Double CF Bond Activation through β-Fluorine Elimination: Nickel-Mediated [3+2] Cycloaddition of 2-Trifluoromethyl-1-alkenes with Alkynes

Palladium-Catalyzed Coupling Reaction of Perfluoroarenes with Diarylzinc Compounds

(2014) Masato Ohashi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Domino Synthesis of Fluorine-Substituted Polycyclic Aromatic Hydrocarbons: 1,1-Difluoroallenes as Synthetic Platforms

(2013) Kohei Fuchibe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Hydrodefluorination of Fluoroarenes by Copper Hydride Intermediates

(2013) Hongbin Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-CatalyzedOrtho-Selective CF Activation of Polyfluoroarenes with Triethylsilane: A Facile Access to Partially Fluorinated Aromatics

(2013) Zhao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions

(2013) Moritz F. Kuehnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,2,3,4-Tetrasubstituted Cyclopentadienes and Their Applications for Metallocenes: Efficient Synthesis through Zirconocene- and CuCl-Mediated Intermolecular Coupling of Two Alkynes and One Diiodomethane

(2013) Weizhi Geng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt Fluorocarbenes: Cycloaddition Reactions with Tetrafluoroethylene and Reactivity of the Perfluorometallacyclic Products

(2013) Daniel J. Harrison et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–Fluorine Bond Activation of Tetrafluoroethylene on Palladium(0) and Nickel(0): Heat or Lewis Acidic Additive Promoted Oxidative Addition

(2013) Masato Ohashi et al.   ORGANOMETALLICS

Acid-Promoted Selective Carbon–Fluorine Bond Activation and Functionalization of Hexafluoropropene by Nickel Complexes Supported with Phosphine Ligands

(2013) Wengang Xu et al.   ORGANOMETALLICS

Zirconocene Dichloride Catalyzed Hydrodefluorination of C sp 2F bonds

(2012) Shuhui Yow et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Catalytic [6+3] Cycloadditions of Azomethine Ylides

(2012) Marco Potowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Palladium-Catalyzed C–F Activation/Carbon–Carbon Bond Formation of Polyfluoroaryl Oxazolines

(2012) Daohong Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

Low-Coordinate Cobalt Fluoride Complexes: Synthesis, Reactions, and Production from C–F Activation Reactions

(2012) Thomas R. Dugan et al.   ORGANOMETALLICS

Decisive Steps of the Hydrodefluorination of Fluoroaromatics using [Ni(NHC)2]

(2012) Peter Fischer et al.   ORGANOMETALLICS

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

(2011) Eric Clot et al.   ACCOUNTS OF CHEMICAL RESEARCH

[3+2] Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes Catalyzed by Nickel/Dimethylaluminum Chloride

(2011) Takashi Tamaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biphenyl-Based Diaminophosphine Oxides as Air-Stable Preligands for the Nickel-Catalyzed Kumada-Tamao-Corriu Coupling of Deactivated Aryl Chlorides, Fluorides, and Tosylates

(2011) Zhong Jin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Formation of Cyclopentenone Derivatives via the Unique Cycloaddition of α,β-Unsaturated Phenyl Esters with Alkynes

(2011) Masato Ohashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Steric Contours To Understand the Effects ofN-Heterocyclic Carbene Ligands on the Reversal of Regioselectivity in Ni-Catalyzed Reductive Couplings of Alkynes and Aldehydes

(2011) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Coupling Reactions of Tetrafluoroethylene with Arylzinc Compounds

(2011) Masato Ohashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Suzuki–Miyaura Reaction of Aryl Fluorides

(2011) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cyclization of Difluoro-Substituted 1,6-Enynes with Organozinc Reagents through the Stereoselective Activation of CF Bonds: Synthesis of Bicyclo[3.2.0]heptene Derivatives

(2010) Manabu Takachi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium-Catalyzed C-F Activation of Fluoroalkenes

(2010) Moritz F. Kühnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Imine-assisted C–F bond activation using low-valent cobalt compounds supported by trimethylphosphine ligands and formation of novel organic fluorides

(2010) Zhe Lian et al.   DALTON TRANSACTIONS

Palladium-Catalyzed C−F Activation of Polyfluoronitrobenzene Derivatives in Suzuki−Miyaura Coupling Reactions

(2010) Matthew R. Cargill et al.   JOURNAL OF ORGANIC CHEMISTRY

The Bridged Binding Mode as a New, Versatile Template for the Selective Activation of Carbon−Fluorine Bonds in Fluoroolefins: Activation of Trifluoroethylene

(2010) Michael E. Slaney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origins of Regioselectivity and Alkene-Directing Effects in Nickel-Catalyzed Reductive Couplings of Alkynes and Aldehydes

(2010) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed [2 + 2 + 2] Cycloaddition of Two Enones and an Alkyne

(2010) Sensuke Ogoshi et al.   ORGANIC LETTERS

Nickel-Catalyzed Hydrosilylation/Cyclization of Difluoro-Substituted 1,6-Enynes

(2010) Manabu Takachi et al.   ORGANIC LETTERS

Selective CF Bond Activation of Tetrafluorobenzenes by Nickel(0) with a Nitrogen Donor Analogous to N-Heterocyclic Carbenes

(2009) Meghan E. Doster et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Substitution of Allylic Fluorides

(2009) Amaruka Hazari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of Allylic CF bonds: Palladium-Catalyzed Allylic Amination of 3,3-Difluoropropenes

(2009) Xavier Pigeon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Nickel-Catalyzed [4 + 2] Cycloaddition of Enones with Alkynes

(2009) Ichiro Koyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes

(2009) Steven P. Reade et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis ofgem-Difluoroalkenes via β-Fluoride Elimination of Organorhodium(I)

(2008) Tomoya Miura et al.   CHEMISTRY LETTERS

Rhodium-Catalyzed Substitution Reaction of Aryl Fluorides with Disulfides:p-Orientation in the Polyarylthiolation of Polyfluorobenzenes

(2008) Mieko Arisawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations

(2008) Thomas Schaub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Cp*Ir(CO)2 with Activated Perfluoroaromatic Compounds: Formation of Metallocarboxylic Acids via Aromatic Nucleophilic Substitution

(2008) Pek Ke Chan et al.   ORGANOMETALLICS

Ortho-Selective Cross-Coupling of Fluorobenzenes with Grignard Reagents: Acceleration by Electron-DonatingOrtho-Directing Groups

(2008) Kei Manabe et al.   SYNTHESIS-STUTTGART