Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 11, Pages 2481-2511Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201601607
Keywords
cross-coupling; electrophilic amination; O-benzoylhydroxylamines; tertiary amines; transition-metal catalysis
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Funding
- National Natural Science Foundation of China [21302057, 21405095]
- Young Talents Joint Fund of Shandong Province [ZR2015JL005]
- CPSF [2016M590736]
- Special Funding for Postdoctoral Innovation Project of Shandong Province [201501002]
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Transition-metal-catalyzed electrophilic amination has been developed into a powerful tool for C-N bond construction. So far, O-benzoylhydroxylamines are the most widely used electrophilic aminating reagents. Herein, we summarize the recent advances of O-benzoylhydroxylamines involved in electrophilic amination catalyzed by transition metals. Several pioneering studies and some of the relevant mechanisms are discussed in this review.
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