Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 44, Pages 15654-15658Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603677
Keywords
alkyl boronic esters; amides; copper; cross-coupling; NacNac ligand
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Funding
- University of Delaware (UD)
- NIH [P20GM104316, NSF CHE0421224, CHE1229234, CHE0840401, NIH P20GM104316, P30GM110758, S10RR026962, S10OD016267]
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The oxidative copper-catalyzed cross-coupling of functionalized alkyl boronic esters with primary amides is reported. Through the identification of appropriate diketimine ligands, conditions for efficient coupling of both primary and secondary alkyl boronic esters with diverse primary amides, including acetamide, have been developed.
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