4.7 Article

Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Triflates and Lithium Arylborates

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 19, Pages 12686-12691

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02105

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Funding

  1. GSK-EDB Singapore Partnership for Green and Sustainable Manufacturing
  2. Institute of Chemical and Engineering Sciences (ICES), Agency for Science, Technology and Research (A*STAR), Singapore

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A catalyst system comprising CoCl2/IAd center dot HBF4 enables the Suzuki-Miyaura cross-coupling reaction of a broad range of aryl triflates and arylboronic esters that are activated by n-butyllithium.

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