Article
Materials Science, Multidisciplinary
He Zhou, Yi Long, Salvatore Miraglia, Florence Porcher, Hu Zhang
Summary: The Curie temperatures of La0.7Ce0.3Fe13-x-yMnxSiy compounds can be raised to near room temperature when fully hydrogenated. The La0.7Ce0.3Fe11.55-yMnySi1.45 hydrides exhibit a giant magnetic entropy change and excellent age stability, making them ideal candidates for room temperature magnetic refrigerants.
Article
Environmental Sciences
Mengjia Li, Fangyu Zhang, Shaojing Li, Xuexia Wang, Jun Liu, Bin Wang, Yibing Ma, Ningning Song
Summary: Increasing pH values can alleviate W(VI) toxicity on wheat, while the activities of H2PO4- and SO42- can also decrease toxicity. Competition from Cl- and NO3 - does not significantly influence W(VI) toxicity.
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
(2021)
Article
Chemistry, Multidisciplinary
Anthony P. Deziel, Sahil Gahlawat, Nilay Hazari, Kathrin H. Hopmann, Brandon Q. Mercado
Summary: This study compares the rates of CO2 insertion into various metal alkyl bonds and provides fundamental information for the development of new catalysts for CO2 utilization.
Article
Chemistry, Physical
Meswa Patel, Pratik M. Pataniya, Dattatray J. Late, C. K. Sumesh
Summary: In this study, Ag-WS2 nanocomposites were successfully synthesized for improved photodetection of visible light, leading to the fabrication of a photodiode with incredible photoswitching ability.
APPLIED SURFACE SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Patrick McCarthy, Dogyun Hwangbo, Shin Kajita, James W. Bradley
Summary: In this study, fuzzy nanostructures were grown on tungsten samples using a linear plasma device with different gas mixtures and under various temperature and ion fluence conditions. The morphology of the fuzzy structures on tungsten surfaces varied depending on the impurity species used, with different impurities leading to different fuzzy structures. The thickness of the fuzzy layer decreased with higher impurity atomic masses and concentrations.
JOURNAL OF NUCLEAR MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Yutaro Norikawa, Toshiyuki Nohira
Summary: This study successfully achieved electrodeposition of film-like Si, Ti, and W using proposed molten salt systems. It has potential applications in fabricating Si solar cell substrates, imparting Ti properties to various substrates, and producing W diverter materials for nuclear fusion. The results demonstrate the advantages of the proposed molten salt systems for electroplating Si, Ti, and W, and the potential applicability for other metals.
ACCOUNTS OF CHEMICAL RESEARCH
(2023)
Article
Chemistry, Physical
Wenjun Yang, Ivan Yu. Chernyshov, Manuela Weber, Evgeny A. Pidko, Georgy A. Filonenko
Summary: In this study, a Mn(I) pincer complex that promotes site-controlled transposition of olefins was reported. By suppressing the N-H functionality within the complex through alkylation, a wide range of allylarenes can be efficiently converted to higher-value 1-propenybenzenes with excellent stereoselectivities. The complex also retains the reactivity towards a single positional isomerization for long-chain alkenes.
Article
Chemistry, Multidisciplinary
Marti Garcon, Andreas Phanopoulos, Andrew J. P. White, Mark R. Crimmin
Summary: Reaction of a hexagonal planar palladium complex with H-2 leads to the formation of a new tetrahydride species and a magnesium hydride co-product. Similar complexes with analogues metals could be isolated and characterized through independent syntheses. Computational analysis suggests a square planar structure with marginal metal-metal interactions, and DFT calculations support a ligand-assisted oxidative addition mechanism for H-2 activation.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Energy & Fuels
Patrick Krane, Austin L. Nash, Davide Ziviani, James E. Braun, Amy M. Marconnet, Neera Jain
Summary: This paper presents the application of metal hydrides in energy storage, hydrogen storage, and air-conditioning systems. A nonlinear dynamic model and multivariate control strategy are proposed for a two-reactor system, allowing for cyclic use of hydrogen and achieving desired heat transfer rates even in the presence of varying fluid inlet temperatures.
Article
Metallurgy & Metallurgical Engineering
Gao Guan-jun, Li Xi-wu, Yan Li-zhen, Xiong Bai-qing, Li Zhi-hui, Zhang Yong-an, Wen Kai, Li Ya-nan
Summary: This study investigates the effects of dynamic cooling pre-aging treatment on an Al-Mg-Si alloy sheet. It is found that the treatment at low temperature region reduces the paint-bake hardening ability, while increasing the cooling pre-aging temperature improves the stability and hardening ability.
JOURNAL OF CENTRAL SOUTH UNIVERSITY
(2022)
Article
Engineering, Mechanical
Chengxin Du, Zhonghua Du, Kehong Wang, Wei Dai, Guangfa Gao, Zhengwang Zhu, Lizhi Xu, Xi Chen
Summary: This study investigates the effect of tungsten fiber diameter on the dynamic compression properties of WF/Zr-MG material. The experimental results show that cracks only propagate within the fibers and are unaffected by the fiber/matrix interfaces. On the other hand, the volume fraction of fiber and strain rate have a significant impact on the fracture mode of the material.
INTERNATIONAL JOURNAL OF IMPACT ENGINEERING
(2022)
Article
Engineering, Mechanical
Atef Hmida, Ahmed Hammami, Fakher Chaari, Mounir Ben Amar, Mohamed Haddar
Summary: This paper investigates the impact of misfire on the dynamic response of the crankshaft and proposes a misfire detection method based on the torsional vibration signal of crankshaft acceleration. Different misfire faults are modeled and vibration responses of the crankshaft are computed to highlight the effects of misfire defects on crankshaft vibration signals.
ENGINEERING FAILURE ANALYSIS
(2021)
Article
Chemistry, Physical
Mohammed Abdelhameed, Wipakorn Jevasuwan, Thiyagu Subramani, Junyi Chen, Naoki Fukata
Summary: Non-radiative energy transfer (NRET) from silicon quantum dots (SiQDs) terminated with ligands can enhance solar cell efficiency, with 1-octene (the shortest ligand length) showing the greatest enhancement of NRET and resulting in the highest solar cell efficiency among the three different ligands studied.
Article
Chemistry, Physical
Hui Xie, Tianxiao Liang, Tian Cui, Xiaolei Feng, Hao Song, Da Li, Fubo Tian, Simon A. T. Redfern, Chris J. Pickard, Defang Duan
Summary: K2SiH6 is a promising hydrogen storage material with high hydrogen density and appropriate dehydrogenation temperature. Other potential hydrogen storage materials have also been found, which require further investigation under high pressure.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Physics, Condensed Matter
Yu Liu, Ying Sun, Pengyue Gao
Summary: This study focused on exploring the crystal structure and superconductivity in ternary N-Si-H system under high pressure. The findings showed that a metastable phase NSiH11 has the potential to be a superconductor with a Tc of 98-110 K at 300 GPa, attributed to the H-H interaction among H2 units.
SOLID STATE COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Tetsuya Fukuda, Hisako Hashimoto, Shigeyoshi Sakaki, Hiromi Tobita
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2016)
Article
Chemistry, Inorganic & Nuclear
Taeko Kakizawa, Hisako Hashimoto, Hiromi Tobita
INORGANICA CHIMICA ACTA
(2015)
Article
Chemistry, Multidisciplinary
Hisako Hashimoto, Yuto Odagiri, Yasuhiro Yamada, Nozomi Takagi, Shigeyoshi Sakaki, Hiromi Tobita
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2015)
Article
Chemistry, Multidisciplinary
Tetsuya Fukuda, Hisako Hashimoto, Hiromi Tobita
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2015)
Article
Chemistry, Multidisciplinary
Mieko Arisawa, Tomoki Yamada, Saori Tanii, Yuta Kawada, Hisako Hashimoto, Masahiko Yamaguchi
CHEMICAL COMMUNICATIONS
(2016)
Article
Chemistry, Inorganic & Nuclear
Tetsuya Fukuda, Takashi Yoshimoto, Hisako Hashimoto, Hiromi Tobita
Article
Chemistry, Inorganic & Nuclear
Takashi Yoshimoto, Hisako Hashimoto, Naoki Hayakawa, Tsukasa Matsuo, Hiromi Tobita
Article
Chemistry, Inorganic & Nuclear
Tetsuya Fukuda, Hisako Hashimoto, Hiromi Tobita
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2017)
Review
Chemistry, Inorganic & Nuclear
Hisako Hashimoto, Hiromi Tobita
COORDINATION CHEMISTRY REVIEWS
(2018)
Article
Chemistry, Multidisciplinary
Tetsuya Fukuda, Hisako Hashimoto, Hiromi Tobita
CHEMICAL COMMUNICATIONS
(2013)
Article
Chemistry, Multidisciplinary
Tetsuya Fukuda, Hisako Hashimoto, Hiromi Tobita
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2014)
Article
Chemistry, Multidisciplinary
Takashi Yoshimoto, Hisako Hashimoto, Nozomi Takagi, Shigeyoshi Sakaki, Naoki Hayakawa, Tsukasa Matsuo, Hiromi Tobita
CHEMISTRY-A EUROPEAN JOURNAL
(2019)
Article
Chemistry, Multidisciplinary
Takashi Yoshimoto, Hisako Hashimoto, Mausumi Ray, Naoki Hayakawa, Tsukasa Matsuo, Jaydeb Chakrabarti, Hiromi Tobita
Article
Chemistry, Inorganic & Nuclear
Hisako Hashimoto, Katsuto Komura, Takatoshi Ishizaki, Yuto Odagiri, Hiromi Tobita
DALTON TRANSACTIONS
(2017)
Article
Chemistry, Inorganic & Nuclear
Tara Prasad Dhungana, Hisako Hashimoto, Hiromi Tobita
DALTON TRANSACTIONS
(2017)