Metal/Organosilicon Complexes: Structure, Reactivity, and Considerations for Catalysis

Computational and Experimental Investigation of Alkene Hydrogenation by a Pincer-Type [P2Si]Rh Complex: Alkane Release via Competitive σ-Bond Metathesis and Reductive Elimination

(2019) Matthew T. Whited et al.   ORGANOMETALLICS

Non-classical hydrosilane mediated reductions promoted by transition metal complexes

(2019) Manuel Iglesias et al.   COORDINATION CHEMISTRY REVIEWS

Square-Planar Iron(II) Silyl Complexes: Synthesis, Characterization, and Insertion Reactivity

(2019) C. Vance Thompson et al.   ORGANOMETALLICS

[2+2] Cycloadduct of Titanium Silylidene and Benzonitrile

(2019) Vladimir Ya. Lee et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Silylpalladium Cations Enable the Oxidative Addition of C(sp3)–O Bonds

(2019) Andreas L. Wierschen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative CO2 Scission by Anomalous Insertion into a Rh–Si Bond

(2019) Matthew T. Whited et al.   ORGANOMETALLICS

Isolation of a Cationic Platinum(II) σ-Silane Complex

(2018) Pablo Ríos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in the chemistry of transition metal–silicon/germanium triple-bonded complexes

(2018) Hisako Hashimoto et al.   COORDINATION CHEMISTRY REVIEWS

Activation of Carbon–Hydrogen Bonds via 1,2-RH-Addition/-Elimination to Early Transition Metal Imides

(2018) Peter T. Wolczanski   ORGANOMETALLICS

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

(2018) Jennifer V. Obligacion et al.   Nature Reviews Chemistry

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(2018)   JOURNAL OF COMPUTATIONAL CHEMISTRY

Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes

(2018) Jia Zhang et al.   ORGANOMETALLICS

Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins

(2017) Yuwen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh and Ir β-Diiminate Complexes of Boranes, Silanes, Germanes, and Stannanes

(2017) Nan Zhang et al.   ORGANOMETALLICS

The unusual hydridicity of a cobalt bound Si–H moiety

(2016) Jin Kim et al.   CHEMICAL COMMUNICATIONS

Reactions of Hydrosilanes with Transition Metal Complexes

(2016) Joyce Y. Corey   CHEMICAL REVIEWS

Examining the role of Rh/Si cooperation in alkene hydrogenation by a pincer-type [P2Si]Rh complex

(2016) Matthew T. Whited et al.   DALTON TRANSACTIONS

Synthesis and characterization of five-coordinate, 16-electron RuII complexes supported by tridentate bis(phosphino)silyl ligation

(2016) Morgan C. MacInnis et al.   DALTON TRANSACTIONS

Significant Cooperativity Between Ruthenium and Silicon in Catalytic Transformations of an Isocyanide

(2016) Mark C. Lipke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of a Tungsten–Silylyne Complex via Stepwise Proton and Hydride Abstraction from a Hydrido Hydrosilylene Complex

(2016) Tetsuya Fukuda et al.   ORGANOMETALLICS

Dinitrogen-Facilitated Reversible Formation of a Si–H Bond in a Pincer-Supported Ni Complex

(2016) David J. Charboneau et al.   ORGANOMETALLICS

A Ni0(η2-(Si–H))(η2-H2) Complex That Mediates Facile H Atom Exchange between Two σ-Ligands

(2016) Bridget A. Connor et al.   ORGANOMETALLICS

Unknown

(2016)   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unknown

(2016)   CHEMISTRY-A EUROPEAN JOURNAL

Stabilization of a Silaaldehyde by its η2 Coordination to Tungsten

(2015) Tetsuya Fukuda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elusive Silane-Alane Complex [SiH⋅⋅⋅Al]: Isolation, Characterization, and Multifaceted Frustrated Lewis Pair Type Catalysis

(2015) Jiawei Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of an [(NHC)2Pd(SiMe3)2] Complex and Catalyticcis-Bis(silyl)ations of Alkynes with Unactivated Disilanes

(2015) Melvyn B. Ansell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

(2015) Lucía Álvarez-Rodríguez et al.   COORDINATION CHEMISTRY REVIEWS

Isolation of a Hydrogen-Bridged Bis(silylene) Tungsten Complex: A Snapshot of a Transition State for 1,3-Hydrogen Migration

(2015) Hisako Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assessment of the Electronic Factors Determining the Thermodynamics of “Oxidative Addition” of C–H and N–H Bonds to Ir(I) Complexes

(2015) David Y. Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unexpected Formation of NHC-Stabilized Hydrosilylyne Complexes via Alkane Elimination from NHC-Stabilized Hydrido(alkylsilylene) Complexes

(2015) Tetsuya Fukuda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Ruthenium Complexes with a Nonspectator Si,O,P-Chelate Ligand: Interconversion between a Hydrido(η2-silane) Complex and a Silyl Complex Leading to Catalytic Alkene Hydrogenation

(2015) Takashi Komuro et al.   ORGANOMETALLICS

Preparation, Characterization, and Catalytic Reactions of NCN Pincer Iron Complexes Containing Stannyl, Silyl, Methyl, and Phenyl Ligands

(2015) Jun-ichi Ito et al.   ORGANOMETALLICS

Silyl–Silylene Interplay in Cationic PSiP Pincer Complexes of Platinum

(2015) Jessica C. DeMott et al.   ORGANOMETALLICS

Silyl Ligand Mediated Reversible β-Hydrogen Elimination and Hydrometalation at Palladium

(2014) Jun Takaya et al.   CHEMISTRY-A EUROPEAN JOURNAL

Interconversion of η3-H2SiRR′ σ-Complexes and 16-Electron Silylene Complexes via Reversible H–H or C–H Elimination

(2014) Mark C. Lipke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclometalated N-Heterocyclic Carbene Complexes of Ruthenium for Access to Electron-Rich Silylene Complexes That Bind the Lewis Acids CuOTf and AgOTf

(2014) Hsueh-Ju Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex

(2014) Toni T. Metsänen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hypercoordinate Ketone Adducts of Electrophilic η3-H2SiRR′ Ligands on Ruthenium as Key Intermediates for Efficient and Robust Catalytic Hydrosilation

(2014) Mark C. Lipke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

(2014) Adrian Y. Houghton et al.   Nature Chemistry

Formation of Chlorosilyl Pincer-Type Rhodium Complexes by Multiple Si–H Activations of Bis(phosphine)/Dihydrosilyl Ligands

(2014) Matthew T. Whited et al.   ORGANOMETALLICS

Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State

(2014) Toni T. Metsänen et al.   ORGANOMETALLICS

A mechanistic study of allene carboxylation with CO2resulting in the development of a Pd(ii) pincer complex for the catalytic hydroboration of CO2

(2014) Hee-Won Suh et al.   Chemical Science

A Unifying Bonding Concept for Metal Hydrosilane Complexes

(2013) Wolfgang Scherer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A d10Ni-(H2) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond

(2013) W. Hill Harman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Alternative Mechanistic Paradigm for the β-ZHydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle

(2013) Manuel Iglesias et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reversible Insertion of Carbenes into Ruthenium–Silicon Bonds

(2013) María J. Bernal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward a Silicon Version of Metathesis: From Schrock-Type Titanium Silylidenes to Silatitanacyclobutenes

(2013) Vladimir Ya. Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

(2013) Daniel Gallego et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Base Mediated β-Elimination and Lewis Acid Mediated Insertion Reactions of Disilazido Zirconium Compounds

(2013) KaKing Yan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Dehydrogenative Borylation of Terminal Alkynes by a SiNN Pincer Complex of Iridium

(2013) Chun-I Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silane–Isocyanide Coupling Involving 1,1-Insertion of XylNC into the Si–H Bond of a σ-Silane Ligand

(2013) Mark C. Lipke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Desulfurization and H-Migration of Secondary Thioamides Catalyzed by an Iron Complex to Yield Imines and Their Reaction Mechanism

(2013) Kozo Fukumoto et al.   ORGANOMETALLICS

Effective Fixation of CO2by Iridium-Catalyzed Hydrosilylation

(2012) Ralte Lalrempuia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds

(2012) Jennifer C. Green et al.   CHEMICAL COMMUNICATIONS

Analysis of Potential Molecular Catalysts for the Hydroamination of Ethylene with Ammonia: A DFT Study with [Ir(PCP)] and [Ir(PSiP)] Complexes

(2012) Andreas Uhe et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules

(2012) Burgert Blom et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

(2012) W. Hill Harman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Density Functional Theory Study of N–CN and O–CN Bond Cleavage by an Iron Silyl Complex

(2012) AbdelRahman A. Dahy et al.   ORGANOMETALLICS

Experimental and Computational Studies of the Reaction of Carbon Dioxide with Pincer-Supported Nickel and Palladium Hydrides

(2012) Hee-Won Suh et al.   ORGANOMETALLICS

Reactions of a Neutral Silylene Ruthenium Complex with Heterocumulenes: C═O Hydrosilylation of Isocyanates vs C═S Bond Cleavage of Isothiocyanate

(2012) Mitsuyoshi Ochiai et al.   ORGANOMETALLICS

Redistribution of Trialkyl Silanes Catalyzed by Iridium Silyl Complexes

(2012) Sehoon Park et al.   ACS Catalysis

The Nature of β-Agostic Bonding in Late-Transition-Metal Alkyl Complexes

(2011) Wolfgang Scherer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

(2011) Joyce Y. Corey   CHEMICAL REVIEWS

Reaction of bis(o-phosphinophenyl)silane with M(PPh3)4 (M = Ni, Pd, Pt): synthesis and structural analysis of η2-(Si–H) metal(0) and pentacoordinate silyl metal(ii) hydride complexes of the Ni triad bearing a PSiP-pincer ligand

(2011) Jun Takaya et al.   DALTON TRANSACTIONS

Four-Coordinate, 14-Electron RuIIComplexes: Unusual Trigonal Pyramidal Geometry Enforced by Bis(phosphino)silyl Ligation

(2011) Morgan C. MacInnis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High Electrophilicity at Silicon in η3-Silane σ-Complexes: Lewis Base Adducts of a Silane Ligand, Featuring Octahedral Silicon and Three Ru–H–Si Interactions

(2011) Mark C. Lipke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of CO2by a Heterobimetallic Zr/Co Complex

(2011) Jeremy P. Krogman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Reduction of CO2with pinB-SiMe2Ph via CO2Insertion into a Copper–Silicon Bond

(2011) Christian Kleeberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DFT Study on the Mechanism of the Activation and Cleavage of CO2by (NHC)CuEPh3(E = Si, Ge, Sn)

(2011) Alireza Ariafard et al.   ORGANOMETALLICS

Electron-Precise Coordination Modes of Boron-Centered Ligands

(2010) Holger Braunschweig et al.   CHEMICAL REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Synthesis and characterisation of hydrido molybdenum and tungsten complexes having a hemilabile tridentate Si,Si,O-ligand: observation of stepwise hydrosilylation of a nitrile to form an N-silylimine on the metal centre

(2010) Takashi Komuro et al.   DALTON TRANSACTIONS

Addition of Water Across Si−Ir Bonds in Iridium Complexes with κ-P,P,Si(biPSi) Pincer Ligands

(2010) Alba García-Camprubí et al.   INORGANIC CHEMISTRY

Iridium Compounds with κ-P,P,Si(biPSi) Pincer Ligands: Favoring Reactive Structures in Unsaturated Complexes

(2010) Eduardo Sola et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-quinolyl): an unusual δ-agostic iron complex containing an η1-SiH interaction

(2010) Jian Yang et al.   NEW JOURNAL OF CHEMISTRY

Hydrosilylation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η1-Silane Iridium(III) Complex

(2010) Sehoon Park et al.   ORGANOMETALLICS

Reactions of Cationic PNP-Supported Iridium Silylene Complexes with Polar Organic Substrates

(2010) Elisa Calimano et al.   ORGANOMETALLICS

Late Metal Carbene Complexes Generated by Multiple C−H Activations: Examining the Continuum of M═C Bond Reactivity

(2009) Matthew T. Whited et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel and Palladium Silyl Pincer Complexes: Unusual Structural Rearrangements that Involve Reversible SiC(sp3) and SiC(sp2) Bond Activation

(2009) Samuel J. Mitton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

(2009) Mitsuyoshi Ochiai et al.   DALTON TRANSACTIONS

Nature of the Bonding in Metal-Silane σ-Complexes

(2009) G. Sean McGrady et al.   INORGANIC CHEMISTRY

Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands

(2009) Matthew T. Whited et al.   INORGANIC CHEMISTRY

High Oxidation State Rhodium and Iridium Bis(silyl)dihydride Complexes Supported by a Chelating Pyridyl-Pyrrolide Ligand

(2009) Jennifer L. McBee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium and Iridium Amido Complexes Supported by Silyl Pincer Ligation: Ammonia N−H Bond Activation by a [PSiP]Ir Complex

(2009) Erin Morgan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structure of PNP-Supported Iridium Silyl and Silylene Complexes: Catalytic Hydrosilation of Alkenes

(2009) Elisa Calimano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(o-phosphinophenyl)silane as a Scaffold for Dynamic Behavior of H−Si and C−Si Bonds with Palladium(0)

(2009) Jun Takaya et al.   ORGANOMETALLICS

Structural and Spectroscopic Characterization of an Unprecedented Cationic Transition-Metal η1-Silane Complex

(2008) Jian Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silanol-Based Pincer Pt(II) Complexes: Synthesis, Structure, and Unusual Reactivity

(2008) Edward E. Korshin et al.   INORGANIC CHEMISTRY

Alkene Hydrosilation by a Cationic Hydrogen-Substituted Iridium Silylene Complex

(2008) Elisa Calimano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism of the Iridium-Catalyzed Cleavage of Alkyl Ethers with Triethylsilane

(2008) Jian Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrocarboxylation of Allenes with CO2Catalyzed by Silyl Pincer-Type Palladium Complex

(2008) Jun Takaya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N−CN Bond Cleavage of Cyanamides by a Transition-Metal Complex

(2008) Kozo Fukumoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of Iridium(III) Dihydrido Aminocarbenes

(2008) Matthew T. Whited et al.   ORGANOMETALLICS