Rhodium(iii)-catalyzed C–H activation and intermolecular annulation with terminal alkynes: from indoles to carbazoles

One-pot cascade synthesis of N-methoxyisoquinolinediones via Rh(iii)-catalyzed carbenoid insertion C–H activation/cyclization

(2015) Jingjing Shi et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed Asymmetric Allylic Dearomatization Reactions

(2014) Chun-Xiang Zhuo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium(III)-Catalyzed Regioselective Direct C-2 Alkenylation of Indoles Assisted by the Removable N-(2-Pyrimidyl) Group

(2014) Binwei Gong et al.   ADVANCED SYNTHESIS & CATALYSIS

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

Manganese-Catalyzed Dehydrogenative [4+2] Annulation of NH Imines and Alkynes by CH/NH Activation

(2014) Ruoyu He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The CH Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by RhIIICatalysis

(2014) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Synthesis of Highly Substituted Polyheteroaromatic Compounds by Rhodium(III)-Catalyzed Multiple CH Activation and Annulation

(2014) Jayachandran Jayakumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Homologation by Non-Chelate-Assisted RhIII-Catalyzed CH Functionalization of Arenes with Alkynes

(2014) Manh V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed CH Alkynylation of Arenes at Room Temperature

(2014) Chao Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of conjugated 1,3-enynes by Rh(iii)-catalysed alkynylation of alkenes via C–H activation

(2014) Karl D. Collins et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

(2014) Chao Feng et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed C2-selective carbenoid functionalization and subsequent C7-alkenylation of indoles

(2014) Jingjing Shi et al.   CHEMICAL COMMUNICATIONS

Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds

(2014) Feng Chen et al.   CHEMICAL REVIEWS

Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes

(2014) Ying-Feng Han et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium(II)-Catalyzed Oxidative CH Alkenylations of Sulfonic Acids, Sulfonyl Chlorides and Sulfonamides

(2014) Wenbo Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)- and Iridium(III)-Catalyzed C7 Alkylation of Indolines with Diazo Compounds

(2014) Wen Ai  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh(III)- and Ir(III)-Catalyzed C–H Alkynylation of Arenes under Chelation Assistance

(2014) Fang Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient synthesis strategies by application of transition metal-catalyzed carbene/nitrene insertions into C–H bonds

(2014) Julian Egger et al.   NATURAL PRODUCT REPORTS

Rhodium(iii)-catalyzed C–H alkynylation of azomethine ylides under mild conditions

(2014) Xueyun Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(iii)-catalyzed regioselective C2-amidation of indoles with N-(2,4,6-trichlorobenzoyloxy)amides and its synthetic application to the development of a novel potential PPARγ modulator

(2014) Jingjing Shi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)-Catalyzed C–C Bond Formation of Quinoline N-Oxides at the C-8 Position under Mild Conditions

(2014) Jisu Jeong et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Olefinic C–H Alkynylation of Acrylamides Using Tosyl-Imide as Directing Group

(2014) Chao Feng et al.   ORGANIC LETTERS

Isoquinoline skeleton synthesis via chelation-assisted C−H activation

(2014) Ruoyu He et al.   TETRAHEDRON LETTERS

Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

(2014) Min Zhang et al.   Organic Chemistry Frontiers

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Oxidative Annulation of Sulfoximines and Alkynes as an Approach to 1,2-Benzothiazines

(2013) Wanrong Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Cross-Coupling between Heterocycles and Terminal Alkynes with Low Catalyst Loading

(2013) Xiaoming Jie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H nitrogenation and oxygenation by ruthenium catalysis

(2013) Vedhagiri S. Thirunavukkarasu et al.   CHEMICAL COMMUNICATIONS

Synthesis of heterocycles via transition-metal-catalyzed hydroarylation of alkynes

(2013) Yoshihiko Yamamoto   CHEMICAL SOCIETY REVIEWS

Design of Potent Poxvirus Inhibitors of the Heterodimeric Processivity Factor Required for Viral Replication

(2013) Manunya Nuth et al.   JOURNAL OF MEDICINAL CHEMISTRY

Mn-Catalyzed Aromatic C–H Alkenylation with Terminal Alkynes

(2013) Bingwei Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

PdII-Catalyzed Di-o-olefination of Carbazoles Directed by the Protecting N-(2-Pyridyl)sulfonyl Group

(2013) Beatriz Urones et al.   ORGANIC LETTERS

Intramolecular C(sp3)–H amination

(2013) Jenna L. Jeffrey et al.   Chemical Science

Recent Advances in Iridium-Catalyzed Alkylation of C–H and N–H Bonds

(2013) Shiguang Pan et al.   ACS Catalysis

Water as a green solvent for efficient synthesis of isocoumarins through microwave-accelerated and Rh/Cu-catalyzed C–H/O–H bond functionalization

(2013) Qiu Li et al.   RSC Advances

Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential CH and CN Cleavage

(2012) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Occurrence, Biogenesis, and Synthesis of Biologically Active Carbazole Alkaloids

(2012) Arndt W. Schmidt et al.   CHEMICAL REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Rhodium-catalysed asymmetric hydrogenation as a valuable synthetic tool for the preparation of chiral drugs

(2012) Pablo Etayo et al.   CHEMICAL SOCIETY REVIEWS

Amide-Directed Tandem CC/CN Bond Formation through CH Activation

(2012) Chen Zhu et al.   Chemistry-An Asian Journal

Rhodium-catalyzed regioselective amidation of indoles with sulfonyl azides via C–H bond activation

(2012) Jingjing Shi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Toward Polynuclear Ru–Cu Catalytic Dehydrogenative C–N Bond Formation, on the Reactivity of Carbazoles

(2012) Marie-Laure Louillat et al.   ORGANIC LETTERS

Direct Ortho Arylation of 9-(Pyridin-2-yl)-9H-carbazoles Bearing a Removable Directing Group via Palladium(II)-Catalyzed C–H Bond Activation

(2012) Jean-Ho Chu et al.   ORGANOMETALLICS

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Recent advances in [2+2+2] cycloaddition reactions

(2011) Gema Domínguez et al.   CHEMICAL SOCIETY REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Vinyl Moiety as a Handle for Regiocontrol in the Preparation of Unsymmetrical 2,3-Aliphatic-Substituted Indoles and Pyrroles

(2010) Malcolm P. Huestis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

(2010) Anna J. Kochanowska-Karamyan et al.   CHEMICAL REVIEWS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation

(2010) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyrrole Synthesis via Allylic sp3C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes

(2010) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes

(2009) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Oxidative Coupling Reactions of Two Different Terminal Alkynes Using O2as the Oxidant at Room Temperature: Facile Syntheses of Unsymmetric 1,3-Diynes

(2009) Weiyan Yin et al.   ORGANIC LETTERS

Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation

(2008) Jared C. Lewis et al.   ACCOUNTS OF CHEMICAL RESEARCH