Precise electro-reduction of alkyl halides for radical defluorinative alkylation

Photocatalytic Deoxygenative Carboimination towards Functionalized Pyrrolines by Using Unstrained γ , δ ‐Unsaturated Oximes

(2021) Min Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Photoredox/Hydrogen Atom Transfer Cocatalyzed C–H Difluoroallylation of Amides, Ethers, and Alkyl Aldehydes

(2021) Yuan-Qiang Guo et al.   ORGANIC LETTERS

Site-Selective Defluorinative sp3 C–H Alkylation of Secondary Amides

(2021) Wen-Jun Yue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chromium-Catalyzed Allylic Defluorinative Ketyl Olefin Coupling

(2021) Chang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Borylation of Alkyl Halides: Fast, Scalable Access to Alkyl Boronic Esters

(2021) Bingbing Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox Generation of N-Centered Hydrazonyl Radicals Enables the Construction of Dihydropyrazole-Fused gem-Difluoroalkenes

(2021) Qi-Sheng Gao et al.   ORGANIC LETTERS

C-F bond activation under transition-metal-free conditions

(2021) Han-Jun Ai et al.   Science China-Chemistry

Recent advances in organic electrosynthesis employing transition metal complexes as electrocatalysts

(2021) Cong Ma et al.   Science Bulletin

Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis

(2021) Christian A. Malapit et al.   CHEMICAL REVIEWS

Electroreductive Cross‐Coupling of Trifluoromethyl Alkenes and Redox Active Esters for the Synthesis of Gem ‐Difluoroalkenes

(2021) Aurélie Claraz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Decarboxylative/Defluorinative Alkylation for the Synthesis of gem ‐Difluoroalkenes through an S N 2 ’‐Type Route

(2021) Wei‐Long Xing et al.   CHINESE JOURNAL OF CHEMISTRY

Glycosyl-Radical-Based Synthesis of C-Alkyl Glycosides via Photomediated Defluorinative gem-Difluoroallylation

(2021) Cai-Yi Li et al.   ORGANIC LETTERS

Electrochemical C–N bond activation for deaminative reductive coupling of Katritzky salts

(2021) Yeqing Liu et al.   Nature Communications

Electrochemical synthesis of functionalized gem-difluoroalkenes with diverse alkyl sources via a defluorinative alkylation process

(2021) Haoxiang Zhang et al.   Organic Chemistry Frontiers

Site-Selective C–H Functionalization via Synergistic Use of Electrochemistry and Transition Metal Catalysis

(2020) Ke-Jin Jiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery

(2020) Juno C. Siu et al.   ACCOUNTS OF CHEMICAL RESEARCH

NiH-Catalyzed Migratory Defluorinative Olefin Cross-Coupling: Trifluoromethyl-Substituted Alkenes as Acceptor Olefins to Form gem -Difluoroalkenes

(2020) Fenglin Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyzing the Hydrodefluorination of CF3-Substituted Alkenes by PhSiH3. H• Transfer from a Nickel Hydride

(2020) Chengbo Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Nature of C(sp3)–C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides

(2020) Mingbin Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Terminal Monofluoroalkenes from Trifluoromethylated Alkenes

(2020) Pauline Poutrel et al.   ORGANIC LETTERS

General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis

(2020) Lei Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile and Economical Electrochemical Dehalogenative Deuteration of (Hetero)Aryl Halides

(2020) Lijun Lu et al.   CCS Chemistry

Synthesis of gem-Difluoroalkenes by Merging Ni-Catalyzed C–F and C–C Bond Activation in Cross-Electrophile Coupling

(2019) Decai Ding et al.   ORGANIC LETTERS

Open-Air Alkylation Reactions in Photoredox-Catalyzed DNA-Encoded Library Synthesis

(2019) James P. Phelan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Oxidative R1-H/R2-H Cross-Coupling with Hydrogen Evolution via Photo-/Electrochemistry

(2019) Huamin Wang et al.   CHEMICAL REVIEWS

Chemistry with Electrochemically Generated N-Centered Radicals

(2019) Peng Xiong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Reductive Allylic Defluorinative Cross-Coupling Enabled by Ni/Ti Cooperative Catalysis

(2019) Zhiyang Lin et al.   ORGANIC LETTERS

Visible-Light-Induced Selective Defluoroborylation of Polyfluoroarenes, gem -Difluoroalkenes, and Trifluoromethylalkenes

(2019) Wengang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu-Catalyzed tertiary alkylation of α-(trifluoromethyl)styrenes with tertiary alkylmagnesium reagents

(2018) Wenpeng Dai et al.   Organic Chemistry Frontiers

Synthesis of gem-Difluoroalkenes via Nickel-Catalyzed Allylic Defluorinative Reductive Cross-Coupling

(2018) Yun Lan et al.   ACS Catalysis

Fluoro-Hydroxylation of gem -Difluoroalkenes: Synthesis of 18 O-labeled α-CF3 Alcohols

(2018) Jingyu Hu et al.   CHINESE JOURNAL OF CHEMISTRY

Recent advances in the synthesis and CF functionalization of gem-difluoroalkenes

(2017) Xuxue Zhang et al.   TETRAHEDRON LETTERS

China's flourishing synthetic organofluorine chemistry: innovations in the new millennium

(2017) Qinghe Liu et al.   National Science Review

Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects

(2015) Mohammad Rafiee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Allylic C(sp3)–F Bond Activation of Trifluoromethyl Groups via β-Fluorine Elimination: Synthesis of Difluoro-1,4-dienes

(2015) Tomohiro Ichitsuka et al.   ACS Catalysis

Double CF Bond Activation through β-Fluorine Elimination: Nickel-Mediated [3+2] Cycloaddition of 2-Trifluoromethyl-1-alkenes with Alkynes

(2014) Tomohiro Ichitsuka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox catalysis in organic electrosynthesis: basic principles and recent developments

(2014) Robert Francke et al.   CHEMICAL SOCIETY REVIEWS

Recent Advances in the Synthetic Application of Difluorocarbene

(2014) Jinbo Hu et al.   SYNTHESIS-STUTTGART

NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes

(2011) Rosa Corberán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of α-trifluoromethylstyrene derivatives via Ni-catalyzed cross-coupling of 2-bromo-3,3,3-trifluoropropene and aryl Grignard reagents

(2009) Osamu Kobayashi et al.   JOURNAL OF FLUORINE CHEMISTRY