Redox-active ligands in catalysis

Azo NN Bond Cleavage with a Redox-Active Vanadium Compound Involving Metal-Ligand Cooperativity

(2012) Carsten Milsmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative & Redox Non-Innocent Ligands in Directing Organometallic Reactivity (Eur. J. Inorg. Chem. 3/2012)

(2012) Karen Hindson et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The Shrinking World of Innocent Ligands: Conventionaland Non-Conventional Redox-Active Ligands

(2012) Wolfgang Kaim   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Non-Heme Iron(III) Complex with Porphyrin-like Properties That Catalyzes Asymmetric Epoxidation

(2012) Takashi Niwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational and Experimental Study of the Mechanism of Hydrogen Generation from Water by a Molecular Molybdenum-Oxo Electrocatalyst

(2012) Eric J. Sundstrom et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Ru(I) Metalloradical That Catalyzes Nitrene Coupling to Azoarenes from Arylazides

(2012) Ayumi Takaoka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploring the Fuel Limits of Direct Oxidation Proton Exchange Membrane Fuel Cells with Platinum Based Electrocatalysts

(2012) Jack R. Ferrell et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II

(2012) Lele Duan et al.   Nature Chemistry

Closed-shell and open-shell square-planar iridium nitrido complexes

(2012) Markus G. Scheibel et al.   Nature Chemistry

A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

(2012) Oana R. Luca et al.   NEW JOURNAL OF CHEMISTRY

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Splitting Water with Cobalt

(2011) Vincent Artero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligands that Store and Release Electrons during Catalysis

(2011) Wojciech I. Dzik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The radical mechanism of cobalt(ii) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding

(2011) Alma I. Olivos Suarez et al.   DALTON TRANSACTIONS

A Redox-Active Ligand as a Reservoir for Protons and Electrons: O2 Reduction at Zirconium(IV)

(2011) Feng Lu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Electronic Effects of Ligands on the Cobalt(II)-Porphyrin-Catalyzed Direct C-H Arylation of Benzene

(2011) Tek Long Chan et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Aerobic Alcohol Oxidations Catalyzed by Oxorhenium Complexes Containing Redox-Active Ligands

(2011) Cameron A. Lippert et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Radical Chemistry of Iminepyridine Ligands

(2011) Peter H. M. Budzelaar   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Non-Innocent Ligands: New Opportunities in Iron Catalysis

(2011) Sébastien Blanchard et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ligand Redox Non-Innocence in Transition-Metal σ-Alkynyl and Related Complexes

(2011) Phil A. Schauer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Harnessing Redox-Active Ligands for Low-Barrier Radical Addition at Oxorhenium Complexes

(2011) Cameron A. Lippert et al.   INORGANIC CHEMISTRY

Designing Catalysts for Nitrene Transfer Using Early Transition Metals and Redox-Active Ligands

(2011) Alan F. Heyduk et al.   INORGANIC CHEMISTRY

Redox Noninnocence of Carbene Ligands: Carbene Radicals in (Catalytic) C−C Bond Formation

(2011) Wojciech I. Dzik et al.   INORGANIC CHEMISTRY

Preface: Forum on Redox-Active Ligands

(2011) Paul J. Chirik   INORGANIC CHEMISTRY

Noninnocence in Metal Complexes: A Dithiolene Dawn

(2011) Richard Eisenberg et al.   INORGANIC CHEMISTRY

Palladium(II) complexes of imidazolin-2-ylidene N-heterocyclic carbene ligands with redox-active dimethoxyphenyl or (hydro)quinonyl substituents

(2011) Louise A. Berben et al.   INORGANICA CHIMICA ACTA

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox Control of a Ring-Opening Polymerization Catalyst

(2011) Erin M. Broderick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of Three-Coordinate Ni(III)-Imide Complexes

(2011) Vlad M. Iluc et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Intermolecular [2π + 2π] Cycloaddition

(2011) Sarah K. Russell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid Water Reduction to H2Catalyzed by a Cobalt Bis(iminopyridine) Complex

(2011) Bryan D. Stubbert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cobalt–Dithiolene Complex for the Photocatalytic and Electrocatalytic Reduction of Protons

(2011) William R. McNamara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C−H Bond Amination from High-Spin Iron Imido Complexes

(2011) Evan R. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DDQ as an electrocatalyst for amine dehydrogenation, a model system for virtual hydrogen storage

(2011) Oana R. Luca et al.   NEW JOURNAL OF CHEMISTRY

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

Cp* Iridium Precatalysts for Selective C–H Oxidation via Direct Oxygen Insertion: A Joint Experimental/Computational Study

(2011) Meng Zhou et al.   ACS Catalysis

Non-innocent ligands in bioinorganic chemistry—An overview

(2010) Wolfgang Kaim et al.   COORDINATION CHEMISTRY REVIEWS

Photolysis and Thermolysis of Bis(imino)pyridine Cobalt Azides: C−H Activation from Putative Cobalt Nitrido Complexes

(2010) Crisita Carmen Hojilla Atienza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic N−N Coupling of Aryl Azides To Yield Azoarenes via Trigonal Bipyramid Iron−Nitrene Intermediates

(2010) Neal P. Mankad et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Active Ligands Facilitate Bimetallic O2Homolysis at Five-Coordinate Oxorhenium(V) Centers

(2010) Cameron A. Lippert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arrested Catalysis: Controlling Kumada Coupling Activity via a Redox-Active N-Heterocyclic Carbene

(2010) Andrew G. Tennyson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation

(2010) Wojciech I. Dzik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Active Ligand-Mediated Oxidative Addition and Reductive Elimination at Square Planar Cobalt(III): Multielectron Reactions for Cross-Coupling

(2010) Aubrey L. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions

(2010) Ekambaram Balaraman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A molecular molybdenum-oxo catalyst for generating hydrogen from water

(2010) Hemamala I. Karunadasa et al.   NATURE

Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron

(2010) Yunho Lee et al.   Nature Chemistry

Multifunctional ligands in transition metal catalysis

(2010) Robert H. Crabtree   NEW JOURNAL OF CHEMISTRY

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

C–H arylation of unactivated arenes with aryl halides catalyzed by cobalt porphyrin

(2010) Ching Tat To et al.   TETRAHEDRON LETTERS

Catalytic nitrene transfer by a zirconium(iv) redox-active ligand complex

(2010) Andy I. Nguyen et al.   Chemical Science

Making Oxygen with Ruthenium Complexes

(2009) Javier J. Concepcion et al.   ACCOUNTS OF CHEMICAL RESEARCH

Development of Molecular Electrocatalysts for CO2Reduction and H2Production/Oxidation

(2009) M. Rakowski Dubois et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3)

(2009) Velusamy Subbarayan et al.   CHEMICAL COMMUNICATIONS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

Hydrogen-Atom Transfer in Reactions of Organic Radicals with [CoII(por)].(por=Porphyrinato) and in Subsequent Addition of [Co(H)(por)] to Olefins

(2009) Bas de Bruin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis

(2009) Julie L. Boyer et al.   COORDINATION CHEMISTRY REVIEWS

Characterization of Intermediary Redox States of the Water Oxidation Catalyst, [Ru(bpy)2(OH2)]2O4+

(2009) Jonathan L. Cape et al.   INORGANIC CHEMISTRY

Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands

(2009) Matthew T. Whited et al.   INORGANIC CHEMISTRY

Iron-Catalyzed, Hydrogen-Mediated Reductive Cyclization of 1,6-Enynes and Diynes: Evidence for Bis(imino)pyridine Ligand Participation

(2009) Kevin T. Sylvester et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of a Redox-Active Ligand Complex of Nickel with Dioxygen Probes Ligand-Radical Character

(2009) Tony D. Manuel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Active N-Heterocyclic Carbenes: Design, Synthesis, and Evaluation of Their Electronic Properties

(2009) Evelyn L. Rosen et al.   ORGANOMETALLICS

Rethinking Water Splitting

(2009) Richard Eisenberg   SCIENCE

Consecutive Thermal H2and Light-Induced O2Evolution from Water Promoted by a Metal Complex

(2009) Stephan W. Kohl et al.   SCIENCE

Four-Electron Oxidative Formation of Aryl Diazenes Using a Tantalum Redox-Active Ligand Complex

(2008) Ryan A. Zarkesh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach

(2008) Julio Piera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective CC Coupling of Ir-Ethene and Ir-Carbenoid Radicals

(2008) Wojciech I. Dzik et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen storage in liquid organic heterocycles

(2008) Robert H. Crabtree   Energy & Environmental Science

Reactions of Tetrabromocatecholatomanganese(III) Complexes with Dioxygen

(2008) Clarence J. Rolle et al.   INORGANIC CHEMISTRY

Mechanisms of Water Oxidation Catalyzed by Ruthenium Diimine Complexes

(2008) James K. Hurst et al.   INORGANIC CHEMISTRY

Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II

(2008) Feng Liu et al.   INORGANIC CHEMISTRY

Water Oxidation by a Ruthenium Complex with Noninnocent Quinone Ligands: Possible Formation of an O−O Bond at a Low Oxidation State of the Metal

(2008) James T. Muckerman et al.   INORGANIC CHEMISTRY

Manganese Catalysts with Molecular Recognition Functionality for Selective Alkene Epoxidation

(2008) Jonathan F. Hull et al.   INORGANIC CHEMISTRY

Cobalt-Catalyzed Asymmetric Olefin Aziridination with Diphenylphosphoryl Azide

(2008) Jess E. Jones et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Reactivity of a Zirconium(IV) Redox-Active Ligand Complex with 1,2-Diphenylhydrazine

(2008) Karen J. Blackmore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Effective Cobalt Catalyst for Olefin Aziridination with Azides: Hydrogen Bonding Guided Catalyst Design

(2008) Joshua V. Ruppel et al.   ORGANIC LETTERS

Functional Group Tolerance and Substrate Scope in Bis(imino)pyridine Iron Catalyzed Alkene Hydrogenation

(2008) Ryan J. Trovitch et al.   ORGANOMETALLICS

Molecular recognition in homogeneous transition metal catalysis: a biomimetic strategy for high selectivity

(2007) Siddartha Das et al.   CHEMICAL COMMUNICATIONS

Functional models for the oxygen-evolving complex of photosystem II

(2007) C CADY et al.   COORDINATION CHEMISTRY REVIEWS

Redox-Switched Oxidation of Dihydrogen Using a Non-Innocent Ligand

(2007) Mark R. Ringenberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY