Glycosyl-Radical-Based Synthesis of C-Alkyl Glycosides via Photomediated Defluorinative gem-Difluoroallylation

Diastereoselective Synthesis of Aryl C‐Glycosides from Glycosyl Esters via C‐O Bond Homolysis

(2021) Yongliang Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Excited-State Palladium-Catalyzed 1,2-Spin-Center Shift Enables Selective C-2 Reduction, Deuteration, and Iodination of Carbohydrates

(2021) Gaoyuan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

β-Glycosyl Trifluoroborates as Precursors for Direct α-C-Glycosylation: Synthesis of 2-Deoxy-α-C-glycosides

(2021) Daiki Takeda et al.   ORGANIC LETTERS

Site-Selective Defluorinative sp3 C–H Alkylation of Secondary Amides

(2021) Wen-Jun Yue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,2-trans-Stereoselective Synthesis of C-Glycosides of 2-Deoxy-2-amino-sugars Involving Glycosyl Radicals

(2021) Wen-Ze Shi et al.   ORGANIC LETTERS

Diastereoselective Decarboxylative Alkynylation of Anomeric Carboxylic Acids Using Cu/Photoredox Dual Catalysis

(2021) Mingxiang Zhu et al.   ACS Catalysis

Synthesis of C-Mannosylated Glycopeptides Enabled by Ni-Catalyzed Photoreductive Cross-Coupling Reactions

(2021) Runyu Mao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Radical Migratory Coupling Enables C-2 Arylation of Carbohydrates

(2021) Gaoyuan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chromium-Catalyzed Allylic Defluorinative Ketyl Olefin Coupling

(2021) Chang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Light-Mediated Cross-Coupling of Anomeric Trifluoroborates

(2021) Eric M. Miller et al.   ORGANIC LETTERS

Visible-Light-Mediated C–I Difluoroallylation with an α-Aminoalkyl Radical as a Mediator

(2021) Fuyang Yue et al.   ORGANIC LETTERS

Facile access to C-glycosyl amino acids and peptides via Ni-catalyzed reductive hydroglycosylation of alkynes

(2021) Yan-Hua Liu et al.   Nature Communications

Photoredox-Catalyzed Stereoselective Synthesis of C-Nucleoside Analogues from Glycosyl Bromides and Heteroarenes

(2021) Liwen Xia et al.   ACS Catalysis

Photoredox‐Mediated Net‐Neutral Radical/Polar Crossover Reactions

(2020) Rebecca J. Wiles et al.   ISRAEL JOURNAL OF CHEMISTRY

Radical Clock Probes to Determine Carbohydrate Radical Stabilities

(2020) Yasemin Mai-Linde et al.   ORGANIC LETTERS

Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides

(2020) Timothée Constantin et al.   SCIENCE

Convergent Total Synthesis of Hikizimycin Enabled by Intermolecular Radical Addition to Aldehyde

(2020) Haruka Fujino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Induced Pd-Catalyzed Radical Strategy for Constructing C-Vinyl Glycosides

(2020) Ming Li et al.   ORGANIC LETTERS

Total Synthesis of Diospyrodin and Its Three Diastereomers

(2020) Takumi Fukuda et al.   ORGANIC LETTERS

A radical approach to make unnatural amino acids through converting C–S bonds in cysteine derivatives to C–C bonds

(2020) Dawen Niu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of Glycosyl Radicals from Glycosyl Sulfoxides and Its Use in the Synthesis of C‐linked Glycoconjugates

(2020) Weidong Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Emerging Organometallic Methods for the Synthesis of C‐Branched (Hetero)aryl, Alkenyl, and Alkyl Glycosides: C−H Functionalization and Dual Photoredox Approaches

(2020) Juba Ghouilem et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyanide-Free Synthesis of Glycosyl Carboxylic Acids and Application for the Synthesis of Scleropentaside A

(2020) Liang-Jing Zou et al.   ORGANIC LETTERS

Synthesis of non-classical heteroaryl C-glycosides via Minisci-type alkylation of N-heteroarenes with 4-glycosyl-dihydropyridines

(2020) Qingbing Wang et al.   Science China-Chemistry

Synthesis of CH2-Linked α(1,6)-Disaccharide Analogues by α-Selective Radical Coupling C-Glycosylation

(2019) Noriaki Kiya et al.   ORGANIC LETTERS

Visible-Light-Mediated, Chemo- and Stereoselective Radical Process for the Synthesis of C-Glycoamino Acids

(2019) Peng Ji et al.   ORGANIC LETTERS

Stereoselective Synthesis of C,C-Glycosides from exo-Glycals Enabled by Iron-Mediated Hydrogen Atom Transfer

(2019) Damien Tardieu et al.   ORGANIC LETTERS

From d- to l-Monosaccharide Derivatives via Photodecarboxylation–Alkylation

(2019) I. C. Steven Wan et al.   ORGANIC LETTERS

Versatile Glycosyl Sulfonates in β-Selective C-Glycosylation

(2019) Jesse Ling et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Non-Classical Arylated C-Saccharides through Nickel/Photoredox Dual Catalysis

(2018) Audrey Dumoulin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Reversed C -Acyl Glycosides through Ni/Photoredox Dual Catalysis

(2018) Shorouk O. Badir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent progress of C-glycosylation methods in the total synthesis of natural products and pharmaceuticals

(2018) Hongze Liao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Aryl C-Glycosides via Iron-Catalyzed Cross Coupling of Halosugars: Stereoselective Anomeric Arylation of Glycosyl Radicals

(2017) Laksmikanta Adak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Glycosyl Stille Cross-Coupling with Anomeric Nucleophiles – A General Solution to a Long-Standing Problem of Stereocontrolled Synthesis of C-Glycosides

(2017) Maciej Walczak et al.   SYNLETT

Synthesis of Functionalized gem-Difluoroalkenes via a Photocatalytic Decarboxylative/Defluorinative Reaction

(2016) Tiebo Xiao et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct assembly of multiply oxygenated carbon chains by decarbonylative radical–radical coupling reactions

(2016) Kengo Masuda et al.   Nature Chemistry

A Modular Approach to the Total Synthesis of Tunicamycins

(2015) Jiakun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Et3B-mediated two- and three-component coupling reactions via radical decarbonylation of α-alkoxyacyl tellurides: single-step construction of densely oxygenated carboskeletons

(2015) Masanori Nagatomo et al.   Chemical Science

Ni-Catalyzed Reductive Coupling of Alkyl Acids with Unactivated Tertiary Alkyl and Glycosyl Halides

(2014) Chenglong Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective Metal-Catalyzed Synthesis ofC-Aryl andC-Vinyl Glycosides

(2012) Lionel Nicolas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Photoflow Reactor for the Continuous Photoredox-Mediated Synthesis ofC-Glycoamino Acids andC-Glycolipids

(2012) R. Stephen Andrews et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Addition of Glycosyl Halides to Alkenes Mediated by Visible Light

(2010) R. Stephen Andrews et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sn-Free Ni-Catalyzed Reductive Coupling of Glycosyl Bromides with Activated Alkenes

(2009) Hegui Gong et al.   ORGANIC LETTERS

Diastereoselective Ni-Catalyzed Negishi Cross-Coupling Approach to Saturated, Fully OxygenatedC-Alkyl andC-Aryl Glycosides

(2008) Hegui Gong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY