Preparation of Optically Enriched Secondary Alkyllithium and Alkylcopper Reagents-Synthesis of (−)-Lardolure and Siphonarienal

α-Sulfinyl Benzoates as Precursors to Li and Mg Carbenoids for the Stereoselective Iterative Homologation of Boronic Esters

(2017) Giorgia Casoni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergy of synthesis, computation and NMR reveals correct baulamycin structures

(2017) Jingjing Wu et al.   NATURE

Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C–H activation

(2017) Natthawat Semakul et al.   Chemical Science

Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene

(2016) Xiben Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper mediated carbometalation reactions

(2016) D. S. Müller et al.   CHEMICAL SOCIETY REVIEWS

Stereoselective Synthesis and Retentive Trapping of α-Chiral Secondary Alkyllithiums Leading to Stereodefined α,β-Dimethyl Carboxylic Esters

(2016) Varvara Morozova et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groups

(2016) Fanke Meng et al.   NATURE

Strategies for the Synthesis of Deoxypropionates

(2016) Sabine Laschat et al.   SYNTHESIS-STUTTGART

Stereoselective Synthesis of Secondary Alkyllithiums and Their Application to Stereoselective Cuprations or Intramolecular Carbolithiations for the Stereoselective Synthesis of Alkylidene­cyclobutanes

(2016) Paul Knochel et al.   SYNTHESIS-STUTTGART

Concise synthesis of (+)-fastigiatine

(2016) Renzo A. Samame et al.   Chemical Science

Stereoselective Retentive Domino Transmetalations of Secondary Alkyllithium Compounds to Functionalized Secondary Alkylcopper Reagents

(2015) Kohei Moriya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position

(2015) Kohei Moriya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereocontrolled Formation of Several Carbon–Carbon Bonds in Acyclic Systems

(2015) Guillaume Eppe et al.   CHEMICAL REVIEWS

Enantioselective Installation of Quaternary Centers in Cyclic Oxonitriles

(2015) Yakup Gunes et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Rhodium-Catalyzed Isomerization of 4-Iminocrotonates: Asymmetric Synthesis of a Unique Chiral Synthon

(2015) Wen-Zhen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation, structure and reactivity of tertiary organolithium reagents

(2015) Matthew A. Perry et al.   NATURAL PRODUCT REPORTS

Stereoselective syntheses of siphonarienal and siphonarienone

(2015) Supriya Ghanty et al.   TETRAHEDRON-ASYMMETRY

Enantioselective Construction of Quaternary Stereogenic Carbon Atoms by the Lewis Base Catalyzed Additions of Silyl Ketene Imines to Aldehydes

(2014) Scott E. Denmark et al.   CHEMISTRY-A EUROPEAN JOURNAL

“The Great Beauty” of organolithium chemistry: a land still worth exploring

(2014) Vito Capriati et al.   DALTON TRANSACTIONS

Complexation Phenomena and Dynamics at Work in the Lithiation Reactions of Small-Ring Heterocycles: Regio- and Stereoselectivity

(2014) Vito Capriati et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 1,1-Disubstituted Tetrahydroisoquinolines by Lithiation and Substitution, with in Situ IR Spectroscopy and Configurational Stability Studies

(2014) Xiabing Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assembly-line synthesis of organic molecules with tailored shapes

(2014) Matthew Burns et al.   NATURE

Titanium Salalen Catalysts Based oncis-1,2-Diaminocyclohexane: Enantioselective Epoxidation of Terminal Non-Conjugated Olefins with H2O2

(2013) Albrecht Berkessel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Catalysis of the Mukaiyama Directed Aldol Reaction: 40 Years of Inspiration and Advances

(2013) Gregory L. Beutner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective Synthesis of Open-Chain Secondary Alkyllithium Compounds and Trapping Reactions with Electrophiles

(2013) Guillaume Dagousset et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Stereodefined Secondary Alkyllithium Compounds

(2013) Stephanie Seel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divergent Enantioselective Total Synthesis of Siphonarienal, Siphonarienone, and Pectinatone

(2013) Jhillu Singh Yadav et al.   HELVETICA CHIMICA ACTA

Direct observation of a lithiated oxirane: a synergistic study using spectroscopic, crystallographic, and theoretical methods on the structure and stereodynamics of lithiated ortho-trifluoromethyl styrene oxide

(2013) Antonio Salomone et al.   Chemical Science

Stereoselective synthesis of methyl branched chiral deoxypropionate units: a new route for synthesis of insect pheromone (−)-lardolure and (2R,4R,6R,8R) 2,4,6,8-tetramethylundecanoic acid

(2012) J.S. Yadav et al.   TETRAHEDRON LETTERS

Iterative strategies for the synthesis of deoxypropionates

(2010) Bjorn ter Horst et al.   CHEMICAL COMMUNICATIONS

Lithiated Fluorinated Styrene Oxides: Configurational Stability, Synthetic Applications, and Mechanistic Insight

(2010) Vito Capriati et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective and Stereoselective Copper(I)-Promoted Allylation and Conjugate Addition ofN-Boc-2-lithiopyrrolidine andN-Boc-2-lithiopiperidine

(2010) Iain Coldham et al.   JOURNAL OF ORGANIC CHEMISTRY

Total synthesis of the marine polypropionates, siphonarienal, siphonarienone, and pectinatone

(2009) Gowravaram Sabitha et al.   TETRAHEDRON-ASYMMETRY

Asymmetric Epoxidation of Olefins with Hydrogen Peroxide—Catalysis by an Aspartate-Containing Tripeptide

(2008) Albrecht Berkessel   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION