(2010) Qian Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Oxidative Coupling ofN-Aryl-2-aminopyridine with Alkynes and Alkenes

(2010) Jinlei Chen et al.   ORGANIC LETTERS

Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes

(2010) Ling Li et al.   ORGANOMETALLICS

Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C–H bond cleavage

(2009) Tatsuya Fukutani et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Mono- and Divinylation of 1-Phenylpyrazoles and Related Compounds via Regioselective C−H Bond Cleavage

(2009) Nobuyoshi Umeda et al.   JOURNAL OF ORGANIC CHEMISTRY

High Oxidation State Rhodium and Iridium Bis(silyl)dihydride Complexes Supported by a Chelating Pyridyl-Pyrrolide Ligand

(2009) Jennifer L. McBee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Five-Coordinate Dihydridosilyl Platinum(IV) Complexes Supported by a Chelating Monoanionic Nitrogen-Based Ligand

(2009) Jennifer L. McBee et al.   ORGANOMETALLICS

Monomeric and Linear Polymeric Samarium(II) Complexes of the 2-(N-Arylimino)pyrrolide Ligand

(2009) Jingjun Hao et al.   ORGANOMETALLICS

An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C−H Activation with [Cp*MCl2]2(M = Rh, Ir)

(2008) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY