Introduction of Fluorine and Fluorine-Containing Functional Groups

Molecular Design of Photovoltaic Materials for Polymer Solar Cells: Toward Suitable Electronic Energy Levels and Broad Absorption

(2012) Yongfang Li   ACCOUNTS OF CHEMICAL RESEARCH

Thiourea-Catalyzed Enantioselective Fluorination of β-Keto Esters

(2012) Junxing Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Photo-fluorodecarboxylation of 2-Aryloxy and 2-Aryl Carboxylic Acids

(2012) Joe C. T. Leung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluoroform-Derived CuCF3for Low-Cost, Simple, Efficient, and Safe Trifluoromethylation of Aryl Boronic Acids in Air

(2012) Petr Novák et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation of Allylsilanes

(2012) Ryo Shimizu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes

(2012) Joy M. Racowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Di- and Trifluoromethylation of α,β-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations

(2012) Zhengbiao He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Oxidative Fluorination of Phenols with [18F]Fluoride

(2012) Zhanghua Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Promoted Trifluoromethylation of Primary and Secondary Alkylboronic Acids

(2012) Jun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical Fluorination Using Alkali-Metal Fluorides

(2012) Takahiro Sawamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides

(2012) François Baert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Electrophilic N-Trifluoromethylation of Azoles by a Hypervalent Iodine Reagent

(2012) Katrin Niedermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ortho-Trifluoromethylation of Functionalized Aromatic Triazenes

(2012) Andreas Hafner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Substitution of Two Fluorine Atoms in a Trifluoromethyl Group: Regioselective Synthesis of 3-Fluoropyrazoles

(2012) Kohei Fuchibe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Mono-Fluorination of α-Keto Esters: Synthesis of Optically Active β-Fluoro-α-Hydroxy and β-Fluoro-α-Amino Acid Derivatives

(2012) Shoko Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Difluoromethylation of (Hetero)aryl Iodides and β-Styryl Halides with Tributyl(difluoromethyl)stannane

(2012) G. K. Surya Prakash et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur

(2012) Chao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates

(2012) Andrew T. Parsons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Doubly Axially Chiral Phosphoric Acid Catalyst for the Asymmetric Tandem Oxyfluorination of Enamides

(2012) Takashi Honjo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Enantioselective Nucleophilic Fluorination: Ring Opening of Oxabicyclic Alkenes

(2012) Jiangtao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

(2012) Yi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides: A Simple Approach to Allylic Trifluoromethylation

(2012) Yoshihiro Miyake et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trifluoromethylation of Allylsilanes under Copper Catalysis

(2012) Satoshi Mizuta et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Trifluoromethylation of Arylboronates with Shelf-Stable Potassium (Trifluoromethyl)trimethoxyborate

(2012) Bilal A. Khan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Nucleophilic Monofluorobenzylation of Carbonyl Compounds: Synthesis of Enantiopure vic-Fluorohydrins and α-Fluorobenzylketones

(2012) Yolanda Arroyo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Trifluoromethylthiolations of Aryl Boronic Acids Using a Copper/O2-Based Protocol

(2012) Cheng-Pan Zhang et al.   Chemistry-An Asian Journal

Substrate Range of the Titanium TADDOLate Catalyzed Asymmetric Fluorination of Activated Carbonyl Compounds

(2012) Andreas Bertogg et al.   HELVETICA CHIMICA ACTA

Direct trifluoro-methoxylation of aromatics with perfluoro-methyl-hypofluorite

(2012) Francesco Venturini et al.   JOURNAL OF FLUORINE CHEMISTRY

Synthetic chemistry and biological activity of pentafluorosulphanyl (SF5) organic molecules

(2012) Stefano Altomonte et al.   JOURNAL OF FLUORINE CHEMISTRY

Carrier-effect on palladium-catalyzed, nucleophilic18F-fluorination of aryl triflates

(2012) Jens Cardinale et al.   JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS

Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkynes and Aryl Boronic Acids Using (Trifluoromethyl)trimethylsilane

(2012) Xueliang Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Fluorination of Unprotected 3-Substituted Oxindoles: One-Step Synthesis of BMS 204352 (MaxiPost)

(2012) Jun Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Organofluorine Chemistry: Synthesis and Conformation of Vicinal Fluoromethylene Motifs

(2012) David O’Hagan   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed Ortho Trifluoromethylation of Arenes and Insights into the Coordination Mode of Acidic Amide Directing Groups

(2012) Xing-Guo Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorine Transfer to Alkyl Radicals

(2012) Montserrat Rueda-Becerril et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning the Reactivity of Difluoromethyl Sulfoximines from Electrophilic to Nucleophilic: Stereoselective Nucleophilic Difluoromethylation of Aryl Ketones

(2012) Xiao Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur

(2012) Chao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Mediated Oxidative Fluorination for PET with Aqueous [18F] Fluoride

(2012) Eunsung Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Olefination to Alkylation: In-Situ Halogenation of Julia–Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds

(2012) Yanchuan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Simple Method for Asymmetric Trifluoromethylation of N-Acyl Oxazolidinones via Ru-Catalyzed Radical Addition to Zirconium Enolates

(2012) Aaron T. Herrmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Fluorination of Aryl Iodides

(2012) Patrick S. Fier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature

(2012) Qingqing Qi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Reagent for Direct Difluoromethylation

(2012) Yuta Fujiwara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Difluoromethylation of Aryl and Vinyl Iodides

(2012) Patrick S. Fier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage

(2012) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Fluorination of Enamides: Access to α-Fluoroimines Using an Anionic Chiral Phase-Transfer Catalyst

(2012) Robert J. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Feng Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I

(2012) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Promoted Sulfenylation of sp2 C–H Bonds

(2012) Ly Dieu Tran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Oxytrifluoromethylation of Unactivated Alkenes

(2012) Rong Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters

(2012) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter

(2012) Mingyou Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical and innate carbon–hydrogen functionalization of heterocycles

(2012) Yuta Fujiwara et al.   NATURE

Expedient synthesis of α-substituted fluoroethenes

(2012) Samir K. Mandal et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ag(I)-Catalyzed Aminofluorination of Alkynes: Efficient Synthesis of 4-Fluoroisoquinolines and 4-Fluoropyrrolo[α]isoquinolines

(2012) Tao Xu et al.   ORGANIC LETTERS

Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group

(2012) Yanchuan Zhao et al.   ORGANIC LETTERS

Simple Synthesis of β-Trifluoromethylstyrenes Using (E)-Trimethyl-(3,3,3-trifluoroprop-1-enyl)silane

(2012) Masaaki Omote et al.   ORGANIC LETTERS

A Domino Approach of Heck Coupling for the Synthesis of β-Trifluoromethylstyrenes

(2012) G. K. Surya Prakash et al.   ORGANIC LETTERS

Trifluoromethylation of Propargylic Halides and Trifluoroacetates Using (Ph3P)3Cu(CF3) Reagent

(2012) Tony S. N. Zhao et al.   ORGANIC LETTERS

Palladium-Catalyzed Allylic Fluorination of Cinnamyl Phosphorothioate Esters

(2012) Andrew M. Lauer et al.   ORGANIC LETTERS

Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkenes Using Nucleophilic CF3SiMe3: Efficient C(sp3)–CF3 Bond Formation

(2012) Lingling Chu et al.   ORGANIC LETTERS

Practical Method for the Cu-Mediated Trifluoromethylation of Arylboronic Acids with CF3 Radicals Derived from NaSO2CF3 and tert-Butyl Hydroperoxide (TBHP)

(2012) Yingda Ye et al.   ORGANIC LETTERS

Pd-Catalyzed C–H Fluorination with Nucleophilic Fluoride

(2012) Kate B. McMurtrey et al.   ORGANIC LETTERS

Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes

(2012) Pär G. Janson et al.   ORGANIC LETTERS

Copper Catalyzed Cross-Coupling of Iodobenzoates with Bromozinc-difluorophosphonate

(2012) Zhang Feng et al.   ORGANIC LETTERS

Selective Continuous Flow Processes Using Fluorine Gas

(2012) Christopher B. McPake et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Oxygen-Bound Trifluoromethoxide Complexes of Copper and Gold

(2012) Cheng-Pan Zhang et al.   ORGANOMETALLICS

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Hydrophobically Assisted Separation-Friendly Mitsunobu Reaction

(2012) Xin-Shan Ye et al.   SYNLETT

Hydrogen bonds with fluorine. Studies in solution, in gas phase and by computations, conflicting conclusions from crystallographic analyses

(2012) Hans-Jörg Schneider   Chemical Science

Rhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine Reagents

(2012) Esteban Mejía et al.   ACS Catalysis

Copper-Catalyzed Aromatic Trifluoromethylation via Group Transfer from Fluoral Derivatives

(2011) Hideaki Kondo et al.   ADVANCED SYNTHESIS & CATALYSIS

Efficient Trifluoromethylation of Activated and Non-Activated Alkenyl Halides by Using (Trifluoromethyl)trimethylsilane

(2011) Andreas Hafner et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Selective Trifluoromethylation of 1,3-Disubstituted Arenes through Iridium-Catalyzed Arene Borylation

(2011) Tianfei Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel Strategies for Fluorine-18 Radiochemistry

(2011) Ryan Littich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Allylic Fluorination

(2011) Charlotte Hollingworth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nucleophilic Fluoromethylation of Aldehydes with Fluorobis(phenylsulfonyl)methane: The Importance of Strong Li-O Coordination and Fluorine Substitution for CC Bond Formation

(2011) Xiao Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed Selective Monofluorination of Benzoic Acids Using a Practical Auxiliary: A Weak-Coordination Approach

(2011) Kelvin S. L. Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Intramolecular Aminofluorination of Activated Allenes

(2011) Tao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Difluoromethyl 2-Pyridyl Sulfone to Difluorinated Sulfonates: A Protocol for Nucleophilic Difluoro(sulfonato)methylation

(2011) G. K. Surya Prakash et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters

(2011) Yanchuan Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylation of Aromatic Isoxazoles: Regio- and Diastereoselective Route to 5-Trifluoromethyl-2-isoxazolines

(2011) Hiroyuki Kawai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Accelerating Palladium-Catalyzed CF Bond Formation: Use of a Microflow Packed-Bed Reactor

(2011) Timothy Noël et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Use of Fluoride as a Leaving Group: SN2′ Displacement of a CF Bond on 3,3-Difluoropropenes with Organolithium Reagents To Give Direct Access to Monofluoroalkenes

(2011) Maxime Bergeron et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF]

(2011) Nichole D. Litvinas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

(2011) Andrew T. Parsons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple, Stable, and Easily Accessible Well-Defined CuCF3 Aromatic Trifluoromethylating Agents

(2011) Olesya A. Tomashenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides

(2011) Hiroyuki Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts

(2011) Cheng-Pan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions

(2011) Georgiy Teverovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α-Trifluoromethyl Carbonyl Compounds

(2011) Phong V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalyzed Enantioselective Fluorocyclizations

(2011) Oscar Lozano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development of the titanium–TADDOLate-catalyzed asymmetric fluorination of β-ketoesters

(2011) Lukas Hintermann et al.   Beilstein Journal of Organic Chemistry

Practical Synthesis of 1,1-Difluoro- or 1-Fluoroalkenes from 2,2,2-Trifluoroacetophenone Derivatives

(2011) Min-Hyuk Kang et al.   BULLETIN OF THE KOREAN CHEMICAL SOCIETY

Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts

(2011) Cheng-Pan Zhang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent

(2011) Jun Xu et al.   CHEMICAL COMMUNICATIONS

Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes

(2011) Cheng-Pan Zhang et al.   CHEMICAL COMMUNICATIONS

Electrophilic fluorination of cationic Pt-aryl complexes

(2011) Shu-Bin Zhao et al.   CHEMICAL COMMUNICATIONS

Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines

(2011) Luca Bernardi et al.   CHEMICAL COMMUNICATIONS

Organic fluorine compounds: a great opportunity for enhanced materials properties

(2011) Ricarda Berger et al.   CHEMICAL SOCIETY REVIEWS

The fluorous effect in biomolecular applications

(2011) Massimo Cametti et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Oxidative Trifluoromethylation of Indoles at Room Temperature

(2011) Xin Mu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Trifluoromethylation of Aryl Iodides with Potassium (Trifluoromethyl)trimethoxyborate

(2011) Thomas Knauber et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Improved Copper-Mediated Oxidative Trifluoromethylation of Terminal Alkynes

(2011) Ke Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Fluorination of elastomer materials

(2011) Sandra Schlögl et al.   EUROPEAN POLYMER JOURNAL

Ionic liquids as media for nucleophilic ring opening fluorination of aziridines

(2011) Shun Noritake et al.   HETEROCYCLIC COMMUNICATIONS

N,N-Dimethyl-S-difluoromethyl-S-phenylsulfoximinium tetrafluoroborate: A versatile electrophilic difluoromethylating reagent

(2011) G.K. Surya Prakash et al.   JOURNAL OF FLUORINE CHEMISTRY

NHC-catalyzed generation of difluorocarbene and its application to difluoromethylation of oxygen nucleophiles

(2011) Kohei Fuchibe et al.   JOURNAL OF FLUORINE CHEMISTRY

Electrophilic Trifluoromethylation ofS-Hydrogen Phosphorothioates

(2011) Nico Santschi et al.   JOURNAL OF ORGANIC CHEMISTRY

Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling

(2011) Todd D. Senecal et al.   JOURNAL OF ORGANIC CHEMISTRY

4-Fluoropyrrolidine-2-carbonyl Fluorides: Useful Synthons and Their Facile Preparation with 4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride

(2011) Rajendra P. Singh et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Allylic Fluorination of Trichloroacetimidates

(2011) Joseph J. Topczewski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deoxyfluorination of Phenols

(2011) Pingping Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for in Situ Catalyst Modification during the Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides

(2011) Thomas J. Maimone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Organocatalytic α-Fluorination of Cyclic Ketones

(2011) Piotr Kwiatkowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature

(2011) Xin Mu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic and Computational Studies of Oxidatively-Induced Aryl−CF3Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation

(2011) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond Activation

(2011) Jun Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Cupration of Fluoroform

(2011) Alessandro Zanardi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Direct C–H Oxidative Trifluoromethylation of Heteroarenes

(2011) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Regio- and Enantioselective Fluorination of Acyclic Allylic Halides

(2011) Matthew H. Katcher et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Arylation of 1H-Perfluoroalkanes

(2011) Ilya Popov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation

(2011) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Trifluoromethoxylation of Aryl Stannanes and Arylboronic Acids

(2011) Chenghong Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Bifunctional to Trifunctional (Tricomponent Nucleophile–Transition Metal–Lewis Acid) Catalysis: The Catalytic, Enantioselective α-Fluorination of Acid Chlorides

(2011) Jeremy Erb et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

(2011) Cheng-Pan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of Cooperative Catalysis in the Enantioselective Fluorination of Epoxides

(2011) Julia A. Kalow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIIICatalytic Cycle

(2011) Alicia Casitas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

(2011) David A. Nagib et al.   NATURE

Highly Diastereoselective and General Synthesis of Primary β-Fluoroamines

(2011) Michael L. Schulte et al.   ORGANIC LETTERS

Synthesis of α-CF3-Substituted Carbonyl Compounds with Relative and Absolute Stereocontrol Using Electrophilic CF3-Transfer Reagents

(2011) Václav Matoušek et al.   ORGANIC LETTERS

Room Temperature Asymmetric Allylic Trifluoromethylation of Morita–Baylis–Hillman Carbonates

(2011) Yun Li et al.   ORGANIC LETTERS

Palladium-Catalyzed Tandem Fluorination and Cyclization of Enynes

(2011) Haihui Peng et al.   ORGANIC LETTERS

Organocatalyzed Regio- and Enantioselective Allylic Trifluoromethylation of Morita–Baylis–Hillman Adducts Using Ruppert–Prakash Reagent

(2011) Tatsuya Furukawa et al.   ORGANIC LETTERS

Oxidation of Primary Aliphatic and Aromatic Aldehydes with Difluoro(aryl)-λ3-bromane

(2011) Masahito Ochiai et al.   ORGANIC LETTERS

Cu-Mediated Chemoselective Trifluoromethylation of Benzyl Bromides Using Shelf-Stable Electrophilic Trifluoromethylating Reagents

(2011) Hiroyuki Kawai et al.   ORGANIC LETTERS

Fluoroanalogs of DDT: Superacidic BF3–H2O Catalyzed Facile Synthesis of 1,1,1-Trifluoro-2,2-diarylethanes and 1,1-Difluoro-2,2-diarylethanes

(2011) G. K. Surya Prakash et al.   ORGANIC LETTERS

Nucleophilic Deoxyfluorination of Catechols

(2011) Hiroyuki Nemoto et al.   ORGANIC LETTERS

A New Method for Aromatic Difluoromethylation: Copper-Catalyzed Cross-Coupling and Decarboxylation Sequence from Aryl Iodides

(2011) Kenichi Fujikawa et al.   ORGANIC LETTERS

Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent

(2011) Tianfei Liu et al.   ORGANIC LETTERS

The Palladium-Catalyzed Trifluoromethylation of Vinyl Sulfonates

(2011) Eun Jin Cho et al.   ORGANIC LETTERS

Silver-Mediated Trifluoromethylation of Arenes Using TMSCF3

(2011) Yingda Ye et al.   ORGANIC LETTERS

Palladium-Catalyzed C–H Perfluoroalkylation of Arenes

(2011) Rebecca N. Loy et al.   ORGANIC LETTERS

Cooperative Effect of Silver in Copper-Catalyzed Trifluoromethylation of Aryl Iodides Using Me3SiCF3

(2011) Zhiqiang Weng et al.   ORGANOMETALLICS

CF3–Ph Reductive Elimination from [(Xantphos)Pd(CF3)(Ph)]

(2011) Vladimir I. Bakhmutov et al.   ORGANOMETALLICS

Innate C-H trifluoromethylation of heterocycles

(2011) Y. Ji et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Fluoride-Derived Electrophilic Late-Stage Fluorination Reagent for PET Imaging

(2011) E. Lee et al.   SCIENCE

Asymmetric Electrophilic Fluorination Using an Anionic Chiral Phase-Transfer Catalyst

(2011) V. Rauniyar et al.   SCIENCE

Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides

(2011) JieMing Zhu et al.   Science China-Chemistry

A Ligand-Free Copper-Catalyzed Decarboxylative Trifluoromethylation of Aryliodides with Sodium Trifluoroacetate Using Ag2O as a Promoter

(2011) Yaming Li et al.   SYNLETT

Synthesis of Monofluoroalkenes via the Activation of Allylic C-F Bonds: A Novel Route to β-Aminofluoroalkenes Using Pd-Catalyzed Allylic Amination Reactions of 3,3-Difluoropropenes

(2011) Jean-François Paquin   SYNLETT

Silver-mediated fluorination of aryl silanes

(2011) Pingping Tang et al.   TETRAHEDRON

C(sp3)–F reductive elimination from alkylgold(iii) fluoride complexes

(2011) Neal P. Mankad et al.   Chemical Science

Morpholinosulfur Trifluoride (Morph-DAST)-Mediated Rearrangement in the Fluorination of Cyclic α,α-Dialkoxy Ketones toward 1,2-Dialkoxy-1,2-difluorinated Compounds

(2010) Riccardo Surmont et al.   ADVANCED SYNTHESIS & CATALYSIS

2-Fluoro-1,3-benzodithiole-1,1,3,3-tetraoxide: A Reagent for Nucleophilic Monofluoromethylation of Aldehydes

(2010) Tatsuya Furukawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Convenient Electrophilic Fluorination of Functionalized Aryl and Heteroaryl Magnesium Reagents

(2010) Shigeyuki Yamada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radiosynthesis and Evaluation of [18F]Selectfluor bis(triflate)

(2010) Harriet Teare et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inherent Oxygen Preference in Enolate Monofluoromethylation and a Synthetic Entry to Monofluoromethyl Ethers

(2010) Yoshinori Nomura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of CF Bonds in Preference to CI Bonds: Difluoromethylation of Lithium Enolates with Trifluoromethyl Iodide

(2010) Koichi Mikami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Ritter-Type Reaction: Direct Electrophilic Trifluoromethylation at Nitrogen Atoms Using Hypervalent Iodine Reagents

(2010) Katrin Niedermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Benzoyl peroxide (BPO)-promoted oxidative trifluoromethylation of tertiary amines with trimethyl(trifluoromethyl)silane

(2010) Lingling Chu et al.   CHEMICAL COMMUNICATIONS

Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

(2010) Teresa de Haro et al.   CHEMICAL COMMUNICATIONS

Chloride ion-catalyzed generation of difluorocarbene for efficient preparation of gem-difluorinated cyclopropenes and cyclopropanes

(2010) Fei Wang et al.   CHEMICAL COMMUNICATIONS

A New and Practical Grignard-Coupling-Fluorination Sequence: Synthesis of 2-Aryl Fluoroarenes

(2010) Pazhamalai Anbarasan et al.   Chemistry-An Asian Journal

A General Approach to (Trifluoromethoxy)pyridines: First X-ray Structure Determinations and Quantum Chemistry Studies

(2010) Baptiste Manteau et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of monofluoroalkenes via Julia–Kocienski reaction

(2010) G.K. Surya Prakash et al.   JOURNAL OF FLUORINE CHEMISTRY

Decarboxylative trifluoromethylation of aryl halides using well-defined copper–trifluoroacetate and –chlorodifluoroacetate precursors

(2010) Kristen A. McReynolds et al.   JOURNAL OF FLUORINE CHEMISTRY

Electrophilic trifluoromethylation of arenes and N-heteroarenes using hypervalent iodine reagents

(2010) Matthias S. Wiehn et al.   JOURNAL OF FLUORINE CHEMISTRY

Preparation of Trifluoromethylated Dihydrocoumarins, Indanones, and Arylpropanoic Acids by Tandem Superacidic Activation of 2-(Trifluoromethyl)acrylic Acid with Arenes

(2010) G. K. Surya Prakash et al.   JOURNAL OF ORGANIC CHEMISTRY

Reactivity of a Hypervalent Iodine Trifluoromethylating Reagent toward THF: Ring Opening and Formation of Trifluoromethyl Ethers

(2010) Serena Fantasia et al.   JOURNAL OF ORGANIC CHEMISTRY

Aminodifluorosulfinium Salts: Selective Fluorination Reagents with Enhanced Thermal Stability and Ease of Handling†,‡

(2010) Alexandre L’Heureux et al.   JOURNAL OF ORGANIC CHEMISTRY

Fluorocyanation of Enamines

(2010) Alexander D. Dilman et al.   JOURNAL OF ORGANIC CHEMISTRY

The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes

(2010) Anna E. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3

(2010) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Asymmetric Synthesis of Allylic Fluorides

(2010) Matthew H. Katcher et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discovery of 4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride as a Deoxofluorinating Agent with High Thermal Stability as Well as Unusual Resistance to Aqueous Hydrolysis, and Its Diverse Fluorination Capabilities Including Deoxofluoro-Arylsulfinylation with High Stereoselectivity

(2010) Teruo Umemoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryl−CF3Bond-Forming Reductive Elimination from Palladium(IV)

(2010) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides

(2010) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Mechanism of Palladium-Catalyzed Aromatic C−H Oxidation

(2010) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Ring Opening of Epoxides by Fluoride Anion Promoted by a Cooperative Dual-Catalyst System

(2010) Julia A. Kalow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex

(2010) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes

(2010) Shuifa Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Late-Stage Fluorination

(2010) Pingping Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophilic Perfluoroalkylation of Imines and Carbonyls: Perfluoroalkyl Sulfones as Efficient Perfluoroalkyl-Transfer Motifs

(2010) G. K. Surya Prakash et al.   ORGANIC LETTERS

Cinchona Alkaloid-Catalyzed Asymmetric Trifluoromethylation of Alkynyl Ketones with Trimethylsilyl Trifluoromethane

(2010) Hiroyuki Kawai et al.   ORGANIC LETTERS

Copper-Mediated Oxidative Trifluoromethylation of Boronic Acids

(2010) Lingling Chu et al.   ORGANIC LETTERS

Enantioselective Synthesis of β-Fluoroamines from β-Amino Alcohols: Application to the Synthesis of LY503430

(2010) Béranger Duthion et al.   ORGANIC LETTERS

Monofluorovinyl Tosylate: A Useful Building Block for the Synthesis of Terminal Vinyl Monofluorides via Suzuki−Miyaura Coupling

(2010) He Zhang et al.   ORGANIC LETTERS

Electrophilic Trifluoromethylation of Primary Phosphines: Synthesis of aP-Bis(trifluoromethyl) Derivative of BINAP

(2010) Nicolas Armanino et al.   ORGANOMETALLICS

Fluorinated high-performance polymers: Poly(arylene ether)s and aromatic polyimides containing trifluoromethyl groups

(2010) Mahua G. Dhara et al.   PROGRESS IN POLYMER SCIENCE

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

(2010) E. J. Cho et al.   SCIENCE

1-tert-Butyl-1H-tetrazol-5-yl fluoromethyl sulfone (TBTSO2CH2F): a versatile fluoromethylidene synthon and its use in the synthesis of monofluorinated alkenes via Julia–Kocienski olefination

(2010) Lingui Zhu et al.   TETRAHEDRON

Nucleophilic (phenylsulfonyl)difluoromethylation of alkyl halides using PhSO2CF2SiMe3: preparation of gem-difluoroalkenes and trifluoromethyl compounds

(2010) Lingui Zhu et al.   TETRAHEDRON LETTERS

Direct C2-trifluoromethylation of indole derivatives catalyzed by copper acetate

(2010) Ryo Shimizu et al.   TETRAHEDRON LETTERS

Nucleophilic trifluoromethylation with organoboron reagents

(2010) Vitalij V. Levin et al.   TETRAHEDRON LETTERS

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination

(2009) Vladimir V. Grushin   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Enantioselective Trifluoromethylation of Azomethine Imines with Trimethyl(trifluoromethyl)silane

(2009) Hiroyuki Kawai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Stereoselective Synthesis of Monofluoroalkenes from α-Fluorosulfoximines and Nitrones

(2009) Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Substitution of Allylic Fluorides

(2009) Amaruka Hazari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hypervalent Bromine Compounds: Smaller, More Reactive Analogues of Hypervalent Iodine Compounds

(2009) Umar Farooq et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc-Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation Reagents

(2009) Raffael Koller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diaryliodonium Salts: A Journey from Obscurity to Fame

(2009) Eleanor���A. Merritt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Synthesis of Aryl Fluorides

(2009) Pazhamalai Anbarasan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine substitutions in an antigenic peptide selectively modulate T-cell receptor binding in a minimally perturbing manner

(2009) Kurt H. Piepenbrink et al.   BIOCHEMICAL JOURNAL

Aromatic trifluoromethylation catalytic in copper

(2009) Masahiro Oishi et al.   CHEMICAL COMMUNICATIONS

Acid-mediated formation of trifluoromethyl sulfonates from sulfonic acids and a hypervalent iodine trifluoromethylating agent

(2009) Raffael Koller et al.   CHEMICAL COMMUNICATIONS

Benchmark and Solvent-Free Preparation of Sulfonium Salt Based Electrophilic Trifluoromethylating Reagents

(2009) Yohan Macé et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Asymmetric oxidative α-fluorination of 2-alkylphenylacetaldehydes with AgHF2 and ruthenium/PNNP catalysts

(2009) Martin Althaus et al.   JOURNAL OF FLUORINE CHEMISTRY

Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations

(2009) Jinbo Hu   JOURNAL OF FLUORINE CHEMISTRY

Difluoromethylation of some C–H acids with chlorodifluoromethane under conditions of phase transfer catalysis (PTC)

(2009) Ewelina Nawrot et al.   JOURNAL OF FLUORINE CHEMISTRY

The solid complex Zn(CF3)Br·2DMF as an alternative reagent for the preparation of both, trifluoromethyl and pentafluoroethyl copper, CuCF3 and CuC2F5

(2009) Mikhail M. Kremlev et al.   JOURNAL OF FLUORINE CHEMISTRY

Trifluoromethylation of various aromatic compounds by CF3I in the presence of Fe(II) compound, H2O2 and dimethylsulfoxide

(2009) Tatsuhito Kino et al.   JOURNAL OF FLUORINE CHEMISTRY

New trends in the chemistry of α-fluorinated ethers, thioethers, amines and phosphines

(2009) Baptiste Manteau et al.   JOURNAL OF FLUORINE CHEMISTRY

Target-Directed Organocatalysis: A Direct Asymmetric Catalytic Approach to Chiral Propargylic and Allylic Fluorides

(2009) Hao Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes

(2009) Tao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Fluorination of Functionalized Aryl Stannanes

(2009) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis

(2009) David A. Nagib et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatile Pd(OTf)2·2H2O-Catalyzedortho-Fluorination Using NMP as a Promoter

(2009) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

(2009) David C. Powers et al.   Nature Chemistry

Enantioselective electrophilic trifluoromethylation of β-keto esters with Umemoto reagents induced by chiral nonracemic guanidines

(2009) Shun Noritake et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Mechanistic Comparison between Pd-Catalyzed Ligand-Directed C−H Chlorination and C−H Acetoxylation

(2009) Kara J. Stowers et al.   ORGANIC LETTERS

Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents

(2009) Francis Beaulieu et al.   ORGANIC LETTERS

Regio- and Stereoselective Synthesis of Fluoroalkenes by Directed Au(I) Catalysis

(2009) Benjamin C. Gorske et al.   ORGANIC LETTERS

Efficient Nucleophilic Fluoromethylation and Subsequent Transformation of Alkyl and Benzyl Halides Using Fluorobis(phenylsulfonyl)methane

(2009) G. K. Surya Prakash et al.   ORGANIC LETTERS

Fluorination of Boronic Acids Mediated by Silver(I) Triflate

(2009) Takeru Furuya et al.   ORGANIC LETTERS

N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles

(2009) Wei Zhang et al.   ORGANIC LETTERS

 -Fluoro- -nitro(phenylsulfonyl)methane as a fluoromethyl pronucleophile: Efficient stereoselective Michael addition to chalcones

(2009) G. K. S. Prakash et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides

(2009) D. A. Watson et al.   SCIENCE

An Efficient and Regioselective Difluoromethylation of 3-Iodoindazole with Chlorodifluoromethane

(2009) Matthew Pelc et al.   SYNLETT

Diethyl bromodifluoromethylphosphonate: a highly efficient and environmentally benign difluorocarbene precursor

(2009) Yossi Zafrani et al.   TETRAHEDRON

Synthesis of difluorinated carbocyclic analogues of 5-deoxypentofuranoses

(2009) Gaëlle Fourrière et al.   TETRAHEDRON LETTERS

Palladium/acetic acid-catalyzed fluoroalkylation of alkynes with monofluorinated sulfones as pronucleophiles

(2009) Chuanfa Ni et al.   TETRAHEDRON LETTERS

Trifluoromethylation of enamines under acidic conditions

(2009) Roman T. Gritsenko et al.   TETRAHEDRON LETTERS

Metal-free electrophilic fluorination of alkyl trifluoroborates and boronic acids

(2009) Clément Cazorla et al.   TETRAHEDRON LETTERS

Enantioselective conjugate addition of fluorobis(phenylsulfonyl)methane to α,β-unsaturated ketones catalyzed by chiral bifunctional organocatalysts

(2009) Hyoung Wook Moon et al.   TETRAHEDRON LETTERS

Recent advances in enantioselective trifluoromethylation reactions

(2009) Norio Shibata et al.   TETRAHEDRON-ASYMMETRY

Gold(I)-Catalyzed Alkoxyhalogenation of β-Hydroxy-α,α-Difluoroynones

(2008) Marie Schuler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of11C,18F,15O, and13N Radiolabels for Positron Emission Tomography

(2008) Philip W. Miller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Imaging with PET

(2008) Simon M. Ametamey et al.   CHEMICAL REVIEWS

Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

(2008) Jun-An Ma et al.   CHEMICAL REVIEWS

Synthesis ofgem-Difluoroalkenes via β-Fluoride Elimination of Organorhodium(I)

(2008) Tomoya Miura et al.   CHEMISTRY LETTERS

Recent Advances in Electrophilic CF3-Transfer Using Hypervalent Iodine(III) Reagents

(2008) Iris Kieltsch et al.   CHIMIA

Chemistry with [18F]Fluoride Ion

(2008) Lisheng Cai et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Preparation of Alkyl and Aryl Chlorodifluoromethyl Ethers Using BrF3

(2008) Youlia Hagooly et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Fluorinated Johnson Reagent for Transfer-Trifluoromethylation to Carbon Nucleophiles

(2008) Shun Noritake et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

ElectrophilicS-Trifluoromethylation of Cysteine Side Chains inα- andβ-Peptides: Isolation of Trifluoro-methylatedSandostatin®(Octreotide) Derivatives

(2008) Stefania Capone et al.   HELVETICA CHIMICA ACTA

Stereoselective synthesis of fluorobis(phenylsulfonyl)methyl-substituted alkenes using free radical fluoroalkylation

(2008) G.K. Surya Prakash et al.   JOURNAL OF FLUORINE CHEMISTRY

Nucleophilic difluoromethylation and trifluoromethylation using tetrakis(dimethylamino)ethylene (TDAE) reagent

(2008) Maurice Médebielle et al.   JOURNAL OF FLUORINE CHEMISTRY

Reactions of trimethylsilyl fluorosulfonyldifluoroacetate with purine and pyrimidine nucleosides

(2008) Magdalena Rapp et al.   JOURNAL OF FLUORINE CHEMISTRY

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Constructing the OCF2O Moiety Using BrF3

(2008) Youlia Hagooly et al.   JOURNAL OF ORGANIC CHEMISTRY

Reactivity of a 10-I-3 Hypervalent Iodine Trifluoromethylation Reagent With Phenols

(2008) Kyrill Stanek et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile Nucleophilic Fluorination Reactions Usingtert-Alcohols as a Reaction Medium:  Significantly Enhanced Reactivity of Alkali Metal Fluorides and Improved Selectivity

(2008) Dong Wook Kim et al.   JOURNAL OF ORGANIC CHEMISTRY

Difluoro-λ3-Bromane-Induced Oxidative Carbon−Carbon Bond-Forming Reactions:  Ethanol as an Electrophilic Partner and Alkynes as Nucleophiles

(2008) Masahito Ochiai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insights into Directing Group Ability in Palladium-Catalyzed C−H Bond Functionalization

(2008) Lopa V. Desai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon−Fluorine Reductive Elimination from a High-Valent Palladium Fluoride

(2008) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Active Trifluoromethylating Agents from Well-Defined Copper(I)−CF3Complexes

(2008) Galyna G. Dubinina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multi-vicinal fluoroalkanes: a new class of organofluorine compounds

(2008) Luke Hunter et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct Electrophilic Monofluoromethylation

(2008) G. K. Surya Prakash et al.   ORGANIC LETTERS

Stereoselective Monofluoromethylation ofN-tert-Butylsulfinyl Ketimines Using Pregenerated Fluoro(phenylsulfonyl)methyl Anion

(2008) Jun Liu et al.   ORGANIC LETTERS

Structure of Bis(trifluoromethyl)cuprate and Its Role in Trifluoromethylation Reactions

(2008) Galyna G. Dubinina et al.   ORGANOMETALLICS

Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)

(2008) Vladimir V. Grushin et al.   ORGANOMETALLICS

Direct nucleophilic fluorination of carbonyl groups of benzophenones and benzils with Deoxofluor

(2008) Ying Chang et al.   TETRAHEDRON

New preparation of difluoroiodomethylsulfanylbenzenes and their radical addition to unsaturated compounds initiated by sodium dithionite

(2008) Xueyan Yang et al.   TETRAHEDRON

Nucleophilic difluoromethylation and difluoromethylenation of aldehydes and ketones using diethyl difluoromethylphosphonate

(2008) Petr Beier et al.   TETRAHEDRON

Diastereoselective synthesis of highly functionalized fluoroalkene dipeptide isosteres and its application to Fmoc-based solid-phase synthesis of a cyclic pentapeptide mimetic

(2008) Tetsuo Narumi et al.   TETRAHEDRON

Replacing the carbonyl's oxygen with the difluoromethyl group

(2008) Or Cohen et al.   TETRAHEDRON

Free radical (phenylsulfonyl)difluoromethylation of alkynes with PhSO2CF2I reagent: stereoselective preparation of PhSO2CF2- and CF2H-substituted alkenes

(2008) Ya Li et al.   TETRAHEDRON

Nucleophilic fluoroalkylation of iminium salts

(2008) Vitalij V. Levin et al.   TETRAHEDRON LETTERS

Stereoselective synthesis of α-difluoromethyl-β-amino alcohols via nucleophilic difluoromethylation with Me3SiCF2SO2Ph

(2008) Jun Liu et al.   TETRAHEDRON LETTERS

A general route for constructing difluoromethyl ethers

(2008) Youlia Hagooly et al.   TETRAHEDRON LETTERS

Desymmetrization-like Catalytic Enantioselective Fluorination of Malonates and Its Application to Pharmaceutically Attractive Molecules

(2007) Dhande Sudhakar Reddy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS

Accounting for Fluorine: Production, Use, and Loss

(2007) Gara Villalba et al.   JOURNAL OF INDUSTRIAL ECOLOGY

Versatile application of trifluoromethyl triflate

(2007) Alexander A. Kolomeitsev et al.   TETRAHEDRON LETTERS