Cooperativity in Transition Metal Tetrylene Complexes

Transition-metal Complexes with Triple Bonds to Si, Ge, Sn, and Pb and Relevant Complexes

(2021) Hisako Hashimoto et al.   CHEMISTRY LETTERS

Cycloaddition Chemistry of a Silylene‐Nickel Complex toward Organic π‐Systems: From Reversibility to C−H Activation

(2020) Terrance J. Hadlington et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal/Organosilicon Complexes: Structure, Reactivity, and Considerations for Catalysis

(2020) Matthew T. Whited et al.   COMMENTS ON INORGANIC CHEMISTRY

Element-Ligand Cooperativity with p-Block Elements

(2020) Lutz Greb et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Bimetallic, Silylene‐Mediated Multielectron Reductions of Carbon Dioxide and Ethylene

(2020) Matthew Whited et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural Snapshots of π‐arene Bonding in a Gold Germylene Cation

(2020) Sonia Bajo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactions of Manganese Silyl and Silylene Complexes with CO2 and C(NiPr)2: Synthesis of Mn(I) Formate and Amidinylsilyl Complexes

(2020) Jeffrey S. Price et al.   ORGANOMETALLICS

Frontiers in molecular p-block chemistry: From structure to reactivity

(2019) Rebecca L. Melen   SCIENCE

Versatile Tautomerization of EH2-Substituted Silylenes (E = N, P, As) in the Coordination Sphere of Nickel

(2019) Terrance J. Hadlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Stable N-Hetero-Rh-Metallacyclic Silylene

(2019) Tsuyoshi Kato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cleavage of Si–H, B–H, and C–H Bonds by Metal–Ligand Cooperation

(2019) Takuya Higashi et al.   CHEMICAL REVIEWS

[2+2] Cycloadduct of Titanium Silylidene and Benzonitrile

(2019) Vladimir Ya. Lee et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Heavy Tetrel Complexes of Ru Featuring Ru═E(R)X and Ru–E–R (E = Sn, Pb) Linkages

(2019) Patrick W. Smith et al.   ORGANOMETALLICS

Oxidative Addition and Reductive Elimination at Main-Group Element Centers

(2018) Terry Chu et al.   CHEMICAL REVIEWS

The Road Travelled: After Main-Group Elements as Transition Metals

(2018) Catherine Weetman et al.   ChemCatChem

Introduction: Carbene Chemistry

(2018) F. Ekkehardt Hahn   CHEMICAL REVIEWS

Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes

(2018) Jia Zhang et al.   ORGANOMETALLICS

Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins

(2017) Yuwen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination Chemistry of [E(Idipp)]2+ Ligands (E = Ge, Sn): Metal Germylidyne [Cp*(CO)2W≡Ge(Idipp)]+ and Metallotetrylene [Cp*(CO)3W–E(Idipp)]+ Cations

(2017) Yury N. Lebedev et al.   ORGANOMETALLICS

Theoretical Assessment of Low-Valent Germanium Compounds as Transition Metal Ligands: Can They Be Better than Phosphines or NHCs?

(2017) Zsolt Benedek et al.   ORGANOMETALLICS

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-Coupling

(2016) Mark D. Levin et al.   ACS Central Science

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Compounds with Low-Valent p-Block Elements for Small Molecule Activation and Catalysis

(2015) Sandeep Yadav et al.   ChemCatChem

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

(2015) Lucía Álvarez-Rodríguez et al.   COORDINATION CHEMISTRY REVIEWS

Insertion of a Cationic Metallogermylene into E–H Bonds (E = H, B, Si)

(2015) Koya Inomata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs?

(2015) Zsolt Benedek et al.   RSC Advances

1,2-Hydrogen Migration to a Saturated Ruthenium Complex via Reversal of Electronic Properties for Tin in a Stannylene-to-Metallostannylene Conversion

(2014) Hsueh-Ju Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding the Reactivity Difference of Isocyanate and Isothiocyanate toward a Ruthenium Silylene Hydride Complex

(2014) Hujun Xie et al.   ORGANOMETALLICS

Influence of Ligand Modifications on Structural and Spectroscopic Properties in Terphenyl Based Heavier Group 14 Carbene Homologues

(2014) Petra Wilfling et al.   ORGANOMETALLICS

Silicon-Oxygen Double Bonds: A Stable Silanone with a Trigonal-Planar Coordinated Silicon Center

(2013) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Toward a Silicon Version of Metathesis: From Schrock-Type Titanium Silylidenes to Silatitanacyclobutenes

(2013) Vladimir Ya. Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(η3-α-Silabenzyl)tungsten Complexes: An Isolable Intermediate for Interconversion between a Silylene Complex and a Silyl Complex through 1,2-Aryl Migration

(2013) Eiji Suzuki et al.   ORGANOMETALLICS

Synthesis, Structure, and Reactions of a (η3-α-silabenzyl)molybdenum Complex: A Synthetic Equivalent of a Coordinatively Unsaturated Silyl Complex

(2013) Takashi Komuro et al.   ORGANOMETALLICS

Coordination of non-stabilized germylenes, stannylenes, and plumbylenes to transition metals

(2013) Judith Baumgartner et al.   REVIEWS IN INORGANIC CHEMISTRY

Structural and mechanistic investigation of a cationic hydrogen-substituted ruthenium silylene catalyst for alkene hydrosilation

(2013) Meg E. Fasulo et al.   Chemical Science

Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2(GeRR′)]+

(2012) Meg E. Fasulo et al.   CHEMICAL COMMUNICATIONS

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

Hydrido(hydrosilylene)tungsten Complexes: Dynamic Behavior and Reactivity Toward Acetone

(2012) Takahito Watanabe et al.   Chemistry-An Asian Journal

Germyl- and Germylene-Bridged Complexes of Rh/Ir and Subsequent Chemistry of a Bridging Germylene Group

(2012) Md Hosnay Mobarok et al.   INORGANIC CHEMISTRY

Stoichiometric Reaction Chemistry of Cationic Ruthenium Silylene Complexes toward Polar and Nonpolar Organic Substrates

(2012) Meg E. Fasulo et al.   ORGANOMETALLICS

Reactions of a Neutral Silylene Ruthenium Complex with Heterocumulenes: C═O Hydrosilylation of Isocyanates vs C═S Bond Cleavage of Isothiocyanate

(2012) Mitsuyoshi Ochiai et al.   ORGANOMETALLICS

Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

(2011) Philip P. Power   ACCOUNTS OF CHEMICAL RESEARCH

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Reactions of a hydrido(hydrogermylene)tungsten complex with some heterocumulenes: hydrogermylation and thermal rearrangement

(2010) Hisako Hashimoto et al.   NEW JOURNAL OF CHEMISTRY

Reactions of Cationic PNP-Supported Iridium Silylene Complexes with Polar Organic Substrates

(2010) Elisa Calimano et al.   ORGANOMETALLICS

Facile 1,2-Migration of a Methyl Group on a {Dimethoxy(methyl)silyl}tungsten Complex: Formation of a Base-Stabilized (Dimethoxysilylene)(methyl) Complex†

(2010) Eiji Suzuki et al.   ORGANOMETALLICS

Metal Silylenes Generated by Double Silicon-Hydrogen Activation: Key Intermediates in the Rhodium-Catalyzed Hydrosilylation of Ketones

(2009) Nathanaëlle Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

(2009) Mitsuyoshi Ochiai et al.   DALTON TRANSACTIONS

A Hydrogen-Substituted Osmium Stannylene Complex: Isomerization to a Metallostannylene Complex via an Unusual α-Hydrogen Migration from Tin to Osmium

(2009) Paul G. Hayes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structure of PNP-Supported Iridium Silyl and Silylene Complexes: Catalytic Hydrosilation of Alkenes

(2009) Elisa Calimano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of DMAP-Stabilized Aryl(silylene) Complexes and (Arylsilyl)(DMAP) Complexes of Tungsten: Mechanistic Study on the Interconversion between These Complexes via 1,2-Aryl Migration

(2009) Eiji Suzuki et al.   ORGANOMETALLICS

Synthesis, Structure, and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene and Germylene Complexes

(2009) Paul G. Hayes et al.   ORGANOMETALLICS

Contribution of Electrochemistry to Organometallic Catalysis

(2008) Anny Jutand   CHEMICAL REVIEWS

Alkene Hydrosilation by a Cationic Hydrogen-Substituted Iridium Silylene Complex

(2008) Elisa Calimano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A DFT Study on the Mechanism of Hydrosilylation of Unsaturated Compounds with Neutral Hydrido(hydrosilylene)tungsten Complex

(2007) Xin-Hao Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY