Journal
SYNTHESIS-STUTTGART
Volume 48, Issue 8, Pages 1087-1100Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1560406
Keywords
copper catalyst; allylic substitution; asymmetric catalysis; organoboron; diboron; silylboronate
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Funding
- Grants-in-Aid for Scientific Research [15K13688] Funding Source: KAKEN
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Recent progress in copper-catalyzed asymmetric allylic substitution reactions with organoboron nucleophiles is reviewed. Wide availability, high functional group compatibility, and mild reaction conditions are the main advantages over conventional highly reactive organometallic nucleophiles. The use of diboron and silylboron reagents for the synthesis of enantioenriched allylboronates and allylsilanes is also included.
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