Rational Design of an Iron-Based Catalyst for Suzuki-Miyaura Cross-Couplings Involving Heteroaromatic Boronic Esters and Tertiary Alkyl Electrophiles

Iron-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions between Alkyl Halides and Unactivated Arylboronic Esters

(2018) Michael P. Crockett et al.   ORGANIC LETTERS

Enantiodivergent Pd-catalyzed C–C bond formation enabled through ligand parameterization

(2018) Shibin Zhao et al.   SCIENCE

Ni-Catalyzed Reductive Coupling of Electron-Rich Aryl Iodides with Tertiary Alkyl Halides

(2018) Xuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Xantphos as a Branch-Selective Ligand for the Acyclic sec-Alkyl Negishi Cross-Coupling of Heteroaryl Halides

(2018) Alan H. Cherney et al.   ORGANOMETALLICS

DFT and AFIR Study on the Mechanism and the Origin of Enantioselectivity in Iron-Catalyzed Cross-Coupling Reactions

(2017) Akhilesh K. Sharma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Nakamura’s Bisphosphine-Iron-Catalyzed Asymmetric C(sp2)–C(sp3) Cross-Coupling Reaction: The Role of Spin in Controlling Arylation Pathways

(2017) Wes Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiospecific and Iterative Suzuki–Miyaura Cross-Couplings

(2017) Jason P. G. Rygus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Quaternary Centers via Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling of Tertiary Sulfones

(2017) Zachary T. Ariki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toxicity of Metal Compounds: Knowledge and Myths

(2017) Ksenia S. Egorova et al.   ORGANOMETALLICS

Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

(2017) Junwon Choi et al.   SCIENCE

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates

(2017) Philipp Schäfer et al.   Nature Communications

Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity

(2016) Qi Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Suzuki-Miyaura Coupling of a Tertiary Iodocyclopropane with Wide Boronic Acid Substrate Scope: Coupling Reaction Outcome Depends on Radical Species Stability

(2015) Keisuke Yotsuji et al.   ADVANCED SYNTHESIS & CATALYSIS

Iron-Catalyzed Cross-Coupling of Alkenyl Acetates

(2015) Dominik Gärtner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Radical Nature of Iron-Catalyzed Cross-Coupling Reactions

(2015) Anna Hedström et al.   CHEMISTRY-A EUROPEAN JOURNAL

Analysis of Past and Present Synthetic Methodologies on Medicinal Chemistry: Where Have All the New Reactions Gone?

(2015) Dean G. Brown et al.   JOURNAL OF MEDICINAL CHEMISTRY

Nickel-Catalyzed Reductive Coupling of Aryl Bromides with Tertiary Alkyl Halides

(2015) Xuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expedient Iron-Catalyzed Coupling of Alkyl, Benzyl and Allyl Halides with Arylboronic Esters

(2014) Robin B. Bedford et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cross-Electrophile Coupling: Principles of Reactivity and Selectivity

(2014) Daniel A. Everson et al.   JOURNAL OF ORGANIC CHEMISTRY

Low-Coordinate Iron(II) Complexes of a Bulky Bis(carbene)borate Ligand

(2014) Wei-Tsung Lee et al.   ORGANOMETALLICS

Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations

(2013) Susan L. Zultanski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Controlled Polymerization of Lactide Catalyzed by Bis(imino)pyridine Iron Bis(alkoxide) Complexes

(2013) Ashley B. Biernesser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

Simplifying Iron-Phosphine Catalysts for Cross-Coupling Reactions

(2012) Robin B. Bedford et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addressing Challenges in Palladium-Catalyzed Cross-Coupling Reactions Through Ligand Design

(2012) Rylan J. Lundgren et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cross-Coupling of Non-activated Chloroalkanes with Aryl Grignard Reagents in the Presence of Iron/N-Heterocyclic Carbene Catalysts

(2012) Sujit K. Ghorai et al.   ORGANIC LETTERS

Fe-catalysed Kumada-type alkyl–alkyl cross-coupling. Evidence for the intermediacy of Fe(i) complexes

(2012) Manuel Guisán-Ceinos et al.   Chemical Science

Kumada–Tamao–Corriu Coupling of Alkyl Halides Catalyzed by an Iron–Bisphosphine Complex

(2011) Takuji Hatakeyama et al.   CHEMISTRY LETTERS

Suzuki–Miyaura cross-coupling coupling reactions with low catalyst loading: a green and sustainable protocol in pure water

(2011) Aziz Fihri et al.   DALTON TRANSACTIONS

Stereospecific Cross-Coupling between Alkenylboronates and Alkyl Halides Catalyzed by Iron–Bisphosphine Complexes

(2011) Toru Hashimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Distinguishing Between Pathways for Transmetalation in Suzuki−Miyaura Reactions

(2011) Brad P. Carrow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Friedel-Crafts Alkylation of Thiophenes with Ethyl Glyoxylate: Easy Access to Chiral Secondary Alcohols

(2010) Zhong Huang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Suzuki−Miyaura Coupling of Alkyl Halides

(2010) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple mixed Fe–Zn catalysts for the Suzuki couplings of tetraarylborates with benzyl halides and 2-halopyridines

(2009) Robin B. Bedford et al.   CHEMICAL COMMUNICATIONS

Escape from Flatland: Increasing Saturation as an Approach to Improving Clinical Success

(2009) Frank Lovering et al.   JOURNAL OF MEDICINAL CHEMISTRY

Electronic Structure and Reactivity of Three-Coordinate Iron Complexes

(2008) Patrick L. Holland   ACCOUNTS OF CHEMICAL RESEARCH