Highly Efficient “On Water” Catalyst-Free Nucleophilic Addition Reactions Using Difluoroenoxysilanes: Dramatic Fluorine Effects

Intramolecular C–H⋯F hydrogen bonding-induced 1,2,3-triazole-based foldamers

(2014) Yan-Hua Liu et al.   Organic Chemistry Frontiers

Catalytic fluorination of unactivated C(sp3)–H bonds

(2014) Jun-An Ma et al.   Organic Chemistry Frontiers

Mukaiyama Aldol Reactions in Aqueous Media

(2013) Taku Kitanosono et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Enantioselective Difluoroalkylation of Aldehydes

(2013) Peng Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Difluoro(sulfinato)methylation of N-Sulfinyl Imines Facilitated by 2-Pyridyl Sulfone: Stereoselective Synthesis of Difluorinated β-Amino Sulfonic Acids and Peptidosulfonamides

(2013) G. K. Surya Prakash et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Tandem Approach to Spirocyclic Oxindoles Featuring Adjacent Spiro-Stereocenters

(2013) Yun-Lin Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Difluoromethyl Ethers with Difluoromethyltriflate

(2013) Patrick S. Fier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Benign by design: catalyst-free in-water, on-water green chemical methodologies in organic synthesis

(2013) Manoj B. Gawande et al.   CHEMICAL SOCIETY REVIEWS

Waste as Catalyst: Tandem Wittig/Conjugate Reduction Sequence to α-CF3γ-Keto Esters That Uses Ph3PO as Catalyst for the Chemoselective Conjugate Reduction

(2013) Long Chen et al.   Chemistry-An Asian Journal

One-Pot Synthesis of 1-(Trifluoromethyl)-4-fluoro-1,2-dihydroisoquinolines and 4,4-Difluoro-1,2,3,4-tetrahydroisoquinolines

(2013) Qilun Liu et al.   ORGANIC LETTERS

Catalytic Asymmetric Construction of Stereogenic Carbon Centers that Feature agem-Difluoroalkyl Group

(2013) Yun-Lin Liu et al.   Asian Journal of Organic Chemistry

Highly Enantioselective Organocatalytic Asymmetric Mukaiyama-aldol Reaction of Difluoroenoxysilanes withβ,γ-Unsaturatedα-Ketoesters

(2012) Yunlin Liu et al.   ACTA CHIMICA SINICA

Investigation of “On Water” Conditions Using a Biphasic Fluidic Platform

(2012) Sonia Mellouli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

“On Water”: Efficient Iron-Catalyzed Cycloaddition of Aziridines with Heterocumulenes

(2012) Mani Sengoden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Progress in fluoroalkylation of organic compounds via sulfinatodehalogenation initiation system

(2012) Cheng-Pan Zhang et al.   CHEMICAL SOCIETY REVIEWS

Ethylene Glycol: A Powerful Catalyst-Free Medium for CC Bond-Forming Reactions

(2012) Yun-Lin Liu et al.   Chemistry-An Asian Journal

A New Reagent for Direct Difluoromethylation

(2012) Yuta Fujiwara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Difluoromethylation of Aryl and Vinyl Iodides

(2012) Patrick S. Fier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter

(2012) Mingyou Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand–zinc(ii) complexes

(2012) Zhiliang Yuan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Decarboxylative Allylation of Trifluoroethyl Sulfones and Approach to Difluoromethyl Compounds

(2012) Norio Shibata et al.   ORGANIC LETTERS

Hydrogen bonds with fluorine. Studies in solution, in gas phase and by computations, conflicting conclusions from crystallographic analyses

(2012) Hans-Jörg Schneider   Chemical Science

Aqueous and Solvent-Free Uncatalyzed Three-Component Vinylogous Mukaiyama-Mannich Reactions of Pyrrole-Based Silyl Dienolates

(2011) Andrea Sartori et al.   ADVANCED SYNTHESIS & CATALYSIS

“On water” sp3–sp2 cross-couplings between benzylic and alkenyl halides

(2011) Valeria Krasovskaya et al.   CHEMICAL COMMUNICATIONS

Organocatalytic asymmetric synthesis of 3-difluoroalkyl 3-hydroxyoxindoles

(2011) Yun-Lin Liu et al.   CHEMICAL COMMUNICATIONS

Rate acceleration of Diels–Alder reactions utilizing a fluorous micellar system in water

(2011) Kohsuke Nishimoto et al.   ELECTROCHIMICA ACTA

“On water”-promoted direct alkynylation of isatins catalyzed by NHC–silver complexes for the efficient synthesis of 3-hydroxy-3-ethynylindolin-2-ones

(2011) Xiao-Pu Fu et al.   GREEN CHEMISTRY

Cleavage of Carbon−Carbon Bonds through the Mild Release of Trifluoroacetate: Generation of α,α-Difluoroenolates for Aldol Reactions

(2011) Changho Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Phosphoric Acid Catalyzed Enantioselective Synthesis of β-Amino-α,α-difluoro Carbonyl Compounds

(2011) Wataru Kashikura et al.   ORGANIC LETTERS

Fluoroallylboration−Olefination for the Synthesis of (Z)-4,4-Difluoropent-2-enoates and 5,5-Difluoro-5,6-dihydropyran-2-ones

(2011) P. Veeraraghavan Ramachandran et al.   ORGANIC LETTERS

Organocatalytic Asymmetric Strecker Reaction of Di- and Trifluoromethyl Ketoimines. Remarkable Fluorine Effect

(2011) Yun-Lin Liu et al.   ORGANIC LETTERS

Recent applications of Cinchona alkaloids and their derivatives as catalysts in metal-free asymmetric synthesis

(2011) Elizabeth M.O. Yeboah et al.   TETRAHEDRON

Catalytic Asymmetric Synthesis of Oxindoles Bearing a Tetrasubstituted Stereocenter at the C-3 Position

(2010) Feng Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Functionalization of Peptides and Proteins by Mukaiyama Aldol Reaction

(2010) Jenefer Alam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Halogenated Carboxylic Acids and Amino Acids

(2010) Constantin Czekelius et al.   SYNTHESIS-STUTTGART

Reaction of aldimines and difluoroenoxysilane, an unexpected protocol for the synthesis of 2,2-difluoro-3-hydroxy-1-ones

(2010) Zhi-Liang Yuan et al.   TETRAHEDRON

Iron-Catalyzed Cyclopropanation with Trifluoroethylamine Hydrochloride and Olefins in Aqueous Media: In Situ Generation of Trifluoromethyl Diazomethane

(2009) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective difluoromethylation and monofluoromethylation reactions

(2009) Jinbo Hu et al.   CHEMICAL COMMUNICATIONS

(Thio)urea organocatalysis—What can be learnt from anion recognition?

(2009) Zhiguo Zhang et al.   CHEMICAL SOCIETY REVIEWS

CuBr-Catalyzed Oxidative Difluoromethylation of Tertiary Amines with Difluoroenol Silyl Ethers

(2009) Lingling Chu et al.   ORGANIC LETTERS

Recent advances in enantioselective trifluoromethylation reactions

(2009) Norio Shibata et al.   TETRAHEDRON-ASYMMETRY

Highly Efficient Organic Reactions “on Water”, “in Water”, and Both

(2008) Nelly Shapiro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Rational Approach towards the Nucleophilic Substitutions of Alcohols “on Water”

(2008) Pier Giorgio Cozzi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Green chemistry for chemical synthesis

(2008) C.-J. Li et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS