Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions

An Efficient Method for the Preparation of Styrene Derivatives via Rh(III)-Catalyzed Direct C–H Vinylation

(2015) Kate D. Otley et al.   ORGANIC LETTERS

Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

(2015) Yi Lu et al.   Chemical Science

Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions

(2014) Yuki Hoshino et al.   ADVANCED SYNTHESIS & CATALYSIS

The Oxidative Annulation of Tertiary Benzyl Alcohols with Internal Alkynes using an (Electron-Deficient η5-Cyclopenta- dienyl)Rhodium(III) Catalyst under Ambient Conditions

(2014) Miho Fukui et al.   ADVANCED SYNTHESIS & CATALYSIS

An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and AlkenesviaCH Functionalization

(2014) Lei Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Weakly Coordinating Directing Groups for Ruthenium(II)- Catalyzed CH Activation

(2014) Suman De Sarkar et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Cyclative Capture Approach to Diverse 1-Aminoindoline Derivatives at Room Temperature

(2014) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed Intramolecular Dehydrogenative Aryl–Aryl Coupling Using Air as Terminal Oxidant

(2014) Hannah Baars et al.   CHEMISTRY LETTERS

Palladium-Catalyzed Aryl C–H Olefination with Unactivated, Aliphatic Alkenes

(2014) Arghya Deb et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Oxidative Olefination of Furans with Unactivated Alkenes

(2014) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Intramolecular Redox-Neutral or Oxidative Cyclization of Alkynes: Short, Efficient Synthesis of 3,4-Fused Indole Skeletons

(2014) Bing Zhou et al.   ORGANIC LETTERS

Palladium-Catalyzed C-2 Selective Olefination of Thiazoles

(2014) Wei Liu et al.   ORGANIC LETTERS

Aerobic Direct C–H Arylation of Nonbiased Olefins

(2014) Nicolas Gigant et al.   ORGANIC LETTERS

Access to Cinnamyl Derivatives from Arenes and Allyl Esters by a Biomimetic Aerobic Oxidative Dehydrogenative Coupling

(2014) Nicolas Gigant et al.   ORGANIC LETTERS

Rh-catalyzed sulfonic acid group directed ortho C–H olefination of arenes

(2013) Yi Dong et al.   CHEMICAL COMMUNICATIONS

Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed CH Bond Activation

(2013) Bin Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium- and Iridium-Catalyzed Dehydrogenative Cyclization through Double C–H Bond Cleavages To Produce Fluorene Derivatives

(2013) Masaki Itoh et al.   JOURNAL OF ORGANIC CHEMISTRY

Thioether-Promoted Direct Olefination of Polyfluoroarenes Catalyzed by Palladium

(2013) Cai-Zhi Wu et al.   ORGANIC LETTERS

Phosphoryl-Related Directing Groups in Rhodium(III) Catalysis: A General Strategy to Diverse P-Containing Frameworks

(2013) Dongbing Zhao et al.   ORGANIC LETTERS

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ether-Directedortho-C-H Olefination with a Palladium(II)/Monoprotected Amino Acid Catalyst

(2012) Gang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Fluorene Derivatives through Rhodium-Catalyzed Dehydrogenative Cyclization

(2012) Keisuke Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group

(2012) Chengming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Direct Oxidative Coupling of Arenes with Olefins by Rh-Catalyzed CH Activation in Air: Observation of a Strong Cooperation of the Acid

(2012) Lu Zheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed N-Nitroso-Directed C–H Olefination of Arenes. High-Yield, Versatile Coupling under Mild Conditions

(2012) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of remote meta-C–H bonds assisted by an end-on template

(2012) Dasheng Leow et al.   NATURE

Rhodium(III)- and Ruthenium(II)-Catalyzed Olefination of Isoquinolones

(2012) Peng Zhao et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

(2012) Bin Li et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Alkenylations of Anilides and Benzamides in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Catalytic [2+2+1] Cross-Cyclotrimerization of Silylacetylenes and Two Alkynyl Esters To Produce Substituted Silylfulvenes

(2011) Yu Shibata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C–H Bond Cleavage Directed by a Nitrogen-containing Group

(2011) Yuto Hashimoto et al.   CHEMISTRY LETTERS

Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group

(2011) Satoshi Mochida et al.   JOURNAL OF ORGANIC CHEMISTRY

Ligand-Promoted C-3 Selective C–H Olefination of Pyridines with Pd Catalysts

(2011) Mengchun Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigating N-methoxy-N′-aryl ureas in oxidative C–H olefination reactions: an unexpected oxidation behaviour

(2011) Jens Willwacher et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Pd-Catalyzed Olefination of Furans and Thiophenes with Allyl Esters

(2011) Yuexia Zhang et al.   ORGANIC LETTERS

Rhodium-Catalyzed Selective Olefination of Arene Esters via C−H Bond Activation

(2011) Sae Hume Park et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Olefination ofN-(1-Naphthyl)sulfonamides Using Activated and Unactivated Alkenes

(2011) Xuting Li et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative Vinylation of Heteroarene Carboxylic Acids with Alkenes via Regioselective C−H Bond Cleavage

(2011) Takumi Ueyama et al.   ORGANIC LETTERS

Constructing Multiply Substituted Arenes Using Sequential Palladium(II)-Catalyzed CH Olefination

(2010) Keary M. Engle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Oxidative Olefination of CH Bonds in Acetophenones and Benzamides

(2010) Frederic W. Patureau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(OAc)2Catalyzed Olefination of Highly Electron-Deficient Perfluoroarenes

(2010) Xingang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Hydroxyl-Directed C−H Olefination Enabled by Monoprotected Amino Acid Ligands

(2010) Yi Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism

(2010) Keary M. Engle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides

(2010) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Stilbene and Distyrylbenzene Derivatives through Rhodium-CatalyzedOrtho-Olefination and Decarboxylation of Benzoic Acids

(2010) Satoshi Mochida et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Tandem Oxidative Olefination−Michael Reactions between Aryl Carboxamides and Alkenes

(2010) Fen Wang et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation

(2010) Andy S. Tsai et al.   ORGANIC LETTERS

Chelate-Assisted Oxidative Coupling Reaction of Arylamides and Unactivated Alkenes: Mechanistic Evidence for Vinyl C−H Bond Activation Promoted by an Electrophilic Ruthenium Hydride Catalyst

(2010) Ki-Hyeok Kwon et al.   ORGANOMETALLICS

Palladium(II)-Catalyzed Regioselective Direct C2 Alkenylation of Indoles and Pyrroles Assisted by theN-(2-Pyridyl)sulfonyl Protecting Group

(2009) Alfonso García-Rubia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Mono- and Divinylation of 1-Phenylpyrazoles and Related Compounds via Regioselective C−H Bond Cleavage

(2009) Nobuyoshi Umeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions

(2009) Junliang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Olefination of Electron-Deficient Arenes Using 2,6-Dialkylpyridine Ligands

(2009) Yang-Hui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Enantioselective C−H Olefination of Diphenylacetic Acids

(2009) Bing-Feng Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled Reactivity and Selectivity in a Synthetically Versatile Aryl C-H Olefination

(2009) D.-H. Wang et al.   SCIENCE

Synthesis of Indolines and Tetrahydroisoquinolines from Arylethylamines by PdII-Catalyzed CH Activation Reactions

(2008) Jiao-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C−H Functionalization of PyridineN-Oxides: Highly Selective Alkenylation and Direct Arylation with Unactivated Arenes

(2008) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes

(2008) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective C−H Functionalization Directed by a Removable Carboxyl Group:  Palladium-Catalyzed Vinylation at the Unusual Position of Indole and Related Heteroaromatic Rings

(2008) Atsushi Maehara et al.   ORGANIC LETTERS