Copper-Catalyzed Stereospecific Transformations of Alkylboronic Esters

Hydroamination, Aminoboration, and Carboamination with Electrophilic Amination Reagents: Umpolung-Enabled Regio- and Stereoselective Synthesis of N-Containing Molecules from Alkenes and Alkynes

(2022) Koji Hirano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Stereochemical Course of Pd-Catalyzed Suzuki Reactions Using Primary Alkyltrifluoroborate Nucleophiles

(2021) Benjamin Murray et al.   ACS Catalysis

Chan–Lam Amination of Secondary and Tertiary Benzylic Boronic Esters

(2021) James D. Grayson et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective Synthesis of anti Vicinal Silylboronates by Conjunctive Cross Coupling

(2020) James Patrick Morken et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rational Design of an Iron-Based Catalyst for Suzuki-Miyaura Cross-Couplings Involving Heteroaromatic Boronic Esters and Tertiary Alkyl Electrophiles

(2020) Michael P. Crockett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CuH-Catalyzed Olefin Functionalization: From Hydroamination to Carbonyl Addition

(2020) Richard Y. Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Catalyzed Asymmetric Cross-Coupling Reaction of Fluorinated Secondary Benzyl Bromides with Lithium Aryl Boronates/ZnBr2

(2020) Weichen Huang et al.   ORGANIC LETTERS

Diastereo‐ and Enantioselective Cross‐Couplings of Secondary Alkylcopper Reagents with 3‐Halogeno‐Unsaturated Carbonyl Derivatives

(2020) Alexander Kremsmair et al.   CHEMISTRY-A EUROPEAN JOURNAL

Axial shielding of Pd(II) complexes enables perfect stereoretention in Suzuki-Miyaura cross-coupling of Csp3 boronic acids

(2019) Jonathan W. Lehmann et al.   Nature Communications

Facilitating the transmetalation step with aryl-zincates in nickel-catalyzed enantioselective arylation of secondary benzylic halides

(2019) Weichen Huang et al.   Nature Communications

Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Triflates and Lithium Arylborates

(2019) Hung A. Duong et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Preparation and Reactions of Chiral Secondary Alkyllithiums

(2019) Juri Skotnitzki et al.   SYNTHESIS-STUTTGART

Aminoazanium of DABCO: An Amination Reagent for Alkyl and Aryl Pinacol Boronates

(2019) Xingxing Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Modified System for the Synthesis of Enantioenriched N -Arylamines through Copper-Catalyzed Hydroamination

(2018) Saki Ichikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Optically Enriched Secondary Alkyllithium and Alkylcopper Reagents-Synthesis of (−)-Lardolure and Siphonarienal

(2018) Varvara Morozova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design, synthesis and biological evaluation of substituted (+)-SG-1 derivatives as novel anti-HIV agents

(2018) Xiaoyu Liu et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Copper-catalyzed cross-coupling of aryl-, primary alkyl-, and secondary alkylboranes with heteroaryl bromides

(2018) Allison M. Bergmann et al.   CHEMICAL COMMUNICATIONS

Elucidating the Role of the Boronic Esters in the Suzuki–Miyaura Reaction: Structural, Kinetic, and Computational Investigations

(2018) Andy A. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope

(2018) Lu Yan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Protocol for Direct Stereospecific Amination of Primary, Secondary, and Tertiary Alkylboronic Esters

(2018) James Morken et al.   SYNLETT

Enantiodivergent Pd-catalyzed C–C bond formation enabled through ligand parameterization

(2018) Shibin Zhao et al.   SCIENCE

Intermolecular Reductive C–N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV═O Catalysis

(2018) Trevor V. Nykaza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Functionalized Alkenes by a Transition-Metal-Free Zweifel Coupling

(2017) Roly J. Armstrong et al.   ORGANIC LETTERS

50 Years of Zweifel Olefination: A Transition-Metal-Free Coupling

(2017) Varinder Aggarwal et al.   SYNTHESIS-STUTTGART

Catalytic SN 2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis

(2016) Ying Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Diastereoselective 1,2-Additions to α-Ketoesters with Diborylmethane and Substituted 1,1-Diborylalkanes

(2016) Stephanie A. Murray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The copper-catalysed Suzuki–Miyaura coupling of alkylboron reagents: disproportionation of anionic (alkyl)(alkoxy)borates to anionic dialkylborates prior to transmetalation

(2016) Prakash Basnet et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Amidation of Primary and Secondary Alkyl Boronic Esters

(2016) Luis M. Mori-Quiroz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Catalyzed Electrophilic Amination: Application of O -Benzoylhydroxylamines in the Construction of the C−N Bond

(2016) Xu Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Ketones and Esters from Heteroatom-Functionalized Alkenes by Cobalt-Mediated Hydrogen Atom Transfer

(2016) Xiaoshen Ma et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds

(2016) Marcin Odachowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Progress in Copper-Catalyzed Asymmetric Allylic Substitution Reactions Using Organoboron Nucleophiles

(2016) Ryo Shintani   SYNTHESIS-STUTTGART

Stereoselective Retentive Domino Transmetalations of Secondary Alkyllithium Compounds to Functionalized Secondary Alkylcopper Reagents

(2015) Kohei Moriya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver(I)-Catalyzed Diastereoselective Synthesis ofanti-1,2-Hydroxyboronates

(2015) Matthew V. Joannou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in copper-catalyzed asymmetric coupling reactions

(2015) Fengtao Zhou et al.   Beilstein Journal of Organic Chemistry

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

(2015) Alan H. Cherney et al.   CHEMICAL REVIEWS

Synthesis of Enantioenriched Alkylfluorides by the Fluorination of Boronate Complexes

(2015) Christopher Sandford et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalysed cross-coupling: an untapped potential

(2015) Surendra Thapa et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex

(2014) Fanke Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Pd-Catalyzed Cross-Coupling Reactions of Secondary Alkylboron Nucleophiles and Aryl Chlorides

(2014) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiospecific sp2–sp3 coupling of secondary and tertiary boronic esters

(2014) Amadeu Bonet et al.   Nature Chemistry

Copper-Catalyzed Cross-Coupling of Vinylsiloxanes with Bromoalkynes: Synthesis of Enynes

(2014) Loïc Cornelissen et al.   ORGANIC LETTERS

Recent progress in copper-catalyzed electrophilic amination

(2014) Xiaoyu Yan et al.   Catalysis Science & Technology

Direct N-cyclopropylation of secondary acyclic amides promoted by copper

(2013) Emilie Racine et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Amination of Arylboronates with N,N-Dialkylhydroxylamines

(2012) Naoki Matsuda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Alkyl-Alkyl Suzuki-Miyaura Coupling

(2012) Takuji Hatakeyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Hindered Anilines: Copper-Catalyzed Electrophilic Amination of Aryl Boronic Esters

(2012) Richard P. Rucker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Direct Stereospecific Amination of Alkyl and Aryl Pinacol Boronates

(2012) Scott N. Mlynarski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Tertiary Alkyl Amines from Terminal Alkenes: Copper-Catalyzed Amination of Alkyl Boranes

(2012) Richard P. Rucker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Construction of Quaternary Stereogenic Centers from Tertiary Boronic Esters: Methodology and Applications

(2011) Ravindra P. Sonawane et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific Cross-Coupling between Alkenylboronates and Alkyl Halides Catalyzed by Iron–Bisphosphine Complexes

(2011) Toru Hashimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

CuI-catalyzed Suzuki coupling reaction of organoboronic acids with alkynyl bromides

(2011) Shihua Wang et al.   TETRAHEDRON

Copper-Catalyzed Cross-Coupling of Alkyl and Aryl Grignard Reagents with Alkynyl Halides

(2010) Gérard Cahiez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Suzuki−Miyaura Coupling of Alkyl Halides

(2010) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY