Catalytic SN 2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis

Silver(I)-Catalyzed Diastereoselective Synthesis ofanti-1,2-Hydroxyboronates

(2015) Matthew V. Joannou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes

(2015) Junghoon Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of (+)-Antroquinonol: An Antihyperglycemic Agent

(2015) Rohidas S. Sulake et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Heterocyclic Carbene–Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes

(2015) Ying Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyl-Directed Cross-Coupling: A Scalable Synthesis of Debromohamigeran E and Other Targets of Interest

(2015) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Diastereoselective Synthesis of 1,2-Hydroxyboronates through Cu-Catalyzed Additions of Alkylboronates to Aldehydes

(2015) Matthew V. Joannou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes

(2014) Kentaro Hojoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex

(2014) Fanke Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis

(2014) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nonracemic Allylic Boronates through Enantiotopic-Group-Selective Cross-Coupling of Geminal Bis(boronates) and Vinyl Halides

(2014) Bowman Potter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

(2014) Chunrui Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional organoboron compounds for scalable natural product synthesis

(2014) Fanke Meng et al.   NATURE

Copper-Catalyzed/Promoted Cross-coupling of gem-Diborylalkanes with Nonactivated Primary Alkyl Halides: An Alternative Route to Alkylboronic Esters

(2014) Zhen-Qi Zhang et al.   ORGANIC LETTERS

One-Pot Cross-Coupling of Diborylmethane for the Synthesis of Dithienyl­methane Derivatives

(2014) Kohei Endo et al.   SYNLETT

Copper-Catalyzed Enantioselective Allylic Substitution with Readily Accessible Carbonyl- and Acetal-Containing Vinylboron Reagents

(2012) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature

(2012) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of Symmetrical and Unsymmetrical Diarylmethanes via Diborylmethane

(2012) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes

(2012) Yoshinori Shido et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

(2011) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments in the field of oxa-Michael reactions

(2011) Carl F. Nising et al.   CHEMICAL SOCIETY REVIEWS

A Stereoselective Formal Synthesis of Leucascandrolide A

(2011) Kiyoun Lee et al.   ORGANIC LETTERS

Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of Benzylboronates

(2011) Kohei Endo et al.   ORGANIC LETTERS

Copper-Catalyzed γ-Selective Allyl−Alkyl Coupling between Allylic Phosphates and Alkylboranes

(2010) Hirohisa Ohmiya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature

(2010) Kohei Endo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereogenic-at-Metal Zn- and Al-Based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five-, Six-, and Seven-Membered-Ring β-Substituted Cyclic Enones

(2008) Tricia L. May et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

(2008) Syuzanna R. Harutyunyan et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

Investigation of an Organomagnesium-Based [3 + 3] Annelation to Pyrans and Its Application in the Synthesis of Rhopaloic Acid A

(2008) Julien C. R. Brioche et al.   JOURNAL OF ORGANIC CHEMISTRY