Journal
ORGANOMETALLICS
Volume 38, Issue 21, Pages 4060-4065Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.9b00550
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Funding
- National Science Foundation [CHE-1566538]
- National Institutes of Health [S10-RR027172]
- NSERC of Canada
- NIH [S10OD024998]
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The hydridoruthenate [(solv)Na][Cp*((Pr2MeP)-Pr-i)RuH2] (1; solv = THF or Et2O) provided access to the Ru metallostannylene Cp*((Pr2MeP)-Pr-i)(H)(2)RuSnDMP (DMP = 2,6-dimesitylphenyl) (2) and metalloplumbylene Cp*((Pr2MeP)-Pr-i)(H)(2)RuPbArTrip2 (Ar-Trip2 = 2,6-bis (2,4,6-triisopropylphenyl)phenyl) (3) compounds by salt metathesis reactions with the corresponding [ArEX](2) precursors. The Sn complex 2 reacted nucleophilically with MeI to cleanly generate the addition product Cp*((Pr2MeP)-Pr-i)(H)(2)RuSnI(Me)DMP (4), while a complex mixture was observed for Pb complex 3. A Ru monohydride synthon generated from 1 also provided access to the chlorostannylene and bromoplumbylene complexes Cp*((Pr2MeP)-Pr-i)(H)Ru[SnCl(DMP)] (5) and Cp*((Pr2MeP)-Pr-i)(H)Ru[PbBr(Ar-Trip2)] (6), respectively.
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