Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols
Published 2013 View Full Article
- Home
- Publications
- Publication Search
- Publication Details
Title
Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols
Authors
Keywords
-
Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 52, Issue 37, Pages 9781-9785
Publisher
Wiley
Online
2013-07-19
DOI
10.1002/anie.201304557
References
Ask authors/readers for more resources
Related references
Note: Only part of the references are listed.- Alkene Trifluoromethylation Coupled with CC Bond Formation: Construction of Trifluoromethylated Carbocycles and Heterocycles
- (2013) Hiromichi Egami et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Silver-Catalyzed Hydrotrifluoromethylation of Unactivated Alkenes with CF3SiMe3
- (2013) Xinyue Wu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Catalytic Hydrotrifluoromethylation of Unactivated Alkenes
- (2013) Satoshi Mizuta et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Fluoroform-Derived CuCF3for Low-Cost, Simple, Efficient, and Safe Trifluoromethylation of Aryl Boronic Acids in Air
- (2012) Petr Novák et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Copper-Catalyzed Trifluoromethylation of Allylsilanes
- (2012) Ryo Shimizu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Copper-Catalyzed Di- and Trifluoromethylation of α,β-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations
- (2012) Zhengbiao He et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Copper-Promoted Trifluoromethylation of Primary and Secondary Alkylboronic Acids
- (2012) Jun Xu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Tamed Arene and Heteroarene Trifluoromethylation
- (2012) Tatiana Besset et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Ortho-Trifluoromethylation of Functionalized Aromatic Triazenes
- (2012) Andreas Hafner et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts
- (2012) Yusuke Yasu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A “Renaissance” in Radical Trifluoromethylation
- (2012) Armido Studer ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Iron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates
- (2012) Andrew T. Parsons et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Partially saturated fluorinated heterocycles: diastereo- and enantioselective synthesis of β-trifluoromethyl-pyrroline carboxylates
- (2012) Hiroyuki Kawai et al. CHEMICAL COMMUNICATIONS
- Organic base-catalyzed stereodivergent synthesis of (R)- and (S)-3-amino-4,4,4-trifluorobutanoic acids
- (2012) Norio Shibata et al. CHEMICAL COMMUNICATIONS
- Copper-catalyzed trifluoromethylation of aryl- and vinylboronic acids with generation of CF3-radicals
- (2012) Yang Li et al. CHEMICAL COMMUNICATIONS
- Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides: A Simple Approach to Allylic Trifluoromethylation
- (2012) Yoshihiro Miyake et al. CHEMISTRY-A EUROPEAN JOURNAL
- Trifluoromethylation of Allylsilanes under Copper Catalysis
- (2012) Satoshi Mizuta et al. CHEMISTRY-A EUROPEAN JOURNAL
- Organocatalytic Asymmetric Fluorination/Semipinacol Rearrangement: An Efficient Approach to Chiral β-Fluoroketones
- (2012) Zhi-Min Chen et al. CHEMISTRY-A EUROPEAN JOURNAL
- Recent Developments on the Trifluoromethylation of (Hetero)Arenes
- (2012) Xiao-Feng Wu et al. Chemistry-An Asian Journal
- Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis
- (2012) Naeem Iqbal et al. JOURNAL OF ORGANIC CHEMISTRY
- Pd(II)-Catalyzed Ortho Trifluoromethylation of Arenes and Insights into the Coordination Mode of Acidic Amide Directing Groups
- (2012) Xing-Guo Zhang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Pd(II)/Brønsted Acid Catalyzed Enantioselective Allylic C–H Activation for the Synthesis of Spirocyclic Rings
- (2012) Zhuo Chai et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Trifluoromethylation of α-Haloketones
- (2012) Petr Novák et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- A Simple Method for Asymmetric Trifluoromethylation of N-Acyl Oxazolidinones via Ru-Catalyzed Radical Addition to Zirconium Enolates
- (2012) Aaron T. Herrmann et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature
- (2012) Qingqing Qi et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Catalyzed Alkene Arylation with Diaryliodonium Salts
- (2012) Robert J. Phipps et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I
- (2012) Yingda Ye et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Catalyzed Oxytrifluoromethylation of Unactivated Alkenes
- (2012) Rong Zhu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters
- (2012) Qing-Hai Deng et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter
- (2012) Mingyou Hu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Practical and innate carbon–hydrogen functionalization of heterocycles
- (2012) Yuta Fujiwara et al. NATURE
- Diastereoselective Synthesis of CF3-Substituted, Epoxide-Fused Heterocycles with β-(Trifluoromethyl)vinylsulfonium Salts
- (2012) Sven P. Fritz et al. ORGANIC LETTERS
- Palladium-Catalyzed Trifluoromethylation of Aromatic C–H Bond Directed by an Acetamino Group
- (2012) Li-Sheng Zhang et al. ORGANIC LETTERS
- Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkenes Using Nucleophilic CF3SiMe3: Efficient C(sp3)–CF3 Bond Formation
- (2012) Lingling Chu et al. ORGANIC LETTERS
- Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes
- (2012) Pär G. Janson et al. ORGANIC LETTERS
- Axially chiral dicarboxylic acid catalyzed asymmetric semipinacol rearrangement of cyclic β-hydroxy-α-diazo esters
- (2012) Takuya Hashimoto et al. TETRAHEDRON
- Oxytrifluoromethylation of multiple bonds using copper catalyst under mild conditions
- (2012) Hiromichi Egami et al. TETRAHEDRON LETTERS
- Copper-catalyzed olefinic trifluoromethylation of enamides at room temperature
- (2012) Chao Feng et al. Chemical Science
- Rhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine Reagents
- (2012) Esteban Mejía et al. ACS Catalysis
- Stereoselective Construction of Quaternary Carbon Stereocenters via a Semipinacol Rearrangement Strategy
- (2011) Baomin Wang et al. ACCOUNTS OF CHEMICAL RESEARCH
- Highly Selective Trifluoromethylation of 1,3-Disubstituted Arenes through Iridium-Catalyzed Arene Borylation
- (2011) Tianfei Liu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and Cyclohexanones
- (2011) Bill Morandi et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF]
- (2011) Nichole D. Litvinas et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Copper-Catalyzed Trifluoromethylation of Unactivated Olefins
- (2011) Andrew T. Parsons et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Traceless Solid-Phase Synthesis of Trifluoromethylarenes
- (2011) Marion Döbele et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Simple, Stable, and Easily Accessible Well-Defined CuCF3 Aromatic Trifluoromethylating Agents
- (2011) Olesya A. Tomashenko et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides
- (2011) Hiroyuki Morimoto et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Copper-Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts
- (2011) Cheng-Pan Zhang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α-Trifluoromethyl Carbonyl Compounds
- (2011) Phong V. Pham et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A novel catalytic process for trifluoromethylation of bromoaromatic compounds
- (2011) Bhupesh S. Samant et al. CHEMICAL COMMUNICATIONS
- Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent
- (2011) Jun Xu et al. CHEMICAL COMMUNICATIONS
- Aromatic Trifluoromethylation with Metal Complexes
- (2011) Olesya A. Tomashenko et al. CHEMICAL REVIEWS
- Semipinacol Rearrangement in Natural Product Synthesis
- (2011) Zhen-Lei Song et al. CHEMICAL REVIEWS
- Palladium-Catalyzed Oxidative Trifluoromethylation of Indoles at Room Temperature
- (2011) Xin Mu et al. CHEMISTRY-A EUROPEAN JOURNAL
- Copper-Catalyzed Trifluoromethylation of Aryl Iodides with Potassium (Trifluoromethyl)trimethoxyborate
- (2011) Thomas Knauber et al. CHEMISTRY-A EUROPEAN JOURNAL
- Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling
- (2011) Todd D. Senecal et al. JOURNAL OF ORGANIC CHEMISTRY
- Organocatalytic Asymmetric Halogenation/Semipinacol Rearrangement: Highly Efficient Synthesis of Chiral α-Oxa-Quaternary β-Haloketones
- (2011) Zhi-Min Chen et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature
- (2011) Xin Mu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond Activation
- (2011) Jun Xu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Direct Cupration of Fluoroform
- (2011) Alessandro Zanardi et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Catalyzed Direct C–H Oxidative Trifluoromethylation of Heteroarenes
- (2011) Lingling Chu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Catalyzed Arylation of 1H-Perfluoroalkanes
- (2011) Ilya Popov et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation
- (2011) Xi Wang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalysis for fluorination and trifluoromethylation
- (2011) Takeru Furuya et al. NATURE
- Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis
- (2011) David A. Nagib et al. NATURE
- Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent
- (2011) Tianfei Liu et al. ORGANIC LETTERS
- Silver-Mediated Trifluoromethylation of Arenes Using TMSCF3
- (2011) Yingda Ye et al. ORGANIC LETTERS
- Palladium-Catalyzed C–H Perfluoroalkylation of Arenes
- (2011) Rebecca N. Loy et al. ORGANIC LETTERS
- Innate C-H trifluoromethylation of heterocycles
- (2011) Y. Ji et al. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
- Reaction of Baylis-Hillman Adducts with Fluorinated Silanes
- (2010) Artem A. Zemtsov et al. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Electrophilic trifluoromethylation of arenes and N-heteroarenes using hypervalent iodine reagents
- (2010) Matthias S. Wiehn et al. JOURNAL OF FLUORINE CHEMISTRY
- The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes
- (2010) Anna E. Allen et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter
- (2010) Xisheng Wang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- A Tandem Prins/Schmidt Reaction Approach to Marine Alkaloids: Formal and Total Syntheses of Lepadiformines A and C
- (2010) Angelica M. Meyer et al. ORGANIC LETTERS
- Copper-Mediated Oxidative Trifluoromethylation of Boronic Acids
- (2010) Lingling Chu et al. ORGANIC LETTERS
- The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides
- (2010) E. J. Cho et al. SCIENCE
- Brønsted Acid Catalyzed Enantioselective Semipinacol Rearrangement for the Synthesis of Chiral Spiroethers
- (2009) Qing-Wei Zhang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Aromatic trifluoromethylation catalytic in copper
- (2009) Masahiro Oishi et al. CHEMICAL COMMUNICATIONS
- Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols
- (2009) Florian Kleinbeck et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective Total Synthesis of (−)-Napyradiomycin A1 via Asymmetric Chlorination of an Isolated Olefin
- (2009) Scott A. Snyder et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Organocatalytic Asymmetric Vinylogous α-Ketol Rearrangement: Enantioselective Construction of Chiral All-Carbon Quaternary Stereocenters in Spirocyclic Diketones via Semipinacol-Type 1,2-Carbon Migration
- (2009) En Zhang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis
- (2009) David A. Nagib et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Nucleophilic trifluoromethylation of arylidene Meldrum’s acids
- (2009) Artem A. Zemtsov et al. TETRAHEDRON LETTERS
- Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions
- (2008) Jun-An Ma et al. CHEMICAL REVIEWS
- The Many Roles for Fluorine in Medicinal Chemistry
- (2008) William K. Hagmann JOURNAL OF MEDICINAL CHEMISTRY
- Synthetic Studies toward Halichlorine: Complex Azaspirocycle Formation with Use of an NBS-Promoted Semipinacol Reaction
- (2008) Paul B. Hurley et al. JOURNAL OF ORGANIC CHEMISTRY
- Fluorination in Medicinal Chemistry: Methods, Strategies, and Recent Developments
- (2008) Kenneth L. Kirk ORGANIC PROCESS RESEARCH & DEVELOPMENT
- Nucleophilic trifluoromethylation of arylidenemalononitriles
- (2008) Alexander D. Dilman et al. TETRAHEDRON LETTERS
- Fluorine in medicinal chemistry
- (2007) Sophie Purser et al. CHEMICAL SOCIETY REVIEWS
Find Funding. Review Successful Grants.
Explore over 25,000 new funding opportunities and over 6,000,000 successful grants.
ExploreBecome a Peeref-certified reviewer
The Peeref Institute provides free reviewer training that teaches the core competencies of the academic peer review process.
Get Started