Rhodium(I)‐Catalyzed C2‐Selective Decarbonylative C−H Alkylation of Indoles with Alkyl Carboxylic Acids and Anhydrides

Bidentate Directing Groups: An Efficient Tool in C–H Bond Functionalization Chemistry for the Expedient Construction of C–C Bonds

(2020) Supriya Rej et al.   CHEMICAL REVIEWS

Modular Synthesis of Carbon-Substituted Furoxans via Radical Addition Pathway. Useful Tool for Transformation of Aliphatic Carboxylic Acids Based on “Build-and-Scrap” Strategy

(2020) Ryosuke Matsubara et al.   ORGANIC LETTERS

Cobalt-Catalyzed Direct C(sp2)-H Alkylation with Unactivated Alkenes

(2020) Ye Lim Kim et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Enantioselective Hydroarylation of 1,6-Enynes

(2020) Andrew Whyte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides

(2020) Haoqiang Zhao et al.   ORGANIC LETTERS

MnBr2-Catalyzed Direct and Site-Selective Alkylation of Indoles and Benzo[h]quinoline

(2020) Rahul A. Jagtap et al.   ORGANIC LETTERS

Silver-Catalyzed C–H Aryloxydifluoromethylation and Arylthiodifluoromethylation of Heteroarenes

(2020) Xiao-Lei Zhu et al.   ORGANIC LETTERS

Recent Advances in Minisci-Type Reactions

(2019) Rupert S. J. Proctor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative Coupling Reaction of 2‐(1 H ‐Indol‐3‐yl)acetic Acids with Indole, Azaindole, Benzimidazole and Indazole Derivatives

(2019) Thanigaimalai Pillaiyar et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible-Light Photoredox-Catalyzed Decarboxylative Alkylation of Heteroarenes Using Carboxylic Acids with Hydrogen Release

(2019) Wan-Fa Tian et al.   ORGANIC LETTERS

Stereoselective C(sp2)–H Alkylation of Enamides with Unactivated Aliphatic Carboxylic Acids via Decarboxylative Cross-Coupling Reactions

(2019) Jing-Yu Guo et al.   ORGANIC LETTERS

C−H Functionalization of Indoles by 3d Transition‐Metal Catalysis

(2019) Rahul A. Jagtap et al.   Asian Journal of Organic Chemistry

Rh-Catalyzed C–H bond alkylation of indoles with α,α-difluorovinyl tosylate via indolyl group migration

(2018) Lu Zhou et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed, Remote Terminal Hydroarylation of Activated Olefins through a Long-Range Deconjugative Isomerization

(2018) Arun Jyoti Borah et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H alkylation reactions of indoles mediated by Pd(ii) and norbornene: applications and recent developments

(2018) Marcus Wegmann et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Silver-Mediated Oxidative Decarboxylative Intramolecular Asymmetric Radical Cyclization (Csp3–Csp2) via Memory of Chirality: Access to Circumdatin Alkaloids

(2018) Pankaj S. Mahajan et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Oxidative Annulation of 2,2′-Bipyridine N-Oxides with Alkynes via Dual C–H Bond Activation

(2018) Xin Xu et al.   ORGANIC LETTERS

Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups

(2018) Eric Tan et al.   ACS Catalysis

Photoredox-Mediated Minisci Alkylation of N-Heteroarenes using Carboxylic Acids and Hypervalent Iodine

(2018) Junhua Wang et al.   Asian Journal of Organic Chemistry

Metal-Catalyzed Synthesis of Substituted Indoles

(2018) So Won Youn et al.   Asian Journal of Organic Chemistry

Iron(ii)-catalyzed C-2 cyanomethylation of indoles and pyrroles via direct oxidative cross-dehydrogenative coupling with acetonitrile derivatives

(2018) Kai Qiao et al.   Organic Chemistry Frontiers

Rhodium(i)-catalysed decarbonylative direct C–H vinylation and dienylation of arenes

(2018) Jianbin Xu et al.   Organic Chemistry Frontiers

A versatile rhodium(iii) catalyst for direct acyloxylation of aryl and alkenyl C–H bonds with carboxylic acids

(2018) Changjun Chen et al.   Organic Chemistry Frontiers

Enantioselective Friedel–Crafts C2-alkylation of 3-substituted indoles with trifluoropyruvates and cyclic N-sulfonyl α-ketiminoesters

(2018) Bing-Bing Huang et al.   Organic Chemistry Frontiers

Rhodium(III)-Catalyzed Selective Direct Olefination of Imidazoles

(2018) Haoqiang Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition-Metal-Free Decarboxylation of 3,3,3-Trifluoro-2,2-dimethylpropanoic Acid for the Preparation of C(CF3)Me2-Containing Heteroarenes

(2018) Shuai Liu et al.   ORGANIC LETTERS

Visible-Light-Initiated, Photocatalyst-Free Decarboxylative Coupling of Carboxylic Acids with N-Heterocycles

(2018) Xiao-Yu Zhang et al.   ORGANIC LETTERS

PIII -Chelation-Assisted Indole C7-Arylation, Olefination, Methylation, and Acylation with Carboxylic Acids/Anhydrides by Rhodium Catalysis

(2018) Xiaodong Qiu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh-Catalyzed Removable Directing Group Assisted sp2 or sp3-C-H Bond Functionalization

(2018) Naoto Chatani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis

(2017) Gregory J. P. Perry et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Silver-Catalyzed Minisci Reactions Using Selectfluor as a Mild Oxidant

(2017) Jordan D. Galloway et al.   ORGANIC LETTERS

Ruthenium(II)-Catalyzed C–H Alkynylation of Weakly Coordinating Benzoic Acids

(2017) Ruhuai Mei et al.   ORGANIC LETTERS

C–H Alkylations of (Hetero)Arenes by Maleimides and Maleate Esters through Cobalt(III) Catalysis

(2017) Zhao Zhang et al.   ORGANIC LETTERS

Cobalt(II)-Catalyzed Oxidative C–H Arylation of Indoles and Boronic Acids

(2017) Xinju Zhu et al.   ORGANIC LETTERS

Nickel-Catalyzed C(sp2)–H/C(sp3)–H Oxidative Coupling of Indoles with Toluene Derivatives

(2017) Vineeta Soni et al.   ACS Catalysis

Visible Light-Mediated Direct Decarboxylative C–H Functionalization of Heteroarenes

(2017) R. Aleyda Garza-Sanchez et al.   ACS Catalysis

Ruthenium(II)- or Rhodium(III)-Catalyzed Grignard-Type Addition of Indolines and Indoles to Activated Carbonyl Compounds

(2016) Hyeim Jo et al.   ADVANCED SYNTHESIS & CATALYSIS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Iridium(III)-Catalyzed Regioselective Carbenoid Insertion C-H Alkylation by α-Diazotized Meldrum's Acid

(2016) Honggui Lv et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed C–H Arylation of Indoles at the C7 Position

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalysed direct C-2 methylation of indoles

(2016) Daoquan Tu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

C2-Alkylation and Alkenylation of Indoles Catalyzed by a Low-Valent Cobalt Complex in the Absence of Reductant

(2016) Brendan J. Fallon et al.   ORGANIC LETTERS

Unified Strategy for Nickel-Catalyzed C-2 Alkylation of Indoles through Chelation Assistance

(2016) Vineeta Soni et al.   ACS Catalysis

Very Important Publication: Iridium-Catalyzed Intramolecular Enantioselective CH Alkylation at the C-2 Position ofN-Alkenylindoles

(2015) Takanori Shibata et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition Metal-Catalyzed CH Activation of Indoles

(2015) Alexander H. Sandtorv   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Decarbonylative Direct Olefination of Arenes with Vinyl Carboxylic Acids

(2015) Ruiying Qiu et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Direct CH Olefination of Arenes with Aliphatic Olefins

(2015) Xiao Xue et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(iii)-catalyzed C–H activation and intermolecular annulation with terminal alkynes: from indoles to carbazoles

(2015) Jinlong Jia et al.   CHEMICAL COMMUNICATIONS

Strategies for the asymmetric functionalization of indoles: an update

(2015) Renato Dalpozzo   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Direct C2-Benzylation of Indoles with Alkylarenes

(2015) Hui-Jun Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel–N-Heterocyclic Carbene System

(2015) York Schramm et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver catalysed decarboxylative alkylation and acylation of pyrimidines in aqueous media

(2015) Wen-Peng Mai et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Regioselective Decarboxylative Alkylation of Arenes and Heteroarenes with Aliphatic Carboxylic Acids

(2015) Chanchal Premi et al.   ORGANIC LETTERS

Divergent Functionalization of Indoles with Acryloyl Silanes via Rhodium-Catalyzed C–H Activation

(2015) Ping Lu et al.   ORGANIC LETTERS

Rh(III)-Catalyzed C–H Alkylation of Arenes Using Alkylboron Reagents

(2015) He Wang et al.   ORGANIC LETTERS

Cp ∗ Co(III)-catalyzed direct functionalization of aromatic C–H bonds with α-diazomalonates

(2015) Xu-Ge Liu et al.   TETRAHEDRON LETTERS

Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C–H Activation and Ring Opening

(2015) Xukai Zhou et al.   ACS Catalysis

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Nickel-Catalyzed CH Alkylations: Direct Secondary Alkylations and Trifluoroethylations of Arenes

(2014) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Decarbonylative Direct C2-Arylation of Indoles with Aryl Carboxylic Acids

(2014) Lingjuan Zhang et al.   ChemCatChem

Rh(i)-catalyzed decarbonylative direct C2-olefination of indoles with vinyl carboxylic acids

(2014) Lingjuan Zhang et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed Oxidative CH Alkenylations of Sulfonic Acids, Sulfonyl Chlorides and Sulfonamides

(2014) Wenbo Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkene Isomerization-Hydroarylation Tandem Catalysis: Indole C2-Alkylation with Aryl-Substituted Alkenes Leading to 1,1-Diarylalkanes

(2014) Takeshi Yamakawa et al.   Chemistry-An Asian Journal

Cobalt-Catalyzed Enantioselective Directed C–H Alkylation of Indole with Styrenes

(2014) Pin-Sheng Lee et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–C Coupling of Arenes with 2-Vinyloxiranes: Synthesis of Allylic Alcohols

(2014) Songjie Yu et al.   ORGANIC LETTERS

Direct alkenyl C–H functionalization of cyclic enamines with carboxylic acids via Rh catalysis assisted by hydrogen bonding

(2014) Zhi-Quan Lei et al.   Organic Chemistry Frontiers

Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

(2014) Min Zhang et al.   Organic Chemistry Frontiers

Rhodium(I)-Catalyzed Redox-Economic Cross-Coupling of Carboxylic Acids with Arenes Directed by N-Containing Groups

(2013) Fei Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes through C-H Cleavage

(2013) Marvin Schinkel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(iii)-catalyzed dehydrogenative alkylation of (hetero)arenes with allylic alcohols, allowing aldol condensation to indenes

(2013) Zhuangzhi Shi et al.   CHEMICAL COMMUNICATIONS

Enantioselective Friedel–Crafts alkylation for synthesis of 2-substituted indole derivatives

(2013) Yulong Zhang et al.   CHEMICAL COMMUNICATIONS

Silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids

(2013) Wei-Ming Zhao et al.   CHEMICAL COMMUNICATIONS

Cobalt-Catalyzed CH Bond Functionalizations with Aryl and Alkyl Chlorides

(2013) Benudhar Punji et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed Intermolecular Asymmetric Hydroheteroarylation of Bicycloalkenes

(2013) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Route for the Alkylation of Purine Nucleosides at C6 via Minisci Reaction

(2013) Ran Xia et al.   ORGANIC LETTERS

Transition metal-catalyzed decarboxylative coupling reactions of alkynyl carboxylic acids

(2013) Kyungho Park et al.   RSC Advances

Palladium-Catalyzed Highly Regioselective Arylation of Allylamines with Thiophenes and Furans

(2012) Zhen Jiang et al.   ADVANCED SYNTHESIS & CATALYSIS

Cobalt-Catalyzed Direct Arylation and Benzylation by CH/CO Cleavage with Sulfamates, Carbamates, and Phosphates

(2012) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C2-Alkylation ofN-pyrimidylindole with vinylsilane via cobalt-catalyzed C–H bond activation

(2012) Zhenhua Ding et al.   Beilstein Journal of Organic Chemistry

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Indoles in Multicomponent Processes (MCPs)

(2012) Morteza Shiri   CHEMICAL REVIEWS

Ir(I)-Catalyzed C–H Bond Alkylation of C2-Position of Indole with Alkenes: Selective Synthesis of Linear or Branched 2-Alkylindoles

(2012) Shiguang Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Regioselective 2-Alkylation of Indoles via a Norbornene-Mediated C–H Activation: Mechanism and Applications

(2012) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways

(2012) Wojciech I. Dzik et al.   Chemical Science

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

(2011) Nuria Rodríguez et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Direct 2-Alkylation of Indoles by Norbornene-Mediated Regioselective Cascade C–H Activation

(2011) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Minisci reactions: Versatile CH-functionalizations for medicinal chemists

(2011) Matthew A. J. Duncton   MedChemComm

Nickel-Catalyzed Hydroheteroarylation of Vinylarenes

(2010) Yoshiaki Nakao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

(2010) Anna J. Kochanowska-Karamyan et al.   CHEMICAL REVIEWS

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Variolins and Related Alkaloids

(2009) Scott R. Walker et al.   CHEMICAL REVIEWS

Carboxylic Acids as Substrates in Homogeneous Catalysis

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION