Journal
ORGANIC LETTERS
Volume 19, Issue 10, Pages 2498-2501Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00695
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Funding
- National Natural Science Foundation of China (NSFC) [21502037, 21373073, 21672048]
- Natural Science Foundation of Zhejiang Province (ZJNSF) [LY15B020008]
- Program for Innovative Research Team in Chinese University [IRT 1231]
- Hangzhou Normal University
- Qianjiang Scholar award from Zhejiang Province, China
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A ruthenium-catalyzed direct cross-coupling between alkenes and alkynes via directed C-H bond activation is described. By using N,N-disubstituted aminocarbonyl as a directing group, this oxidant-free and atom-economic protocol resulted in high efficiency and good stereoselectivities, which opens a novel synthetic passway for access to substituted (Z,Z)-butadiene skeletons.
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