China's flourishing synthetic organofluorine chemistry: innovations in the new millennium
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Title
China's flourishing synthetic organofluorine chemistry: innovations in the new millennium
Authors
Keywords
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Journal
National Science Review
Volume 4, Issue 3, Pages 303-325
Publisher
Oxford University Press (OUP)
Online
2017-06-05
DOI
10.1093/nsr/nwx058
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- Copper-mediated difluoromethylation of electron-poor aryl iodides at room temperature
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- Palladium-Catalyzed Desulfitative Direct CH Arylation of Electron-Deficient Polyfluoroarenes with Sodium Arenesulfinates
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- Highly Enantioselective Construction of 3-Hydroxy Oxindoles through a Decarboxylative Aldol Addition of Trifluoromethyl α-Fluorinatedgem-Diols toN-Benzyl Isatins
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- Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols
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- Copper-Catalyzed Regioselective Fluorination of Allylic Halides
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- Palladium-CatalyzedOrtho-Selective CF Activation of Polyfluoroarenes with Triethylsilane: A Facile Access to Partially Fluorinated Aromatics
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- Silver-Catalyzed Radical Aminofluorination of Unactivated Alkenes in Aqueous Media
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- Silver-Catalyzed Radical Phosphonofluorination of Unactivated Alkenes
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- Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group
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- Highly Enantioselective Construction of Trifluoromethylated All-Carbon Quaternary Stereocenters via Nickel-Catalyzed Friedel–Crafts Alkylation Reaction
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- Copper- and Iron-Catalyzed Decarboxylative Tri- and Difluoromethylation of α,β-Unsaturated Carboxylic Acids with CF3SO2Na and (CF2HSO2)2Zn via a Radical Process
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- Efficient SN2 Fluorination of Primary and Secondary Alkyl Bromides by Copper(I) Fluoride Complexes
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- Copper-catalyzed fluorination of 2-pyridyl aryl bromides
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- Direct monofluoromethylation of O-, S-, N-, and P-nucleophiles with PhSO(NTs)CH2F: the accelerating effect of α-fluorine substitution
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- Silver-Assisted Difunctionalization of Terminal Alkynes: Highly Regio- and Stereoselective Synthesis of Bromofluoroalkenes
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- A Facile Parallel Synthesis of Trifluoroethyl-Substituted Alkynes
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- Enantioselective Synthesis of β,γ-Unsaturated α-Fluoroesters Catalyzed by N-Heterocyclic Carbenes
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- An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides
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- Organocatalytic Asymmetric Fluorination/Semipinacol Rearrangement: An Efficient Approach to Chiral β-Fluoroketones
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- Hypervalent Iodine Mediated para-Selective Fluorination of Anilides
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- Selective Palladium-Catalyzed C–F Activation/Carbon–Carbon Bond Formation of Polyfluoroaryl Oxazolines
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- Cu(ClO4)2-Mediated Arene C–H Bond Halogenations of Azacalixaromatics Using Alkali Metal Halides as Halogen Sources
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- Tuning the Reactivity of Difluoromethyl Sulfoximines from Electrophilic to Nucleophilic: Stereoselective Nucleophilic Difluoromethylation of Aryl Ketones
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- From Olefination to Alkylation: In-Situ Halogenation of Julia–Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds
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- Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature
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- Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution
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- Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter
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- Copper-Mediated Oxidative Cross-Coupling Reaction of Terminal Alkynes with α-Silyldifluoromethylphosphonates: An Efficient Method for α,α-Difluoropropargylphosphonates
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- Au(I)-Catalyzed Intramolecular Hydroamination of the Fluorinated N′-Aryl-N-Propargyl Amidines: Mild Conditions for the Synthesis of 2-Fluoroalkyl Imidazole Derivatives
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- Copper-catalyzed olefinic trifluoromethylation of enamides at room temperature
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- Silver-Catalyzed Intramolecular Aminofluorination of Activated Allenes
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- Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters
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- Copper-Catalyzed Trifluoromethylation of Unactivated Olefins
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- Copper-Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts
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- Direct Palladium-Catalyzed Intermolecular Allylation of Highly Electron-Deficient Polyfluoroarenes
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- Synthetic approaches to monofluoroalkenes
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- Palladium-Catalyzed Oxidative Trifluoromethylation of Indoles at Room Temperature
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- Enantioselective Friedel−Crafts Alkylation of Indoles with Trifluoroethylidene Malonates by Copper−Bis(oxazoline) Complexes: Construction of Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Center
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- Optically Pure Polyfluoroalkanesulfinamides: Synthesis and Application as Promising and Monitorable Chiral Auxiliaries
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- β-(Trifluoromethyl)vinyl Sulfonium Salts: Preparation and Reactions with Active Methylene and Methenyl Compounds
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- Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation
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- Palladium-Catalyzed Tandem Fluorination and Cyclization of Enynes
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- Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at Ambient or Low Temperature
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- Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent
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- Pd(OAc)2Catalyzed Olefination of Highly Electron-Deficient Perfluoroarenes
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- Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes
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- Difluoromethyl 2-Pyridyl Sulfone: A Newgem-Difluoroolefination Reagent for Aldehydes and Ketones
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- Palladium-Catalyzed Cross-Coupling of Polyfluoroarenes with Simple Arenes
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- Highly Stereoselective Synthesis of Monofluoroalkenes from α-Fluorosulfoximines and Nitrones
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- Copper-Catalyzed Decarboxylative Cross-Coupling of Potassium Polyfluorobenzoates with Aryl Iodides and Bromides
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- Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes
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- Synergistic Effect of a Low-Valent Cobalt Complex and a Trimethylphosphine Ligand on Selective C−F Bond Activation of Perfluorinated Toluene
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- Cinchona alkaloid-derived quaternary ammonium salt combined with NaH: a facile catalyst system for the asymmetric trifluoromethylation of ketones
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- An Efficient Approach for Monofluorination via Highly Regioselective Fluorohydroxylation Reaction of 3-Aryl-1,2-allenes with Selectfluor
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