Rh-Catalyzed C–H bond alkylation of indoles with α,α-difluorovinyl tosylate via indolyl group migration

Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes

(2017) Hironobu Sakaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Redox-Neutral Unsymmetrical C–H Alkylation and Amidation Reactions of N-Phenoxyacetamides

(2017) Yunxiang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Theoretical Studies on Rhodium-Catalyzed Coupling of Benzamides with 2,2-Difluorovinyl Tosylate: Diverse Synthesis of Fluorinated Heterocycles

(2017) Jia-Qiang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Approach to N-Substituted-2-Fluoroindoles by Sequential Construction of C–N Bonds from gem-Difluorostyrenes

(2017) Bin Zhang et al.   ORGANIC LETTERS

Sulfoxonium Ylides as a Carbene Precursor in Rh(III)-Catalyzed C–H Acylmethylation of Arenes

(2017) Youwei Xu et al.   ORGANIC LETTERS

Recent Developments in Ruthenium-Catalyzed C–H Arylation: Array of Mechanistic Manifolds

(2017) Pradeep Nareddy et al.   ACS Catalysis

C–F/C–H Functionalization by Manganese(I) Catalysis: Expedient (Per)Fluoro-Allylations and Alkenylations

(2017) Daniel Zell et al.   ACS Catalysis

Recent Advances in Catalytic C(sp2)–H Allylation Reactions

(2017) Neeraj Kumar Mishra et al.   ACS Catalysis

Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation

(2017) Wenbo Ma et al.   Organic Chemistry Frontiers

Palladium-Catalyzed Defluorinative Coupling of 1-Aryl-2,2-Difluoroalkenes and Boronic Acids: Stereoselective Synthesis of Monofluorostilbenes

(2016) Richard T. Thornbury et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Coupling Reactions Directed by Sulfoxides: Teaching an Old Functional Group New Tricks

(2016) Alexander P. Pulis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(iii)-catalyzed alkylation of primary C(sp3)–H bonds with α-diazocarbonyl compounds

(2016) Wei Hou et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations

(2016) Chuanfa Ni et al.   CHEMICAL SOCIETY REVIEWS

Mild and Copper-Free Stereoselective Cyanation of gem -Difluoroalkenes by Using Benzyl Nitrile as a Cyanating Reagent

(2016) Juan Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Redox-Neutral Rhodium-Catalyzed [4+1] Annulation through Formal Dehydrogenative Vinylidene Insertion

(2016) Huan Liu et al.   ChemSusChem

Iridium(III)-Catalyzed Regioselective Carbenoid Insertion C-H Alkylation by α-Diazotized Meldrum's Acid

(2016) Honggui Lv et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Difluorinated Enynes through Sonogashira-Type Coupling

(2016) Takumi Fujino et al.   ORGANIC LETTERS

Sterically Controlled Cu-Catalyzed or Transition-Metal-Free Cross-Coupling of gem-Difluoroalkenes with Tertiary, Secondary, and Primary Alkyl Grignard Reagents

(2016) Wenpeng Dai et al.   ORGANIC LETTERS

Rhodium-Catalyzed β-Selective Oxidative Heck-Type Coupling of Vinyl Acetate via C–H Activation

(2016) Hui-Jun Zhang et al.   ORGANIC LETTERS

Cobalt(III)-Catalyzed Regio- and Stereoselective α-Fluoroalkenylation of Arenes with gem-Difluorostyrenes

(2016) Lingheng Kong et al.   ORGANIC LETTERS

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

RhIII-Catalyzed CH Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

(2015) Ju Hyun Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-pot cascade synthesis of N-methoxyisoquinolinediones via Rh(iii)-catalyzed carbenoid insertion C–H activation/cyclization

(2015) Jingjing Shi et al.   CHEMICAL COMMUNICATIONS

Polyfluorinated Ethanes as Versatile Fluorinated C2-Building Blocks for Organic Synthesis

(2015) Valentine G. Nenajdenko et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Direct C-H Vinylation of Arenes To Access Styrenes with Vinyl Acetate as a Vinyl Source

(2015) Shu-Tao Mei et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 3,3,3-trifluoroethyl isocyanate, carbamate and ureas. Anticancer activity evaluation of N-(3,3,3-trifluoroethyl)-N′-substituted ureas

(2015) Elena L. Luzina et al.   JOURNAL OF FLUORINE CHEMISTRY

Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

(2015) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed Suzuki–Miyaura type cross-coupling reactions of (2,2-difluorovinyl)benzene derivatives with arylboronic acids

(2015) Yang Xiong et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Cinnolin-3(2H)-one Derivatives from Rh-Catalyzed Reaction of Azobenzenes with Diazotized Meldrum’s Acid

(2015) Jeong-Yu Son et al.   ORGANIC LETTERS

An Efficient Method for the Preparation of Styrene Derivatives via Rh(III)-Catalyzed Direct C–H Vinylation

(2015) Kate D. Otley et al.   ORGANIC LETTERS

Rhodium-catalysed C(sp2)–C(sp2) bond formation via C–H/C–F activation

(2015) Panpan Tian et al.   Nature Communications

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Efficient “On Water” Catalyst-Free Nucleophilic Addition Reactions Using Difluoroenoxysilanes: Dramatic Fluorine Effects

(2014) Jin-Sheng Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine effects in organocatalysis – asymmetric Brønsted acid assisted Lewis base catalysis for the synthesis of trifluoromethylated heterocycles exploiting the negative hyperconjugation of the CF3-group

(2014) Chandra M. R. Volla et al.   CHEMICAL COMMUNICATIONS

Rhodium(III)- and Iridium(III)-Catalyzed C7 Alkylation of Indolines with Diazo Compounds

(2014) Wen Ai  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed C–C Bond Formation of Quinoline N-Oxides at the C-8 Position under Mild Conditions

(2014) Jisu Jeong et al.   ORGANIC LETTERS

Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bonds

(2014) Xi-Sha Zhang et al.   Chemical Science

Preparation of [3H]fluoroethyl tosylate and its use in the labelling of the dopamine transporter radioligand [3H]FE-PE2I

(2013) Alison R Cochrane et al.   JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Fluorine Conformational Effects in Organocatalysis: An Emerging Strategy for Molecular Design

(2011) Lucie E. Zimmer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The effect of 2′-fluorine substitutions on DNA i-motif conformation and stability

(2008) Clare P. Fenna et al.   CHEMICAL COMMUNICATIONS

Direct Vinylation and Difluorovinylation of Arylboronic Acids Using Vinyl- and 2,2-Difluorovinyl Tosylates via the Suzuki−Miyaura Cross Coupling

(2008) Thomas M. Gøgsig et al.   JOURNAL OF ORGANIC CHEMISTRY