PIII -Chelation-Assisted Indole C7-Arylation, Olefination, Methylation, and Acylation with Carboxylic Acids/Anhydrides by Rhodium Catalysis

Regioselective direct arylation of indoles on the benzenoid moiety

(2018) Youqing Yang et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed, Remote Terminal Hydroarylation of Activated Olefins through a Long-Range Deconjugative Isomerization

(2018) Arun Jyoti Borah et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Chemoselective C(acyl)–O Bond vs C(aryl)–C Bond Activation of Aromatic Esters in Nickel Catalyzed C(sp2)–C(sp3) Cross-Couplings

(2018) Adisak Chatupheeraphat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed, ortho C–H Methylation and Fluorination of Benzaldehydes Using Orthanilic Acids as Transient Directing Groups

(2018) Xiao-Yang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Well-Defined Palladium(II)–NHC Precatalysts for Cross-Coupling Reactions of Amides and Esters by Selective N–C/O–C Cleavage

(2018) Shicheng Shi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel-Catalyzed Amide Bond Formation from Methyl Esters

(2018) Taoufik Ben Halima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-Catalyzed Alkene Carboacylation via Amide C–N Bond Activation

(2017) James A. Walker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Suzuki–Miyaura Coupling of Aryl Esters

(2017) Taoufik Ben Halima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote C6-Selective Ruthenium-Catalyzed C–H Alkylation of Indole Derivatives via σ-Activation

(2017) Jamie A. Leitch et al.   ACS Catalysis

Beyond C2 and C3: Transition-Metal-Catalyzed C–H Functionalization of Indole

(2017) Jamie A. Leitch et al.   ACS Catalysis

Palladium-Catalyzed C–H Arylation of Indoles at the C7 Position

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Direct C6-Arylation of Indoles

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C–H Amidation of N-Pivaloylindoles with Organic Azides

(2016) Youyoung Kim et al.   ORGANIC LETTERS

Electronic Nature of Ketone Directing Group as a Key To Control C-2 vs C-4 Alkenylation of Indoles

(2016) Veeranjaneyulu Lanke et al.   ORGANIC LETTERS

Rhodium-Catalyzed Regioselective C7-Functionalization of N -Pivaloylindoles

(2015) Lanting Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Concise and Scalable Strategy for the Total Synthesis of Dictyodendrin B Based on Sequential CH Functionalization

(2015) Andrew K. Pitts et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Group Exchange between Ketones and Carboxylic Acids through Directing Group Assisted Rh-Catalyzed Reorganization of Carbon Skeletons

(2015) Zhi-Quan Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Decarbonylative Coupling with Alkynes via C–C Activation of Isatins

(2015) Rong Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of amides to esters by the nickel-catalysed activation of amide C–N bonds

(2015) Liana Hie et al.   NATURE

Nickel-catalysed Suzuki–Miyaura coupling of amides

(2015) Nicholas A. Weires et al.   Nature Chemistry

Structure and biosynthesis of a macrocyclic peptide containing an unprecedented lysine-to-tryptophan crosslink

(2015) Kelsey R. Schramma et al.   Nature Chemistry

Rhodium-Catalyzed Decarbonylative Direct C2-Arylation of Indoles with Aryl Carboxylic Acids

(2014) Lingjuan Zhang et al.   ChemCatChem

Rh(i)-catalyzed decarbonylative direct C2-olefination of indoles with vinyl carboxylic acids

(2014) Lingjuan Zhang et al.   CHEMICAL COMMUNICATIONS

Total syntheses of indolactam alkaloids (−)-indolactam V, (−)-pendolmycin, (−)-lyngbyatoxin A, and (−)-teleocidin A-2

(2014) Noah F. Fine Nathel et al.   Chemical Science

Unexpected regioselective carbon–hydrogen bond activation/cyclization of indolyl aldehydes or ketones with alkynes to benzo-fused oxindoles

(2014) Xingyan Liu et al.   Nature Communications

Rhodium(III)-Catalyzed Direct Regioselective Synthesis of 7-Substituted Indoles

(2013) Zengqiang Song et al.   ORGANIC LETTERS

Extrusion of CO from Aryl Ketones: Rhodium(I)-Catalyzed CC Bond Cleavage Directed by a Pyridine Group

(2012) Zhi-Quan Lei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Update 1 of: Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions

(2011) Sandro Cacchi et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Ruthenium-catalyzed Acylation of Arylpyridines with Acyl Chlorides viaortho-Selective C–H Bond Cleavage

(2011) Takuya Kochi et al.   CHEMISTRY LETTERS

Cationic Palladium(II) Catalysis: C−H Activation/Suzuki−Miyaura Couplings at Room Temperature

(2010) Takashi Nishikata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles

(2010) Daniel W. Robbins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal-Catalysed, Direct and Site-Selective N1-, C2- or C3-Arylation of the Indole Nucleus: 20 Years of Improvements

(2009) Lionel Joucla et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium/N-Heterocyclic Carbene Catalyzed Direct Intermolecular Arylation of sp2and sp3CH Bonds with Chelation Assistance

(2009) Min Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Ruthenium-Catalyzed Amino- and Alkoxycarbonylations with Carbamoyl Chlorides and Alkyl Chloroformates via Aromatic C−H Bond Cleavage

(2009) Takuya Kochi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation

(2008) Jared C. Lewis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Regioselective C−H Functionalization via Decarbonylation of Acid Chlorides and C−H Bond Activation under Phosphine-Free Conditions

(2008) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY