Amides as Weak Coordinating Groups in Proximal C-H Bond Activation

Rhodium(III)-Catalyzed Annulation ofN-Methoxybenzamides with Heterobicyclic Alkenes by C-H Functionalization: Synthesis of Benzo[b]phenanthridinones

(2017) Ying Cheng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Access to Indoles by IrIII -Catalyzed C-H Functionalization of Acetanilides with Diazo Compounds

(2017) Pitambar Patel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed, ortho-Selective C–H Halogenation of Benzyl Nitriles, Aryl Weinreb Amides, and Anilides

(2017) Riki Das et al.   JOURNAL OF ORGANIC CHEMISTRY

Weinreb amide directed cross-coupling reaction between electron-deficient alkenes catalyzed by a rhodium catalyst

(2017) Feifei Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh(III)-Catalyzed Diastereoselective Annulation of Amides with Quinone Monoacetals: Access to Bridged Nine-Membered Heterocycles via C–H Activation

(2017) Wei Yang et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Ortho-Alkenylation of Anilines Directed by a Removable Boc-Protecting Group

(2017) Tomohiro Morita et al.   ORGANIC LETTERS

Traceless Directing-Group Strategy in the Ru-Catalyzed, Formal [3 + 3] Annulation of Anilines with Allyl Alcohols: A One-Pot, Domino Approach for the Synthesis of Quinolines

(2017) Gangam Srikanth Kumar et al.   ORGANIC LETTERS

Palladium-Catalyzed Synthesis of 3-Trifluoromethyl-Substituted 1,3-Butadienes by Means of Directed C–H Bond Functionalization

(2017) Qun Zhao et al.   ORGANIC LETTERS

Amide Directed Cross-Coupling between Alkenes and Alkynes: A Regio- and Stereoselective Approach to Substituted (2Z,4Z)-Dienamides

(2017) Keke Meng et al.   ORGANIC LETTERS

Rhodium(III)-catalysed, redox-neutral C(sp 2 )-H alkenylation using pivalimide as a directing group with internal alkynes

(2017) Subban Kathiravan et al.   TETRAHEDRON LETTERS

Highly chemoselective ruthenium(ii)-catalyzed direct arylation of cyclic and N,N-dialkyl benzamides with aryl silanes

(2017) Pradeep Nareddy et al.   Chemical Science

Metal-Catalyzed Annulations through Activation and Cleavage of C−H Bonds

(2016) Moisés Gulías et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanochemical Iridium(III)-Catalyzed C−H Bond Amidation of Benzamides with Sulfonyl Azides under Solvent-Free Conditions in a Ball Mill

(2016) Gary N. Hermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Palladium CatalyzedorthoC-H Bond Functionalizations of Aniline Derivatives

(2016) Ms. Orsolya Tischler et al.   CHEMICAL RECORD

Use of Bromine and Bromo-Organic Compounds in Organic Synthesis

(2016) Indranirekha Saikia et al.   CHEMICAL REVIEWS

WeakO-Assistance Outcompeting StrongN,N-Bidentate Directing Groups in Copper-Catalyzed C−H Chalcogenation

(2016) Gianpiero Cera et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carboxylate-Assisted Iridium-Catalyzed C−H Amination of Arenes with Biologically Relevant Alkyl Azides

(2016) Tao Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Product Control using Substrate Design: Ruthenium-Catalysed Oxidative C−H Olefinations of Cyclic Weinreb Amides

(2016) Riki Das et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(ii) pincer type complex catalyzed tandem C–H and N–H activation of acetanilide in aqueous media: a concise access to functionalized carbazoles in a single step

(2016) Vignesh Arumugam et al.   GREEN CHEMISTRY

Synthesis of Isoindolinones by Pd-Catalyzed Coupling between N-Methoxybenzamide and Styrene Derivatives

(2016) Changkun Xia et al.   JOURNAL OF ORGANIC CHEMISTRY

Primary Amide Directed Regioselective ortho-C–H-Arylation of (Aryl)Acetamides

(2016) Yogesh Jaiswal et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium(iii)-catalyzed regioselective direct arylation of sp2 C–H bonds with diaryliodonium salts

(2016) Pan Gao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Advances in the development of catalytic tethering directing groups for C–H functionalization reactions

(2016) Huan Sun et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

One Substrate, Two Modes of C–H Functionalization: A Metal-Controlled Site-Selectivity Switch in C–H Arylation Reactions

(2016) Virendra Kumar Tiwari et al.   ORGANIC LETTERS

Indole Synthesis via Cobalt(III)-Catalyzed Oxidative Coupling of N-Arylureas and Internal Alkynes

(2016) Zhuo-Zhuo Zhang et al.   ORGANIC LETTERS

Rhodium-Catalyzed β-Selective Oxidative Heck-Type Coupling of Vinyl Acetate via C–H Activation

(2016) Hui-Jun Zhang et al.   ORGANIC LETTERS

Redox-Neutral Couplings between Amides and Alkynes via Cobalt(III)-Catalyzed C–H Activation

(2016) Lingheng Kong et al.   ORGANIC LETTERS

A diversity-oriented synthesis of bioactive benzanilides via a regioselective C(sp2)–H hydroxylation strategy

(2016) Yong-Hui Sun et al.   Chemical Science

Pd-catalyzed dehydrogenative annulation approach for the efficient synthesis of phenanthridinones

(2016) Xinyao Li et al.   Chemical Science

Advances in C–CN Bond Formation via C–H Bond Activation

(2016) Yuanyuan Ping et al.   ACS Catalysis

Transition-Metal-Mediated Direct C–H Amination of Hydrocarbons with Amine Reactants: The Most Desirable but Challenging C–N Bond-Formation Approach

(2016) Hyunwoo Kim et al.   ACS Catalysis

Control over Organometallic Intermediate Enables Cp*Co(III) Catalyzed Switchable Cyclization to Quinolines and Indoles

(2016) Qingquan Lu et al.   ACS Catalysis

Rhodium-catalyzed oxidative coupling of N-acyl anilines with alkynes using an acylamino moiety as the traceless directing group

(2016) Kaijun Geng et al.   Organic Chemistry Frontiers

Cp*Co(iii)-catalyzed vinylic C–H bond activation under mild conditions: expedient pyrrole synthesis via (3 + 2) annulation of enamides and alkynes

(2016) Dhanaji M. Lade et al.   Organic Chemistry Frontiers

Cobalt-catalyzed synthesis of quinolines from the redox-neutral annulation of anilides and alkynes

(2016) Qiangqiang Yan et al.   Organic Chemistry Frontiers

Ru-Catalyzed selective C–H oxidative olefination with N-heteroarenes directed by pivaloyl amide

(2016) Li Zhang et al.   Organic Chemistry Frontiers

Direct and Site-Selective Palladium-Catalyzed C-7 Acylation of Indolines with Aldehydes

(2015) Youngmi Shin et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium(II)-Catalyzed CH Arylation of Anilides with Boronic Acids, Borinic Acids and Potassium Trifluoroborates

(2015) Jonathan Hubrich et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzedortho-Arylation of Anilides with Aryl Halides

(2015) Radhakrishnan Haridharan et al.   ADVANCED SYNTHESIS & CATALYSIS

Mechanochemical Rhodium(III)-Catalyzed CH Bond Functionalization of Acetanilides under Solventless Conditions in a Ball Mill

(2015) Gary N. Hermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Comparative Catalytic Activity of Group 9 [Cp*MIII] Complexes: Cobalt-Catalyzed CH Amidation of Arenes with Dioxazolones as Amidating Reagents

(2015) Juhyeon Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)/PAr3-Catalyzed Intermolecular Amination of C(sp3)H Bonds: Synthesis of β-Amino Acids

(2015) Jian He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(iii)-catalyzed cyanation of vinylic C–H bonds: N-cyano-N-phenyl-p-toluenesulfonamide as a cyanation reagent

(2015) Wei Su et al.   CHEMICAL COMMUNICATIONS

Rh(iii)-catalyzed 7-azaindole synthesis via C–H activation/annulative coupling of aminopyridines with alkynes

(2015) Yechan Kim et al.   CHEMICAL COMMUNICATIONS

Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions

(2015) Yuji Takahama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Acylation of (Hetero)Arenes through CH Activation with Aroyl Surrogates

(2015) Xiao-Feng Wu   CHEMISTRY-A EUROPEAN JOURNAL

Fujiwara-Moritani Reaction of Weinreb Amides using a Ruthenium-Catalyzed C−H Functionalization Reaction

(2015) Riki Das et al.   Chemistry-An Asian Journal

Palladium-Catalyzed C-H Bond Acylation of Acetanilides with Benzylic Alcohols under Aqueous Conditions

(2015) Feihua Luo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Formal Dehydrative [4 + 2] Cycloaddition of Enamides and Alkynes for the Synthesis of Highly Substituted Pyridines: Reaction Development and Mechanistic Study

(2015) Jicheng Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Role of Rh(III) Catalyst Enables Regioselective Halogenation of (Electron-Rich) Heterocycles

(2015) Nils Schröder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(ii)-catalyzed C–H arylation of aryl and benzyl Weinreb amides

(2015) Yan Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules

(2015) Jiao Jiao et al.   ACS Catalysis

Ruthenium-Catalyzed ortho Alkenylation of Aromatics with Alkenes at Room Temperature with Hydrogen Evolution

(2015) Rajendran Manikandan et al.   ACS Catalysis

Iridium-Catalyzed Direct C–H Amination with Alkylamines: Facile Oxidative Insertion of Amino Group into Iridacycle

(2015) Hyunwoo Kim et al.   ACS Catalysis

Carboxylate-assisted ruthenium(ii)-catalyzed C–H activations of monodentate amides with conjugated alkenes

(2015) Jie Li et al.   Organic Chemistry Frontiers

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Palladium-Catalyzed Direct Alkynylation ofN-Vinylacetamides

(2014) Yun-He Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Weakly Coordinating Directing Groups for Ruthenium(II)- Catalyzed CH Activation

(2014) Suman De Sarkar et al.   ADVANCED SYNTHESIS & CATALYSIS

The CH Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by RhIIICatalysis

(2014) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Use of the Wilkinson Catalyst for theortho-CH Heteroarylation of Aromatic Amines: Facile Access to Highly Extended π-Conjugated Heteroacenes for Organic Semiconductors

(2014) Yumin Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative acylation of indolines with α-keto acids under palladium catalysis: a facile strategy for the synthesis of 7-substituted indoles

(2014) Minyoung Kim et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed intramolecular annulation via C–H activation leading to fused tricyclic indole scaffolds

(2014) Pengyu Tao et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed intramolecular amidoarylation and hydroarylation of alkyne via C–H activation: switchable synthesis of 3,4-fused tricyclic indoles and chromans

(2014) Xue Zhang et al.   CHEMICAL COMMUNICATIONS

Ruthenium-catalyzed ortho-arylation of acetanilides with aromatic boronic acids: an easy route to prepare phenanthridines and carbazoles

(2014) Ravi Kiran Chinnagolla et al.   CHEMICAL COMMUNICATIONS

A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides

(2014) Dengke Li et al.   CHEMICAL COMMUNICATIONS

Pd-Catalyzed C–H activation/oxidative cyclization of acetanilide with norbornene: concise access to functionalized indolines

(2014) Yang Gao et al.   CHEMICAL COMMUNICATIONS

Palladium catalyzed, heteroatom-guided C–H functionalization in the synthesis of substituted isoquinolines and dihydroisoquinolines

(2014) Virendra Kumar Tiwari et al.   CHEMICAL COMMUNICATIONS

Versatile ruthenium(ii)-catalyzed C–H cyanations of benzamides

(2014) Weiping Liu et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

(2014) Chao Feng et al.   CHEMICAL COMMUNICATIONS

Iridium-Catalyzed C–H Amination with Anilines at Room Temperature: Compatibility of Iridacycles with External Oxidants

(2014) Hyunwoo Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation Sequence

(2014) Hideya Ikemoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Intramolecular Redox-Neutral or Oxidative Cyclization of Alkynes: Short, Efficient Synthesis of 3,4-Fused Indole Skeletons

(2014) Bing Zhou et al.   ORGANIC LETTERS

Strain-Promoted Oxidative Annulation of Arynes and Cyclooctynes with Benzamides: Palladium-Catalyzed C–H/N–H Activation for the Synthesis of N-Heterocycles

(2014) Xianglong Peng et al.   ORGANIC LETTERS

Amide-Assisted Acetoxylation of Vinyl C(sp2)–H Bonds by Rhodium Catalysis

(2014) Wenlong Yu et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Hydroarylation of Anilides with Alkynes: An Efficient Route to Ortho-Alkenylated Anilines

(2014) Rajendran Manikandan et al.   ORGANIC LETTERS

Pd-Catalyzed Oxidative Coupling of Enamides and Alkynes for Synthesis of Substituted Pyrroles

(2014) Mi-Na Zhao et al.   ORGANIC LETTERS

Synthesis of Phosphoramidates: A Facile Approach Based on the C–N Bond Formation via Ir-Catalyzed Direct C–H Amidation

(2014) Hyunwoo Kim et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Selective Coupling of N-Methoxy-1H-indole-1-carboxamides and Aryl Boronic Acids

(2014) Jing Zheng et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Cyclization of Anilides with Substituted Propiolates or Acrylates: An Efficient Route to 2-Quinolinones

(2014) Rajendran Manikandan et al.   ORGANIC LETTERS

Comparative Investigations of Cp*-Based Group 9 Metal-Catalyzed Direct C–H Amination of Benzamides

(2014) Travis M. Figg et al.   ORGANOMETALLICS

Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

(2014) Min Zhang et al.   Organic Chemistry Frontiers

Mild Palladium-Catalyzed Oxidative Directortho-CH Acylation of Anilides under Aqueous Conditions

(2013) Fruzsina Szabó et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed CH Olefination of Aryl Weinreb Amides

(2013) Yan Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Room Temperature Palladium-Catalyzed Decarboxylative Acyl/Aroylation using [Fe(III)(EDTA)(η2-O2)]3−as Oxidant at Biological pH

(2013) Sugandha Sharma et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct CH Amination of Arenes with Alkyl Azides under Rhodium Catalysis

(2013) Kwangmin Shin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Indole Synthesis by Rhodium(III)-Catalyzed Hydrazine-Directed CH Activation: Redox-Neutral and Traceless by NN Bond Cleavage

(2013) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed Cyclization of Amides with α,β-Unsaturated Aldehydes and Ketones to Azepinones: Application to the Synthesis of the Homoprotoberberine Framework

(2013) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates

(2013) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-catalyzed oxidative ortho-benzoxylation of acetanilides with aromatic acids

(2013) Kishor Padala et al.   CHEMICAL COMMUNICATIONS

Ruthenium-catalyzed ortho-C–H halogenations of benzamides

(2013) Lianhui Wang et al.   CHEMICAL COMMUNICATIONS

Oxidative C–H amination reactions

(2013) Marie-Laure Louillat et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Phenanthridinones fromN-Methoxybenzamides and Aryltriethoxysilanes through RhIII-Catalyzed CH and NH Bond Activation

(2013) Natarajan Senthilkumar et al.   Chemistry-An Asian Journal

Iridium-Catalyzed Direct Arene C–H Bond Amidation with Sulfonyl- and Aryl Azides

(2013) Donggun Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed C–H Activation and Double Directing Group Strategy for the Regioselective Synthesis of Naphthyridinones

(2013) John R. Huckins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed C–H Iodination Using Molecular I2 as the Sole Oxidant

(2013) Xiao-Chen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir(III)-Catalyzed Mild C–H Amidation of Arenes and Alkenes: An Efficient Usage of Acyl Azides as the Nitrogen Source

(2013) Jaeyune Ryu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis

(2013) Mirim Kim et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of 2-Aminophenols and Heterocycles by Ru-Catalyzed C–H Mono- and Dihydroxylation

(2013) Xinglin Yang et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Halogenation of Vinylic C–H Bonds: Rapid and General Access to Z-Halo Acrylamides

(2013) Nadine Kuhl et al.   ORGANIC LETTERS

Ruthenium-Catalyzed C–H Oxygenation on Aryl Weinreb Amides

(2013) Fanzhi Yang et al.   ORGANIC LETTERS

Oxidant-Free Rh(III)-Catalyzed Direct C–H Olefination of Arenes with Allyl Acetates

(2013) Chao Feng et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Tandem C–H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indoles

(2013) Ana Cajaraville et al.   ORGANIC LETTERS

Rh(iii)-catalyzed C–H activation/cycloaddition of benzamides and methylenecyclopropanes: divergence in ring formation

(2013) Sunliang Cui et al.   Chemical Science

Rh(iii)-catalyzed C–H activation/[4 + 3] cycloaddition of benzamides and vinylcarbenoids: facile synthesis of azepinones

(2013) Sunliang Cui et al.   Chemical Science

Palladium-catalyzed C–H activation of anilides at room temperature: ortho-arylation and acetoxylation

(2013) Fan Yang et al.   RSC Advances

A one-pot process for palladium catalyzed direct C–H acylation of anilines in water using a removable ortho directing group

(2013) Fruzsina Szabó et al.   RSC Advances

Rhodium(III)-Catalyzed Intramolecular Annulation through CH Activation: Total Synthesis of (±)-Antofine, (±)-Septicine, (±)-Tylophorine, and Rosettacin

(2012) Xianxiu Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct CH Arylation of Enamides with Simple Arenes

(2012) Sreekumar Pankajakshan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Oxidative CH Coupling ofN-Methoxybenzamides with Aryl Boronic Acids: One-Pot Synthesis of Phenanthridinones

(2012) Jaganathan Karthikeyan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines

(2012) Jaeyune Ryu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[RhIIICp*]-Catalyzed Dehydrogenative ArylAryl Bond Formation

(2012) Joanna Wencel-Delord et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective arene functionalization through sequential oxidative and non-oxidative Heck reactions

(2012) Bernd Schmidt et al.   CHEMICAL COMMUNICATIONS

Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes: efficient access to (Z,E)-dienamides

(2012) Jian Zhang et al.   CHEMICAL COMMUNICATIONS

Toluene derivatives as simple coupling precursors for cascade palladium-catalyzed oxidative C–H bond acylation of acetanilides

(2012) Yinuo Wu et al.   CHEMICAL COMMUNICATIONS

Undirected Arene and Chelate-Assisted Olefin C-H Bond Activation: [RhIIICp*]-Catalyzed Dehydrogenative Alkene-Arene Coupling as a New Pathway for the Selective Synthesis of Highly SubstitutedZOlefins

(2012) Joanna Wencel-Delord et al.   Chemistry-An Asian Journal

Palladium-Catalyzed Direct ortho-Acylation through an Oxidative Coupling of Acetanilides with Toluene Derivatives

(2012) Zhangwei Yin et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Ortho-Alkoxylation of Anilides via C–H Activation

(2012) Tao-Shan Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Ortho-Arylation of Benzamides via Direct sp2 C–H Bond Activation

(2012) Dan-Dan Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed Ortho Trifluoromethylation of Arenes and Insights into the Coordination Mode of Acidic Amide Directing Groups

(2012) Xing-Guo Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Yielding, Versatile, and Practical [Rh(III)Cp*]-Catalyzed Ortho Bromination and Iodination of Arenes

(2012) Nils Schröder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Acylation of Cyclic Enamides with α-Oxocarboxylic Acids by Palladium-Catalyzed C–H Activation at Room Temperature

(2012) Hua Wang et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C(sp2)–H Bond Hydroxylation: Site-Selective C–O Bond Formation on Benzamides

(2012) Vedhagiri S. Thirunavukkarasu et al.   ORGANIC LETTERS

Regioselective Ortho-Arylation and Alkenylation of N-Alkyl Benzamides with Boronic Acids via Ruthenium-Catalyzed C–H Bond Activation: An Easy Route to Fluorenones Synthesis

(2012) Ravi Kiran Chinnagolla et al.   ORGANIC LETTERS

Palladium-Catalyzed Trifluoromethylation of Aromatic C–H Bond Directed by an Acetamino Group

(2012) Li-Sheng Zhang et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

(2012) Bin Li et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Alkenylations of Anilides and Benzamides in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Pyrrole Synthesis via Oxidative Annulation of Enamides and Alkynes

(2012) Bin Li et al.   ORGANIC LETTERS

Palladium-catalyzed direct oxidative ortho-acylation of anilides with toluene derivatives

(2012) Jianquan Weng et al.   TETRAHEDRON LETTERS

Copper-catalyzed olefinic trifluoromethylation of enamides at room temperature

(2012) Chao Feng et al.   Chemical Science

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Oxidative CH Bond Acylation of Acetanilides with Benzylic Alcohols

(2011) Yu Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium(II)-Catalyzed Direct ortho-CH Acylation of Anilides by Oxidative Cross-Coupling with Aldehydes using tert-Butyl Hydroperoxide as Oxidant

(2011) Chun-Wo Chan et al.   ADVANCED SYNTHESIS & CATALYSIS

CC Bond Formation via CH Activation and CN Bond Formation via Oxidative Amination Catalyzed by Palladium- Polyoxometalate Nanomaterials Using Dioxygen as the Terminal Oxidant

(2011) Leng Leng Chng et al.   ADVANCED SYNTHESIS & CATALYSIS

One-Pot Formation of CC and CN Bonds through Palladium-Catalyzed Dual CH Activation: Synthesis of Phenanthridinones

(2011) Guan-Wu Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Oxidative Annulation by Cleavage of CH/NH Bonds

(2011) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild CH Halogenation of Anilides and the Isolation of an Unusual Palladium(I)-Palladium(II) Species

(2011) Robin B. Bedford et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of isoindolinones via palladium-catalyzed C–H activation of N-methoxybenzamides

(2011) Dan-Dan Li et al.   CHEMICAL COMMUNICATIONS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed ortho-Acylation of Acetanilides with Aldehydes through Direct CH Bond Activation

(2011) Chengliang Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

RhIII-Catalyzed Oxidative Olefination of Vinylic CH Bonds: Efficient and Selective Access to Di-unsaturated α-Amino Acid Derivatives and Other Linear 1,3-Butadienes

(2011) Tatiana Besset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alternative to Benzoquinone for Room-Temperature Fujiwara–Moritani Reactions

(2011) Xinzhu Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Expedient Synthesis ofN-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed Amidation of Aryl and Vinyl C–H Bonds with Isocyanates

(2011) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C−H Aminations of Anilides withN-Fluorobenzenesulfonimide

(2011) Kai Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Understanding of the Unexpected Meta Selectivity in Copper-Catalyzed Anilide C–H Bond Arylation

(2011) Bo Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Intermolecular C–H Amination with Alkylamines

(2011) Eun Jeong Yoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Palladium-Catalyzed Oxidative C–H Bond Coupling of Steered Acetanilides and Aldehydes: A Facile Access toortho-Acylacetanilides

(2011) Yinuo Wu et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative Synthesis of 2-Pyridones through C–H/N–H Bond Functionalizations

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Cobalt-Catalyzed Coupling of Alkyl Grignard Reagent with Benzamide and 2-Phenylpyridine Derivatives through Directed C–H Bond Activation under Air

(2011) Quan Chen et al.   ORGANIC LETTERS

Palladium(II)-Catalyzed Direct Alkoxylation of Arenes: Evidence for Solvent-Assisted Concerted Metalation Deprotonation

(2011) Megha Anand et al.   ORGANIC LETTERS

Rh[III]-Catalyzed Direct C–H Amination Using N-Chloroamines at Room Temperature

(2011) Christoph Grohmann et al.   ORGANIC LETTERS

Synthesis and characterization of a cyclic vinylpalladium(ii) complex: vinylpalladium species as the possible intermediate in the catalytic direct olefination reaction of enamide

(2011) Yun-He Xu et al.   Chemical Science

Palladium-Catalyzed Oxidative sp2 CH Bond Acylation with Aldehydes

(2010) Olivier Baslé et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Highly Effective Pd-Catalyzed ortho Olefination of Acetanilides: Broad Substrate Scope and High Tolerability

(2010) Byung Seok Kim et al.   Chemistry-An Asian Journal

Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover

(2010) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Intermolecularortho-C−H Amidation of Anilides byN-Nosyloxycarbamate

(2010) Ka-Ho Ng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides

(2010) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation

(2010) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room Temperature Palladium-Catalyzed Decarboxylativeortho-Acylation of Acetanilides with α-Oxocarboxylic Acids

(2010) Ping Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzedortho-Alkylation of Secondary Benzamide with Alkyl Chloride through Directed C−H Bond Activation

(2010) Quan Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Direct Arylation of Cyclic Enamides with Aryl Silanes by sp2 CH Activation

(2009) Hai Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct arylation of cyclic enamides via Pd(ii)-catalyzed C–H activation

(2009) Hai Zhou et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Alkoxylation ofN-Methoxybenzamides via Direct sp2C−H Bond Activation

(2009) Guan-Wu Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

A Meta-Selective Copper-Catalyzed C-H Bond Arylation

(2009) R. J. Phipps et al.   SCIENCE

Synthesis of β-, γ-, and δ-Lactams via Pd(II)-Catalyzed C−H Activation Reactions

(2008) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes

(2008) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Twofold C−H Functionalization: Palladium-CatalyzedOrthoArylation of Anilides

(2008) Gordon Brasche et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART

Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components

(2007) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION