Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution: From Design to Applications
出版年份 2021 全文链接
标题
Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution: From Design to Applications
作者
关键词
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出版物
CHEMICAL REVIEWS
Volume 121, Issue 8, Pages 4373-4505
出版商
American Chemical Society (ACS)
发表日期
2021-03-19
DOI
10.1021/acs.chemrev.0c00736
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- Enantioselective Palladium-Catalyzed Decarboxylative Allylation of β-Keto Esters Assisted by a Thiourea
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- Palladium catalyzed asymmetric reactions assisted by P* , P* -bidentate bisdiamidophosphites based on 1,4-diols
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- Asymmetric synthesis of all-carbon quaternary spirocycles via a catalytic enantioselective allylic alkylation strategy
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- Palladium-catalyzed asymmetric allylic alkylation of acyclic ketones for synthesis of 2,2-disubsituted pyrrolidine derivatives
- (2017) Wen-Fang Lian et al. TETRAHEDRON LETTERS
- Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade
- (2017) Robert A. Craig et al. Chemical Science
- Highly Enantioselective Construction of Sterically Hindered α-Allyl-α-Aryl Lactones via Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation
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- Palladium-catalyzed asymmetric allylic amination: enantioselective synthesis of chiral α-methylene substituted β-aminophosphonates
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- Palladium-Catalyzed Highly Stereoselective Dearomative [3 + 2] Cycloaddition of Nitrobenzofurans
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- Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts
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- Cyclobutenes: At a Crossroad between Diastereoselective Syntheses of Dienes and Unique Palladium-Catalyzed Asymmetric Allylic Substitutions
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- Catalytic Asymmetric Allylation of 3-Aryloxindoles by Merging Palladium Catalysis and Asymmetric H-Bonding Catalysis
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- Substrate-Regiocontrolled Synthesis of Enantioenriched Allylic Amines by Palladium-Catalysed Asymmetric Allylic Amination: Formal Synthesis of Fagomine
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- Palladium-Catalyzed Asymmetric Allylic Alkylations with Toluene Derivatives as Pronucleophiles
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- Enantioselective Pd-Catalyzed Allylic Alkylation Reactions of Dihydropyrido[1,2-a ]indolone Substrates: Efficient Syntheses of (−)-Goniomitine, (+)-Aspidospermidine, and (−)-Quebrachamine
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- Catalytic Enantioselective and Diastereoselective Allylic Alkylation with Fluoroenolates: Efficient Access to C3-Fluorinated and All-Carbon Quaternary Oxindoles
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- Palladium-Catalyzed Asymmetric Benzylic Alkylation of Active Methylene Compounds with α-Naphthylbenzyl Carbonates and Pivalates
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- P,S Ligands for the Asymmetric Construction of Quaternary Stereocenters in Palladium-Catalyzed Decarboxylative [4+2] Cycloadditions
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- Enantioselective Allylic C−H Oxidation of Terminal Olefins to Isochromans by Palladium(II)/Chiral Sulfoxide Catalysis
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- Decarboxylative [4+2] Cycloaddition by Synergistic Palladium and Organocatalysis
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- Asymmetric Catalysis with CO2 : The Direct α-Allylation of Ketones
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- Multiple Absolute Stereocontrol in Pd-Catalyzed [3+2] Cycloaddition of Oxazolidinones and Trisubstituted Alkenes Using Chiral Ammonium–Phosphine Hybrid Ligands
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- Allylic Alkylations with Enamine Nucleophiles
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- Combinations of Aminocatalysts and Metal Catalysts: A Powerful Cooperative Approach in Selective Organic Synthesis
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- Palladium-catalyzed Asymmetric Allylic Alkylation UsingC2-symmetric Chiral Bidentate Bis(N-heterocyclic carbene) Ligands with theo-Xylylene Framework
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- Palladium(0)-Catalyzed Intermolecular Allylic Dearomatization of Indoles by a Formal [4+2] Cycloaddition Reaction
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- Kinetic Resolution of Racemic Allylic Alcohols by Catalytic Asymmetric Substitution of the OH Group with Monosubstituted Hydrazines
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- Asymmetric Morita-Baylis-Hillman Reaction: Catalyst Development and Mechanistic Insights Based on Mass Spectrometric Back-Reaction Screening
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- Highly Enantioselective Formation of α-Allyl-α-Arylcyclopentanones via Pd-Catalysed Decarboxylative Asymmetric Allylic Alkylation
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- Tandem Thorpe Reaction/Palladium Catalyzed Asymmetric Allylic Alkylation: Access to Chiral β-enaminonitriles with Excellent Enantioselectivity
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- Diphosphorus Ligands Containing a P-Stereogenic Phosphane and a Chiral Phosphite or Phosphorodiamidite - Evaluation in Pd-Catalysed Asymmetric Allylic Substitution Reactions
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- Nickel-Catalyzed Construction of Chiral 1-[6]Helicenols and Application in the Synthesis of [6]Helicene-Based Phosphinite Ligands
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- Production of Csp3-Csp3Bonds through Palladium-Catalyzed Tsuji-Trost-Type Reactions of (Hetero)Benzylic Substrates
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- Synthesis of chiral fluorine-containing compounds via Pd-catalyzed asymmetrical allylations of dimethyl 2-fluoromalonate using sulfonamide-pyridine ligands
- (2016) Min Zhang et al. JOURNAL OF FLUORINE CHEMISTRY
- Enantioselective Formal Synthesis of Nectrisine Using a Palladium-Catalyzed Asymmetric Allylic Amination and Cross-Metathesis as Key Steps
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- Palladium-Catalyzed Regio- and Enantioselective Synthesis of Allylic Amines Featuring Tetrasubstituted Tertiary Carbons
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- Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis
- (2016) Colin Diner et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Cooperative N-Heterocyclic Carbene/Palladium-Catalyzed Enantioselective Umpolung Annulations
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- Highly Enantioselective Allylic C–H Alkylation of Terminal Olefins with Pyrazol-5-ones Enabled by Cooperative Catalysis of Palladium Complex and Brønsted Acid
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- Sugar-Annulated Oxazoline Ligands: A Novel Pd(II) Complex and Its Application in Allylic Substitution
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- Palladium-catalyzed enantioselective allylic alkylation of trifluoromethyl group substituted racemic and acyclic unsymmetrical 1,3-disubstituted allylic esters with malonate anions
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- A Second-Generation Synthesis of the Cyanthiwigin Natural Product Core
- (2016) Kelly E. Kim et al. ORGANIC LETTERS
- 1,3-Dithianes as Acyl Anion Equivalents in Pd-Catalyzed Asymmetric Allylic Substitution
- (2016) Kun Yao et al. ORGANIC LETTERS
- The Construction of Chiral Fused Azabicycles Using a Pd-Catalyzed Allylic Substitution Cascade and Asymmetric Desymmetrization Strategy
- (2016) Qianjin An et al. ORGANIC LETTERS
- A Palladium-Catalyzed Asymmetric Allylic Alkylation Approach to α-Quaternary γ-Butyrolactones
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- Asymmetric Catalyzed Allylic Substitution Using a Pd/P–S Catalyst Library with Exceptional High Substrate and Nucleophile Versatility: DFT and Pd-π-allyl Key Intermediates Studies
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- Cofactor-Controlled Chirality of Tropoisomeric Ligand
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- Diamidophosphite based on (1R,2R)-1,2-bis(3-hydroxybenzamido)cyclohexane in Pd-catalyzed enantioselective allylation
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- Anion-Stoichiometry-Dependent Selectivity Enhancement in Ion-Paired Chiral Ligand–Palladium Complex Catalyzed Enantioselective Allylic Alkylation
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- Enantioselective Construction of Quaternary Carbon Stereocenter via Palladium-Catalyzed Asymmetric Allylic Alkylation of Lactones
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- Enantioselective Synthesis of Planar-Chiral 1,n-Dioxa[n]paracyclophane-Based Phosphites and Their Application as Chiral Ligands
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- Asymmetric Allylation of 2-Oxocycloalkanecarboxylates
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- Recent Developments in Asymmetric Allylic Amination Reactions
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- Synthesis of original phosphine-sulfoxide ligands for asymmetric allylic alkylation
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- Sulfur-containing derivatives from (1 R )-(−)-myrtenal designed as chiral ligands
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- Catalytic enantioselective total synthesis of (+)-eucomic acid
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- Synthesis of novel chiral biquinolyl diphosphine ligand and its applications in palladium-catalyzed asymmetric allylic substitution reactions
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- Palladium-catalyzed construction of quaternary carbon centers with propargylic electrophiles
- (2016) Vilius Franckevičius TETRAHEDRON LETTERS
- Synthesis of chiral S , N -thioimidazoline ligands for palladium-catalyzed asymmetric allylic alkylations
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- Diamidophosphite–oxazolines with a pyridine core in Pd-catalyzed asymmetric reactions
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- Conformational Preferences of a Tropos Biphenyl Phosphinooxazoline–a Ligand with Wide Substrate Scope
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- Rational Design and Synthesis of [5]Helicene-Derived Phosphine Ligands and Their Application in Pd-Catalyzed Asymmetric Reactions
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- Highly enantioselective Pd-catalyzed indole allylic alkylation using binaphthyl-based phosphoramidite-thioether ligands
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- (S)-2-[(N-arylamino)methyl]pyrrolidines-Based PhosphoramiditeP,N-Ligand Library for Asymmetric Metal-Catalyzed Allylic Substitution and Conjugate 1,4-Addition
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- Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules
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- An Efficient Protocol for the Palladium-Catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst
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- Asymmetric Allylic Alkylation of β-Ketoesters with Allylic Alcohols by a Nickel/Diphosphine Catalyst
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- Palladium(II)/Brønsted Acid-Catalyzed Enantioselective Oxidative Carbocyclization-Borylation of Enallenes
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- An Enantioselective Total Synthesis of (−)-Isoschizogamine
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- Theoretical and Experimental Optimization of a New Amino Phosphite Ligand Library for Asymmetric Palladium-Catalyzed Allylic Substitution
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- Palladium-Catalyzed Enantioselective Allylic Substitution in the Presence of Monodentate Furanoside Phosphoramidites
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- Enantioselective transformation of Na2SO3 into allylic sulfonic acids under Pd catalysis
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- Transition metal-catalyzed allylic substitution reactions with unactivated allylic substrates
- (2015) Nicholas A. Butt et al. CHEMICAL SOCIETY REVIEWS
- Stereoselective coordination: a six-membered P,N-chelate tailored for asymmetric allylic alkylation
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- Synthesis of a 4-Vinyltetrahydrocarbazole by Palladium-Catalyzed Asymmetric Allylic Alkylation of Indole-Containing Allylic Carbonates
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- Enantioselective Allylic Alkylation Catalyzed by NovelC2-Symmetric Bisphosphinites
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- Applications of Fluorine in Medicinal Chemistry
- (2015) Eric P. Gillis et al. JOURNAL OF MEDICINAL CHEMISTRY
- Cytisine as a scaffold for ortho-diphenylphosphinobenzenecarboxamide ligands for Pd-catalyzed asymmetric allylic alkylation
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- A Highly Convergent Total Synthesis of Leustroducsin B
- (2015) Barry M. Trost et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective Synthesis of α-Quaternary Mannich Adducts by Palladium-Catalyzed Allylic Alkylation: Total Synthesis of (+)-Sibirinine
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- A New Class of Non-C2-Symmetric Ligands for Oxidative and Redox-Neutral Palladium-Catalyzed Asymmetric Allylic Alkylations of 1,3-Diketones
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- Catalytic Enantioselective Synthesis of Planar-Chiral Cyclic Amides Based on a Pd-Catalyzed Asymmetric Allylic Substitution Reaction
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- Asymmetric Allylic C–H Oxidation for the Synthesis of Chromans
- (2015) Pu-Sheng Wang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective synthesis of monofluorinated allylic compounds: Pd-catalyzed asymmetric allylations of dimethyl 2-fluoromalonate using new N-sulfinyl-based ligands
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- Enantioselective synthesis of 4-substituted tetrahydroisoquinolines via palladium-catalyzed intramolecular Friedel–Crafts type allylic alkylation of phenols
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- Kinetic resolution of primary allylic amines via palladium-catalyzed asymmetric allylic alkylation of malononitriles
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- Enantioselective Direct Functionalization of Indoles by Pd/Sulfoxide-Phosphine-Catalyzed N-Allylic Alkylation
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- Enantioselective Synthesis of Dialkylated N-Heterocycles by Palladium-Catalyzed Allylic Alkylation
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- Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones
- (2015) Robert A. Craig et al. ORGANIC LETTERS
- Hydrogen-Bond Directed Regioselective Pd-Catalyzed Asymmetric Allylic Alkylation: The Construction of Chiral α-Amino Acids with Vicinal Tertiary and Quaternary Stereocenters
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- Enantioselective Synthesis of Homoallylic Azides and Nitriles via Palladium-Catalyzed Decarboxylative Allylation
- (2015) Maria Victoria Vita et al. ORGANIC LETTERS
- Regioselective Derivatizations of a Tribrominated Atropisomeric Benzamide Scaffold
- (2015) Kimberly T. Barrett et al. ORGANIC LETTERS
- Pd-Catalyzed Asymmetric Decarboxylative Cycloaddition of Vinylethylene Carbonates with Imines
- (2015) Lei Yang et al. ORGANIC LETTERS
- Palladium Catalyzed Asymmetric Allylation of 3-OBoc-Oxindoles: An Efficient Synthesis of 3-Allyl-3-hydroxyoxindoles
- (2015) Samydurai Jayakumar et al. ORGANIC LETTERS
- Modular P-Chirogenic Phosphine-Sulfide Ligands: Clear Evidence for Both Electronic Effect and P-Chirality Driving Enantioselectivity in Palladium-Catalyzed Allylations
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- Synthesis of New Chiral Bidentate Isonitrile–Acyclic Diaminocarbene Palladium(II) Compounds and Their Catalytic Activity
- (2015) Matthias Knorn et al. ORGANOMETALLICS
- Metal Complexes Containing Enantiopure Bis(diamidophosphite) Ligands in Asymmetric Allylic Substitution and Hydroformylation Reactions
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- Palladium-catalyzed enantioselective allylation in the presence of phosphoramidites derived from (S a)-3-SiMe3-BINOL, (R,S)-semi-TADDOL, and (R,R)-TADDOL
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- Kinetic Resolution of Unsymmetrical Acyclic Allyl Carbonates Using Trimethylsilyl Cyanide via Palladium-Catalyzed Asymmetric Allylic Alkylation
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- First Example of Intermolecular Palladium-Catalyzed Asymmetric Allylic Alkylation of Hydroxyacrylates: Synthesis of All-Carbon α-Aryl Quaternary Carbonyl Compounds
- (2015) M. Hossain et al. SYNTHESIS-STUTTGART
- Construction of tertiary chiral centers by Pd-catalyzed asymmetric allylic alkylation of prochiral enolate equivalents
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- Chiral N -( tert -butyl)- N -methylaniline type ligands: synthesis and application to palladium-catalyzed asymmetric allylic alkylation
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- Metal catalyzed allylic alkylation: its development in the Trost laboratories
- (2015) Barry M. Trost TETRAHEDRON
- NOBIN-based chiral phosphite-type ligands and their application in asymmetric catalysis
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- Pd-catalyzed asymmetric α-allylic alkylation of thioamides
- (2015) Bin Rong et al. TETRAHEDRON LETTERS
- Enantioselective synthesis of 4-alkenoic acids via Pd-catalyzed allylic alkylation: stereocontrolled construction of γ and δ-lactones
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- Biimidazoline ligands for palladium-catalyzed asymmetric allylic alkylation
- (2015) Xin-Qi Hao et al. TETRAHEDRON-ASYMMETRY
- Atroposelective synthesis of axially chiral P,S-ligands based on arynes
- (2015) Anaïs Berthelot-Bréhier et al. Organic Chemistry Frontiers
- Phosphorylated (S)-tert-leucinol isophthalic diamide as a ligand for Pd-catalyzed asymmetric allylic substitution
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- The [3 + 3]-Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts
- (2014) Xinfang Xu et al. ACCOUNTS OF CHEMICAL RESEARCH
- Synthesis of γ-Lactams and γ-Lactones via Intramolecular Pd-Catalyzed Allylic Alkylations
- (2014) Claire Kammerer et al. ACCOUNTS OF CHEMICAL RESEARCH
- Transition-Metal-Catalyzed Asymmetric Allylic Dearomatization Reactions
- (2014) Chun-Xiang Zhuo et al. ACCOUNTS OF CHEMICAL RESEARCH
- Palladium-Catalyzed Asymmetric Decarboxylative Cycloaddition of Vinylethylene Carbonates with Michael Acceptors: Construction of Vicinal Quaternary Stereocenters
- (2014) Ajmal Khan et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Palladium-Catalyzed Asymmetric Amination of Allenyl Phosphates: Enantioselective Synthesis of Allenes with an Additional Unsaturated Unit
- (2014) Qiankun Li et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Asymmetric Palladium-Catalyzed Allylic Alkylation Using Dialkylzinc Reagents: A Remarkable Ligand Effect
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- Enantioselective Synthesis of α-Secondary and α-Tertiary Piperazin-2-ones and Piperazines by Catalytic Asymmetric Allylic Alkylation
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- Traceless Preparation of C-Terminal α-Ketoacids for Chemical Protein Synthesis by α-Ketoacid-Hydroxylamine Ligation: Synthesis of SUMO2/3
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- Cooperative Catalysis by Palladium and a Chiral Phosphoric Acid: Enantioselective Amination of Racemic Allylic Alcohols
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- Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study
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- Chiral Counteranion Strategy for Asymmetric Oxidative C(sp3)H/C(sp3)H Coupling: Enantioselective α-Allylation of Aldehydes with Terminal Alkenes
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- Palladium-Catalyzed Decarboxylative Cycloaddition of Vinylethylene Carbonates with Formaldehyde: Enantioselective Construction of Tertiary Vinylglycols
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- Synthesis of 1-[bis(trifluoromethyl)phosphine]-1’-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates
- (2014) Zeng-Wei Lai et al. Beilstein Journal of Organic Chemistry
- Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation
- (2014) Yiyang Liu et al. Beilstein Journal of Organic Chemistry
- Multistereogenic Phosphine Ligand-promoted Palladium-Catalyzed Allylic Alkylation of Cyanoesters
- (2014) Wen-Hui Deng et al. ChemCatChem
- Filling the Gaps in the Challenging Asymmetric Hydroboration of 1,1-Disubstituted Alkenes with Simple Phosphite-Based Phosphinooxazoline Iridium Catalysts
- (2014) Marc Magre et al. ChemCatChem
- Rational design of sulfoxide–phosphine ligands for Pd-catalyzed enantioselective allylic alkylation reactions
- (2014) Hong-Gang Cheng et al. CHEMICAL COMMUNICATIONS
- Total synthesis of (+)-kopsihainanine A
- (2014) Masaya Mizutani et al. CHEMICAL COMMUNICATIONS
- A Stereoselective Switch: Enantiodivergent Approach to the Synthesis of Isoflavanones
- (2014) Robert Doran et al. CHEMISTRY-A EUROPEAN JOURNAL
- Palladium-Catalyzed Enantioselective Decarboxylative Cycloaddition of Vinylethylene Carbonates with Isocyanates
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- Versatile CuI/Pd0Dual Catalysis for the Synthesis of Quaternary α-Allylated Carbonyl Compounds: Development, Mechanistic Investigations and Scope
- (2014) Fady Nahra et al. CHEMISTRY-A EUROPEAN JOURNAL
- Carbon-Phosphorus Bond Formation by Enantioselective Palladium-Catalyzed Allylation of Diphenylphosphine Oxide
- (2014) Liang Zhang et al. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- First Example of the Intermolecular Palladium-Catalyzed Asymmetric Allylic Alkylation of Hydroxyacrylates: Synthesis of All-Carbon α-Aryl Quaternary Aldehydes
- (2014) Sharif A. Asad et al. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Synthesis and application of new iminopyridine ligands in the enantioselective palladium-catalyzed allylic alkylation
- (2014) Maurizio Solinas et al. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
- Catalytic Asymmetric Synthesis of Sterically Hindered Tertiary α-Aryl Ketones
- (2014) Robert Doran et al. JOURNAL OF ORGANIC CHEMISTRY
- Two Approaches in the Synthesis of Planar Chiral Azinylferrocenes
- (2014) Irina A. Utepova et al. JOURNAL OF ORGANIC CHEMISTRY
- Mechanistic Insights into the Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Multisubstituted Pyrroles: Understanding the Remarkable Regio- and Enantioselectivity
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- Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles
- (2014) Chun-Xiang Zhuo et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Congested C–C Bonds by Pd-Catalyzed Enantioselective Allyl–Allyl Cross-Coupling, a Mechanism-Guided Solution
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- Decarboxylative allylations of ester enolate equivalents
- (2014) Yamuna Ariyarathna et al. ORGANIC & BIOMOLECULAR CHEMISTRY
- Enantioselective Synthesis of Polycyclic Carbocycles via an Alkynylation–Allylation–Cyclization Strategy
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- Kinetic Resolution of 2-Substituted 2,3-Dihydro-4-pyridones by Palladium-Catalyzed Asymmetric Allylic Alkylation: Catalytic Asymmetric Total Synthesis of Indolizidine (−)-209I
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- Palladium-Catalyzed Asymmetric Cycloadditions of Vinylcyclopropanes and in Situ Formed Unsaturated Imines: Construction of Structurally and Optically Enriched Spiroindolenines
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- Development of (Trimethylsilyl)ethyl Ester Protected Enolates and Applications in Palladium-Catalyzed Enantioselective Allylic Alkylation: Intermolecular Cross-Coupling of Functionalized Electrophiles
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- Branch-Selective Allylic C–H Carboxylation of Terminal Alkenes by Pd/sox Catalyst
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- Enantioselective Allylic Amination of Trifluoromethyl Group Substituted Racemic and Unsymmetrical 1,3-Disubstituted Allylic Esters by Palladium Catalysts
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- Brønsted Acid Accelerated Pd-Catalyzed Direct Asymmetric Allylic Alkylation of Azlactones with Simple Allylic Alcohols: A Practical Access to Quaternary Allylic Amino Acid Derivatives
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- Hydrogen-Bond-Activated Palladium-Catalyzed Allylic Alkylation via Allylic Alkyl Ethers: Challenging Leaving Groups
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- Highly Versatile Pd–Thioether–Phosphite Catalytic Systems for Asymmetric Allylic Alkylation, Amination, and Etherification Reactions
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- Sterically Demanding Planar Chiral P,N Ligands by Diastereoselective Ortho Lithiation of Pentaphenylferrocenyloxazolines and Their Application to Palladium-Catalyzed Substitutions with Cyclic Allylic Acetates
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- Efficient Palladium Catalysts Containing Original Imidazolium-Tagged Chiral Diamidophosphite Ligands for Asymmetric Allylic Substitutions in Neat Ionic Liquid
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- Asymmetric trapping of zwitterionic intermediates by sulphur ylides in a palladium-catalysed decarboxylation-cycloaddition sequence
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- Palladium-Catalyzed Asymmetric [3 + 2] Cycloaddition of 5-Vinyloxazolidinones with Imines Using Chiral Ammonium-Phosphine Hybrid Ligand
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- Enantioselective Pd-catalyzed tandem allylic alkylation reaction using monodentate phosphoramidite ligands for the formal total synthesis of huperzine A
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- Kinetic resolution of 4-substituted-3,4-dihydrocoumarins via Pd-catalyzed asymmetric allylic alkylation reaction: enantioselective synthesis of trans-3,4-disubstituted-3,4-dihydrocoumarins
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- Palladium-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Naphthol Derivatives
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- Enantioselective Construction of α-Quaternary Cyclobutanones by Catalytic Asymmetric Allylic Alkylation
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- Hydrogen-Bond-Promoted Palladium Catalysis: Allylic Alkylation of Indoles with Unsymmetrical 1,3-Disubstituted Allyl Acetates Using Chiral Bis(sulfoxide) Phosphine Ligands
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- Expanding Insight into Asymmetric Palladium-Catalyzed Allylic Alkylation of N-Heterocyclic Molecules and Cyclic Ketones
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- A New Modular Phosphite-Pyridine Ligand Library for Asymmetric Pd-Catalyzed Allylic Substitution Reactions: A Study of the Key Pd-π-Allyl Intermediates
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- Palladium-Catalyzed Asymmetric Benzylation of Azlactones
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- Development of a Novel Multifunctional N,P Ligand for Highly Enantioselective Palladium-Catalyzed Asymmetric Allylic Etherification of Alcohols and Silanols
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- Synthesis and Reactivity of Chiral, Wide-Bite-Angle, Hybrid Diphosphorus Ligands
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- Catalytic Asymmetric Allylic Alkylation of 3-Arylated Piperidin-2-ones
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- Highly Enantioselective Alkylation of Allyl Acetates Using Tartrate-Derived Bioxazoline Ligands
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- The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis
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- Chiral Oxazolidine Catalyst for Asymmetric Synthesis
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- Pd-Catalyzed Asymmetric Allylic Etherification Using Chiral Biphenol-Based Diphosphinite Ligands and Its Application for The Formal Total Synthesis of (−)-Galanthamine
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- Stereodivergent Strategy for Neurofuran Synthesis via Palladium-Catalyzed Asymmetric Allylic Cyclization: Total Synthesis of 7-epi-ST-Δ8-10-Neurofuran
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- Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylation of Nitroalkanes with Monosubstituted Allylic Substrates
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- Enantioselective Synthesis of 4-Heterosubstituted Cyclopentenones
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- Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters via Ir-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation and Applications in Sequential Pd Catalysis
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- Pd-Catalyzed Asymmetric Allylic Alkylation of Pyrazol-5-ones with Allylic Alcohols: The Role of the Chiral Phosphoric Acid in C–O Bond Cleavage and Stereocontrol
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- Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita–Baylis–Hillman Adducts: Exceptionally High Efficiency and New Mechanism
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- Palladium and Organocatalysis: An Excellent Recipe for Asymmetric Synthesis
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- Enantioselective Synthesis of 2,3-Disubstituted Indanones via Pd-Catalyzed Intramolecular Asymmetric Allylic Alkylation of Ketones
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- Desymmetrization of Bicyclo[3.n.1]-3-one Derivatives by Palladium-Catalyzed Asymmetric Allylic Alkylation
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- Pd-Catalyzed Asymmetric Allylic Alkylations of 3-Substituted Indoles Using Chiral P/Olefin Ligands
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- Palladium-Catalyzed Allylic Alkylation of Allyl Dienol Carbonates: Reactivity, Regioselectivity, Enantioselectivity, and Synthetic Applications
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- Carbon-Sulfur Bond Formation via Metal-Catalyzed Allylations of Sulfur Nucleophiles
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- Enantioselective total syntheses of cedrelin A and methylated paralycolin B using Pd-catalyzed asymmetric intramolecular Friedel–Crafts allylic alkylation of phenols
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- Novel O,N,N,O-tetradentate ligand from tartaric acid
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- Development of P∗-monodentate diamidophosphites with a C1-symmetric 1,2-diamine backbone: the effects of substituents in the 1,3,2-diazaphospholidine cycle on Pd-catalyzed asymmetric allylations
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- Camphane-based aminophosphine ligands for Pd-catalyzed asymmetric allylic alkylation
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- Application of pyranoside phosphite-pyridine ligands to enantioselective metal-catalyzed allylic substitutions and conjugate 1,4-additions
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- Mechanistic Investigation of Palladium-Catalyzed Allylic C–H Activation
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- Palladium-Catalyzed Enantioselective Allylic Alkylations through C-H Activation
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- Highly Enantioselective Synthesis of 3-Substituted Furanones by Palladium-Catalyzed Kinetic Resolution of Unsymmetrical Allyl Acetates
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- Diastereodivergent De-epimerization in Catalytic Asymmetric Allylic Alkylation
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- Palladium-Catalyzed Asymmetric Allylic Alkylation of Cyclic Dienol Carbonates: Efficient Route to Enantioenriched γ-Butenolides Bearing an All-Carbon α-Quaternary Stereogenic Center
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- Asymmetric catalysis based on tropos ligands
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- Enantioselective construction of sterically hindered tertiary α-aryl ketones: a catalytic asymmetric synthesis of isoflavanones
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- Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via π-allylic species
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- Mechanism of the Pd-catalyzed Decarboxylative Allylation of α-Imino Esters: Decarboxylation via Free Carboxylate Ion
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- Enantioselective andα-Regioselective Allylic Amination of Morita-Baylis-Hillman Acetates with Simple Aromatic Amines Catalyzed by Planarly Chiral Ligand/Palladium Catalyst
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- N1-Functionalized Indole-Phosphane Oxazoline (IndPHOX) Ligands in Asymmetric Allylic Substitution Reactions
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- Asymmetric Allylic Alkylation of Pyrroles and 4,7-Dihydroindoles with Alkene–Phosphine Ligands
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- Regio- and Enantioselective Palladium-Catalyzed Allylic Alkylation of Nitromethane with Monosubstituted Allyl Substrates: Synthesis of (R)-Rolipram and (R)-Baclofen
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- Palladacyclic Imidazoline–Naphthalene Complexes: Synthesis and Catalytic Performance in Pd(II)-Catalyzed Enantioselective Reactions of Allylic Trichloroacetimidates
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- Palladium(II)-Catalyzed Enantioselective Synthesis of 2-Vinyl Oxygen Heterocycles
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- Bis(perfluoroalkyl) Phosphino-Oxazoline: A Modular, Stable, Strongly π-Accepting Ligand for Asymmetric Catalysis
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- Total Synthesis of Aeruginosin 98B
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- Palladium-Catalyzed Diastereo- and Enantioselective Formal [3 + 2]-Cycloadditions of Substituted Vinylcyclopropanes
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- The Reaction Mechanism of the Enantioselective Tsuji Allylation: Inner-Sphere and Outer-Sphere Pathways, Internal Rearrangements, and Asymmetric C–C Bond Formation
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- Enantioselective Construction of Pyrrolidines by Palladium-Catalyzed Asymmetric [3 + 2] Cycloaddition of Trimethylenemethane with Imines
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- Exploiting the Modularity of Ion-Paired Chiral Ligands for Palladium-Catalyzed Enantioselective Allylation of Benzofuran-2(3H)-ones
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- Benzylic Phosphates as Electrophiles in the Palladium-Catalyzed Asymmetric Benzylation of Azlactones
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- Allylic Alkylations Catalyzed By Palladium-Bis(oxazoline) Complexes Derived From Heteroarylidene Malonate Derivatives
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- Ion-paired chiral ligands for asymmetric palladium catalysis
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- Enantioselective Synthesis of a Hydroxymethyl-cis-1,3-cyclopentenediol Building Block
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- Asymmetric Synthesis of Chiral 9,10-Dihydrophenanthrenes Using Pd-Catalyzed Asymmetric Intramolecular Friedel–Crafts Allylic Alkylation of Phenols
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- Palladium-Catalyzed Asymmetric Allylic Alkylation of Electron-Deficient Pyrroles with Meso Electrophiles
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- Pd- and Mo-Catalyzed Asymmetric Allylic Alkylation
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- Investigation of the Electronic Origin of Asymmetric Induction in Palladium-Catalyzed Allylic Substitutions with Phosphinooxazoline (PHOX) Ligands by Hammett and Swain–Lupton Analysis of the 13C NMR Chemical Shifts of the (π-Allyl)palladium Intermediates
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- Diastereomeric P,N-bidentate amidophosphites based on (S,S)- and (R,R)-hydrobenzoin as ligands in the Pd-catalyzed asymmetric allylation
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- ‘Evans Auxiliary' Based P-N Ligands for Pd-Catalyzed Asymmetric Allylic Alkylation Reactions
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- The synthesis of phosphine oxide-linked bis(oxazoline) ligands and their application in asymmetric allylic alkylation
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- BINOL-derived diphosphoramidites bearing unsymmetrical 1,2-diamine link and their application in asymmetric catalysis
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- Diversity oriented synthesis of indole-based peri-annulated compounds via allylic alkylation reactions
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- Palladium-Catalyzed Allylic Alkylation of Doubly Deprotonated Carboxylic Acids
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- Changing the Palladium Coordination to Phosphinoimidazolines with a Remote Triazole Substituent
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- Palladium-Catalyzed Allylic Alkylation of Carboxylic Acid Derivatives: N-Acyloxazolinones as Ester Enolate Equivalents
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- Catalytic Asymmetric Diastereodivergent Deracemization
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- Direct Asymmetric α-Allylation of Aldehydes with Simple Allylic Alcohols Enabled by the Concerted Action of Three Different Catalysts
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- The Catalytic Enantioselective Total Synthesis of (+)-Liphagal
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- Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes
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- Synthesis of Novel Bidentate P-Chiral Diaminophosphine Oxide Preligands: Application to Pd-Catalyzed Asymmetric Allylic Substitution Reactions
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- Efficient recycling of a chiral palladium catalytic system for asymmetric allylic substitutions in ionic liquid
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- Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions
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- P-Stereogenic Trifluoromethyl Derivatives of Josiphos: Synthesis, Coordination Properties, and Applications in Asymmetric Catalysis
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- Development of a Concise Synthesis of (−)-Oseltamivir (Tamiflu)
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- Total Syntheses of Cyanthiwigins B, F, and G
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- Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies
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- C1-Symmetric carbohydrate diphosphite ligands for asymmetric Pd-allylic alkylation reactions. Study of the key Pd-allyl intermediates
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- Synthesis, Coordination Properties and Application of New N,N-Ligands Based on Bornyl and Binaphthylazepine Chiral Backbones in Palladium-Catalyzed Allylic Substitution Reactions
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- Atropisomerism at C-N Bonds of Acyclic Amines: Synthesis and Application to Palladium-Catalyzed Asymmetric Allylic Alkylations
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- Naplephos through the Looking-Glass: Chiral Bis(phosphanylamides) Based on β-1,2-D-Glucodiamine and Their Application in Enantioselective Allylic Substitutions
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- Enantioselective Palladium-Catalyzed Allylic Substitution of Sodium Benzotriazolide
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- Total Synthesis of (+)-7,11-Helianane and (+)-5-Chloro-7,11-helianane through Stereoselective Aromatic Claisen Rearrangement
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- Design, Synthesis, and Applications of Potential Substitutes of t-Bu-Phosphinooxazoline in Pd-Catalyzed Asymmetric Transformations and Their Use for the Improvement of the Enantioselectivity in the Pd-Catalyzed Allylation Reaction of Fluorinated Allyl Enol Carbonates
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- Pd-Catalyzed Asymmetric Allylic Etherizations with Oximes by Chiral Alkene-Phosphine Ligands
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- Palladium-catalyzed asymmetric allylic substitutions in the presence of chiral phosphine-imine type ligands
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- Diastereocontrol in Asymmetric Allyl–Allyl Cross-Coupling: Stereocontrolled Reaction of Prochiral Allylboronates with Prochiral Allyl Chlorides
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- Exercising Regiocontrol in Palladium-Catalyzed Asymmetric Prenylations and Geranylation: Unifying Strategy toward Flustramines A and B
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- C–N Bond Cleavage of Allylic Amines via Hydrogen Bond Activation with Alcohol Solvents in Pd-Catalyzed Allylic Alkylation of Carbonyl Compounds
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- The Palladium Catalyzed Asymmetric Addition of Oxindoles and Allenes: An Atom-Economical Versatile Method for the Construction of Chiral Indole Alkaloids
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- Palladium-Catalyzed Asymmetric Allylic Alkylations of Polynitrogen-Containing Aromatic Heterocycles
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- Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams
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- Highly effective chiral phosphorus amidite–olefin ligands for palladium-catalyzed asymmetric allylic substitutions
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- Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork–Danheiser approach: preparation of mono-, bi-, and tricyclic systems
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- A Catalytic, Asymmetric Formal Synthesis of (+)-Hamigeran B
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- Asymmetric Decarboxylative Allylation of Oxindoles
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- Highly Enantioselective Pd-Catalyzed Allylic Alkylation of Indoles Using Sulfur-MOP Ligand
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- Acetoxy Meldrum’s Acid: A Versatile Acyl Anion Equivalent in the Pd-Catalyzed Asymmetric Allylic Alkylation
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- Pd-Catalyzed Asymmetric Allylic Alkylation of Indoles and Pyrroles by Chiral Alkene-Phosphine Ligands
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- Chiral Imidazoline–Phosphine Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions
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- Synthesis of a Chiral Key Intermediate of Neurokinin Antagonist SSR 240600 by Asymmetric Allylic Alkylation
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- Asymmetric Synthesis of 2-Substituted Hexahydroquinolin-4-ones Using a Pd-Catalyzed Asymmetric Allylic Amination and Intramolecular Mannich Reaction: Catalytic Asymmetric Synthesis of 2-epi-cis-195A
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- Enantioselective synthesis of 1-vinyltetrahydroisoquinolines via Pd-catalyzed intramolecular asymmetric allylic amination reactions
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- Malonate-type bis(oxazoline) ligands with sp2 hybridized bridge carbon: synthesis and application in Friedel–Crafts alkylation and allylic alkylation
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- Palladium-catalyzed asymmetric alkylation in the synthesis of cyclopentanoid and cycloheptanoid core structures bearing all-carbon quaternary stereocenters
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- Synthesis of phosphorylated sulfoximines and sulfinamides and their application as ligands in asymmetric metal catalysis
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- Mechanistic identification and improvement of a direct enantioconvergent transformation in copper-catalyzed asymmetric allylic alkylation
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- Synthesis of chiral P,N-ligands derived from quinoline and their application in asymmetric allylic alkylations
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- Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution
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- Asymmetric Catalytic Reactions Using P*-Mono-, P*,N- and P*,P*-Bidentate Diamidophosphites with BINOL Backbones and 1,3,2-Diazaphospholidine Moieties: Differences in the Enantioselectivity
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- Preparation of planar-chiral multidonor phosphanylferrocene carboxamides and their application as ligands for palladium-catalysed asymmetric allylic alkylation
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- Artificial Metalloenzymes through Cysteine-Selective Conjugation of Phosphines to Photoactive Yellow Protein
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- Dimethoxydibenzophosphepine: An Axially Chiral Monophosphane for Efficient Asymmetric Catalysis
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- Sterically Congested, “Roofed” β-Iminodisulfides as New Chiral Ligands for Palladium-Catalyzed, Asymmetric Allylic Alkylation
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- Recent developments on chiral P,S-type ligands and their applications in asymmetric catalysis
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- Phosphite-Containing Ligands for Asymmetric Catalysis
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- Cyclic 1,2-Diketones as Core Building Blocks: A Strategy for the Total Synthesis of (−)-Terpestacin
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- (S)-6-Bromo-BINOL-based phosphoramidite ligand with C1 symmetry for enantioselective hydrogenation and allylic substitution
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- Norbornene Bidentate Ligands: Coordination Chemistry and Enantioselective Catalytic Applications
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- Better Performance of Monodentate P-Stereogenic Phosphanes Compared to Bidentate Analogues in Pd-Catalyzed Asymmetric Allylic Alkylations
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- Synthesis and Application of Diphenyl Sulfide Linked Bis(imidazoline) Ligands: Dramatic Electronic Effect of Ligands on Catalytic Behavior
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- Synthesis and Post-Resolution Modification of New Axially Chiral Ligands for Asymmetric Catalysis
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- Imidate-Phosphanes as Highly Versatile N,P Ligands and Their Application in Palladium-Catalyzed Asymmetric Allylic Alkylation Reactions
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- When Organocatalysis Meets Transition-Metal Catalysis
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- Synthesis of chiral thiazoline ligands tethered to a sulfur function and first immobilization of a thiazoline-ligand
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- Phosphinite Thioethers Derived from Chiral Epoxides. ModularP,S-Ligands for Pd-Catalyzed Asymmetric Allylic Substitutions
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- Enantioselective Construction of Highly Substituted Pyrrolidines by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Ketimines
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- Palladium-Catalyzed Asymmetric Allylic Alkylation of 2-Acylimidazoles as Ester Enolate Equivalents
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- Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates
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- Catalytic Asymmetric Synthesis of Chiral Allylic Esters
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- Mechanism of the Cobalt Oxazoline Palladacycle (COP)-Catalyzed Asymmetric Synthesis of Allylic Esters
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- Palladium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Vinyl Aziridines with Nitrogen Heterocycles: Rapid Access to Biologically Active Pyrroles and Indoles
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- Palladium-Catalyzed Asymmetric Benzylation of 3-Aryl Oxindoles
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- A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres
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- Efficient palladium-catalyzed asymmetric allylic alkylation of ketones and aldehydes
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- A Concise Enantioselective Synthesis of (−)-Ranirestat
- (2010) Barry M. Trost et al. ORGANIC LETTERS
- Mechanistic Origin of the Stereodivergence in Decarboxylative Allylation
- (2010) Kalicharan Chattopadhyay et al. ORGANIC LETTERS
- Chiral Phosphaalkene−Oxazoline Ligands for the Palladium-Catalyzed Asymmetric Allylic Alkylation
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- Novel Method for Synthesizing Spiro[4.5]cyclohexadienones through a Pd-Catalyzed Intramolecularipso-Friedel−Crafts Allylic Alkylation of Phenols
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- Development of Chiral Terminal-Alkene−Phosphine Hybrid Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions
- (2010) Zhaoqun Liu et al. ORGANIC LETTERS
- Dinuclear Allylpalladium Complexes ofC2-Symmetric Pyrazolate-Bridged Bis(oxazoline) Ligands (pyrbox's): Structures, Dynamic Behavior, and Application in Asymmetric Allylic Alkylation
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- Isolation and Characterization of a Chiral η1-Allyl Palladium DIPPAM Complex: Application to the Enantioselective Pd-Catalyzed Allylic Alkylation
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- Synthesis and Characterization of New, Chiral P−N Ligands and Their Use in Asymmetric Allylic Alkylation
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- The first pincer-type phosphodiamidite ligand containing chiral phosphorus atoms
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- Palladium-catalyzed allylic substitution assisted by 1,3,2-diazaphospholidine derivatives of (R,R)-N-naphthyltartarimide
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- High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates
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- A general enantioselective route to the chamigrene natural product family
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- Diamidophosphites with isomeric carborane fragments: a comparison of catalytic activity in asymmetric Pd-catalyzed allylic substitution reactions
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- Palladium-catalyzed intramolecular allylic alkylation of α-sulfinyl carbanions: a new asymmetric route to enantiopure γ-lactams
- (2010) Sophie Vogel et al. TETRAHEDRON LETTERS
- Pd-catalyzed asymmetric reactions using resorcinol- and hydroquinone-based P∗,P∗-bidentate diamidophosphites
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- Rational tuning of the rigidity of a ligand scaffold: synthesis of diphenylsulfide-linked bis(oxazoline) ligands and their application in asymmetric allylic alkylation
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- Sulfoxides derived from Cinchona alkaloids—chiral ligands in palladium-catalyzed asymmetric allylic alkylation
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- Synthesis of new fluorous modular chiral ligand derivatives from amino alcohols and application in enantioselective carbon–carbon bond-forming alkylation reactions
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- A modular approach to a new class of phosphinohydrazones and their use in asymmetric allylic alkylation reactions
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- Novel C2-symmetric bisoxazolines with a chiral trans-(2R,3R)-diphenylcyclopropane backbone: preparation and application in several enantioselective catalytic reactions
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- Palladium catalyzed asymmetric sulfonylation mediated chiral β-hydroxy- and β-(o-diphenylphosphino)benzoyloxy (o-diphenyl phosphino)benzamides
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- Palladium-catalyzed regio- and enantio-selective allylic substitution reaction of monosubstituted allyl substrates with benzyl alcohols
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- Chiral, non-racemic diols, and α-amino acid-derived β-amino alcohols as templates for chiral catalysts in the Tsuji–Trost reaction
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- Naplephos: a modular library of chiral phosphines based on d-glucose for highly enantioselective asymmetric catalysis
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- Preparation of indole-phosphine oxazoline (IndPHOX) ligands and their application in allylic alkylation
- (2010) Yu Wang et al. TETRAHEDRON-ASYMMETRY
- Preparation of quarternary ammonium salt-tagged ferrocenylphosphine-imine ligands and their application to palladium-catalyzed asymmetric allylic substitution
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- Synthesis of novel carbohydrate-based iminophosphinite ligands in Pd-catalyzed asymmetric allylic alkylations
- (2010) Chao Shen et al. TETRAHEDRON-ASYMMETRY
- Asymmetric allylic substitutions on symmetrical and non-symmetrical substrates using [5]ferrocenophane ligands
- (2010) Radovan Šebesta et al. TETRAHEDRON-ASYMMETRY
- Highly modular P-OP ligands in asymmetric allylic substitution
- (2010) Armen Panossian et al. TETRAHEDRON-ASYMMETRY
- N-Aryl indole-derived C–N bond axially chiral phosphine ligands: synthesis and application in palladium-catalyzed asymmetric allylic alkylation
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- Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation
- (2010) Barry M. Trost et al. Chemical Science
- Biaryl Phosphites: New Efficient Adaptative Ligands for Pd-Catalyzed Asymmetric Allylic Substitution Reactions
- (2009) Montserrat Diéguez et al. ACCOUNTS OF CHEMICAL RESEARCH
- Pyranoside Phosphite-Oxazoline Ligand Library: Highly Efficient Modular P,N Ligands for Palladium-Catalyzed Allylic Substitution Reactions. A Study of the Key Palladium Allyl Intermediates
- (2009) Yvette Mata et al. ADVANCED SYNTHESIS & CATALYSIS
- Effective Chiral Ferrocenyl Phosphine-Thioether Ligands in Enantioselective Palladium-Catalyzed Allylic Alkylations
- (2009) Hong Yee Cheung et al. ADVANCED SYNTHESIS & CATALYSIS
- Palladium-Catalyzed Asymmetric Allylic Alkylation of 2,3-Allenyl Acetates Using a Chiral Diaminophosphine Oxide
- (2009) Tetsuhiro Nemoto et al. ADVANCED SYNTHESIS & CATALYSIS
- Modular Furanoside Phosphite-Phosphoroamidites, a Readily Available Ligand Library for Asymmetric Palladium-Catalyzed Allylic Substitution Reactions. Origin of Enantioselectivity
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- Determination of the Conformation of the Key Intermediate in an Enantioselective Palladium-Catalyzed Allylic Substitution from Residual Dipolar Couplings
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- Construction of Two Vicinal Quaternary Carbons by Asymmetric Allylic Alkylation: Total Synthesis of Hyperolactone C and (−)-Biyouyanagin A
- (2009) Chao Du et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Palladium-Catalyzed Substitution of Allylic Fluorides
- (2009) Amaruka Hazari et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Allylic Alkylation Reactions of Ketones
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- Mass spectrometric screening of chiral catalysts and catalyst mixtures
- (2009) Constanze Annelie Müller et al. CHEMICAL COMMUNICATIONS
- Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions
- (2009) Luca Pignataro et al. CHEMICAL COMMUNICATIONS
- Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity
- (2009) Ramesh Giri et al. CHEMICAL SOCIETY REVIEWS
- A Stereodivergent Strategy to Both Product Enantiomers from the Same Enantiomer of a Stereoinducing Catalyst: Agelastatin A
- (2009) Barry M. Trost et al. CHEMISTRY-A EUROPEAN JOURNAL
- Toward Efficient Palladium-Catalyzed Allylic CH Alkylation
- (2009) Thomas Jensen et al. CHEMISTRY-A EUROPEAN JOURNAL
- A New Class of Modular P,N-Ligand Library for Asymmetric Pd-Catalyzed Allylic Substitution Reactions: A Study of the Key PdâÏ-Allyl Intermediates
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- A Comparison of (R,R)-Me-DUPHOS and (R,R)-DUPHOS-iPr Ligands in the Pd0-Catalysed Asymmetric Allylic Alkylation Reaction: Stereochemical and Kinetic Considerations
- (2009) Vanda Raquel Marinho et al. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Supported Chiral Monodentate Ligands in Rhodium-Catalysed Asymmetric Hydrogenation and Palladium-Catalysed Asymmetric Allylic Alkylation
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- Synthesis of Novel Ferrocenyl-Based P,S Ligands (ThioClickFerrophos) and Their Use in Pd-Catalyzed Asymmetric Allylic Substitutions
- (2009) Minoru Kato et al. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Synthesis of Chiral (Sulfinyl)furyloxazoline Ligands and Its Application to Enantioselective Palladium-Catalyzed Allylic Alkylation
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- β-Amino Alcohol Derived β-Hydroxy- and β-(o-Diphenylphosphino)benzoyloxy(o-diphenylphosphino)benzamides: An Ester−Amide Ligand Structural Model for the Palladium-Catalyzed Allylic Alkylation Reaction
- (2009) Geetanjali S. Mahadik et al. JOURNAL OF ORGANIC CHEMISTRY
- Atropoisomerism in Phosphepines and Azepines
- (2009) Ester Fjellander et al. JOURNAL OF ORGANIC CHEMISTRY
- Enantioselective Approach to Securinega Alkaloids. Total Synthesis of Securinine and (−)-Norsecurinine
- (2009) David González-Gálvez et al. JOURNAL OF ORGANIC CHEMISTRY
- Influence of structural changes in ferrocene phosphane aminophosphane ligands on their catalytic activity
- (2009) Radovan Šebesta et al. JOURNAL OF ORGANOMETALLIC CHEMISTRY
- The use of a new carboranylamidophosphite ligand in the asymmetric Pd-catalysed allylic alkylation in organic solvents and supercritical carbon dioxide
- (2009) Sergey E. Lyubimov et al. JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Structure-Based Rationale for Selectivity in the Asymmetric Allylic Alkylation of Cycloalkenyl Esters Employing the Trost ‘Standard Ligand’ (TSL): Isolation, Analysis and Alkylation of the Monomeric form of the Cationic η3-Cyclohexenyl Complex [(η3-c-C6H9)Pd(TSL)]+
- (2009) Craig P. Butts et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Iridium Phosphite−Oxazoline Catalysts for the Highly Enantioselective Hydrogenation of Terminal Alkenes
- (2009) Javier Mazuela et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Kinetic Resolution of 2,3-Dihydro-2-substituted 4-Quinolones by Palladium-Catalyzed Asymmetric Allylic Alkylation
- (2009) Bai-Lin Lei et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Asymmetric Synthesis of Diamine Derivatives via Sequential Palladium and Rhodium Catalysis
- (2009) Barry M. Trost et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates
- (2009) Barry M. Trost et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Benzylic Allylation of 2-Substituted Pyridines
- (2009) Barry M. Trost et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Synthetic efforts toward cyathane diterpenoid natural products
- (2009) John A. Enquist et al. NATURAL PRODUCT REPORTS
- Use of 5,5-(Dimethyl)-i-Pr-PHOX as a Practical Equivalent tot-Bu-PHOX in Asymmetric Catalysis
- (2009) Étienne Bélanger et al. ORGANIC LETTERS
- Kinetic Resolution of Indolines by Pd-Catalyzed Asymmetric Allylic Amination
- (2009) Xue Long Hou et al. ORGANIC LETTERS
- Novel, Efficient Alkene-Phosphinite Hybrid Ligand Based ond-Glucose
- (2009) Tobias Minuth et al. ORGANIC LETTERS
- Tandem C−C Bond-Forming Processes: Interception of the Pd-Catalyzed Decarboxylative Allylation of Allyl Diphenylglycinate Imines with Activated Olefins
- (2009) Andrew A. Yeagley et al. ORGANIC LETTERS
- Enantioselective Palladium(II)-Catalyzed Formal [3,3]-Sigmatropic Rearrangement of 2-Allyloxypyridines and Related Heterocycles†
- (2009) Alessandro Rodrigues et al. ORGANIC LETTERS
- Coordination Chemistry and Catalytic Application of Bidentate Phosphaferrocene−Pyrazole and −Imidazole Based P,N-Ligands
- (2009) Holger Willms et al. ORGANOMETALLICS
- INDOLPhosphole and INDOLPhos Palladium−Allyl Complexes in Asymmetric Allylic Alkylations
- (2009) Jeroen Wassenaar et al. ORGANOMETALLICS
- Enantioselective γ-Lactam Synthesis via Palladium-Catalyzed Intramolecular Asymmetric Allylic Alkylation
- (2009) Guillaume Prestat et al. SYNLETT
- Development of a New Chiral Spiro Oxazolinylpyridine Ligand (Spymox) for Asymmetric Catalysis
- (2009) Kazutaka Shibatomi et al. SYNLETT
- Application of Walphos Ligand in the Pd(0)-Catalyzed Asymmetric Allylic Alkylation Reaction
- (2009) Vanda R. Marinho et al. SYNTHETIC COMMUNICATIONS
- Phosphine-oxazoline ligands with an axial-unfixed biphenyl backbone: the effects of the substituent at oxazoline ring and P phenyl ring on Pd-catalyzed asymmetric allylic alkylation
- (2009) Fengtao Tian et al. TETRAHEDRON
- Synthesis of highly modular bis(oxazoline) ligands by Suzuki cross-coupling and evaluation as catalytic ligands
- (2009) Xavier Cattoën et al. TETRAHEDRON
- Origin of enantioselectivity with heterobidentate sulfide-tertiary amine (sp3) ligands in palladium-catalyzed allylic substitution
- (2009) Jun-Long Niu et al. TETRAHEDRON
- Stereoselective synthesis of substituted 1,2-ethylenediaziridines and their use as ligands in palladium-catalyzed asymmetric allylic alkylation
- (2009) Andrea Gualandi et al. TETRAHEDRON
- Kinetic resolution of allylic esters in palladium-catalyzed asymmetric allylic alkylations using C–N bond axially chiral aminophosphine ligands
- (2009) Takashi Mino et al. TETRAHEDRON-ASYMMETRY
- New chiral diphosphites derived from substituted 9,10-dihydroanthracene. Applications in asymmetric catalytic processes
- (2009) Delphine Sanhes et al. TETRAHEDRON-ASYMMETRY
- Chiral amine–imine ligands based on trans-2,5-disubstituted pyrrolidines and their application in the palladium-catalyzed allylic alkylation
- (2009) Hongfeng Chen et al. TETRAHEDRON-ASYMMETRY
- P∗,P∗-Bidentate diastereoisomeric bisdiamidophosphites based on N-benzyltartarimide and their applications in asymmetric catalytic processes
- (2009) Konstantin N. Gavrilov et al. TETRAHEDRON-ASYMMETRY
- Asymmetric hydrogenation and allylic substitution reaction with novel chiral pinene-derived N,P-ligands
- (2009) Xiangyan Meng et al. TETRAHEDRON-ASYMMETRY
- Palladium-catalyzed asymmetric allylic nucleophilic substitution reactions using chiral tert-butanesulfinylphosphine ligands
- (2009) Junmin Chen et al. TETRAHEDRON-ASYMMETRY
- β-Hydroxy and β-(o-diphosphino)benzoyloxy(o-diphosphino) benzamides as ligands for asymmetric allylic alkylation
- (2009) Geetanjali S. Mahadik et al. TETRAHEDRON-ASYMMETRY
- Palladium-Catalyzed Diastereoselective and Enantioselective Allylic Alkylations of Ketone Enolates
- (2008) Manfred Braun et al. ADVANCED SYNTHESIS & CATALYSIS
- Artificial Metalloenzymes for Asymmetric Allylic Alkylation on the Basis of the Biotin–Avidin Technology
- (2008) Julien Pierron et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Palladium–(S,pR)-FerroNPS-Catalyzed Asymmetric Allylic Etherification: Electronic Effect of Nonconjugated Substituents on Benzylic Alcohols on Enantioselectivity
- (2008) Fuk Loi Lam et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A Concise Synthesis of (−)-Oseltamivir
- (2008) Barry M. Trost et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Mass Spectrometric Screening of Chiral Catalysts by Monitoring the Back Reaction of Quasienantiomeric Products: Palladium-Catalyzed Allylic Substitution
- (2008) Constanze A. Müller et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Palladium-Catalyzed Intermolecular Aerobic Oxidative Amination of Terminal Alkenes: Efficient Synthesis of Linear Allylamine Derivatives
- (2008) Guosheng Liu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A Chiral Lewis Acid Strategy for Enantioselective Allylic CH Oxidation
- (2008) Dustin J. Covell et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Heterogeneous Asymmetric Catalysis in Water with Amphiphilic Polymer-Supported Homochiral Palladium Complexes
- (2008) Yasuhiro Uozumi BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
- Exploring the utility of a new chiral phosphoramidite P,N-ligand derived from (R)-BINOL and 7-azaindole in asymmetric catalysis
- (2008) Dominik Wechsler et al. CANADIAN JOURNAL OF CHEMISTRY
- Novel pyridine-phosphite ligands for Pd-catalyzed asymmetric allylic substitution reaction
- (2008) X MENG et al. CATALYSIS COMMUNICATIONS
- Transition Metal-Catalyzed Asymmetric Reactions Using P-Chirogenic Diaminophosphine Oxides: DIAPHOXs
- (2008) Tetsuhiro Nemoto CHEMICAL & PHARMACEUTICAL BULLETIN
- An outstanding palladium system containing a C2-symmetrical phosphite ligand for enantioselective allylic substitution processes
- (2008) Angelica Balanta Castillo et al. CHEMICAL COMMUNICATIONS
- Unexpected effect of the fluorine atom on the optimal ligand-to-palladium ratio in the enantioselective Pd-catalyzed allylation reaction of fluorinated enol carbonates
- (2008) Étienne Bélanger et al. CHEMICAL COMMUNICATIONS
- Biaryl phosphite-oxazolines from hydroxyl aminoacid derivatives: highly efficient modular ligands for Ir-catalyzed hydrogenation of alkenes
- (2008) Montserrat Diéguez et al. CHEMICAL COMMUNICATIONS
- Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
- (2008) Syuzanna R. Harutyunyan et al. CHEMICAL REVIEWS
- Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions
- (2008) A. Alexakis et al. CHEMICAL REVIEWS
- Modular Phosphite–Oxazoline/Oxazine Ligand Library for Asymmetric Pd-Catalyzed Allylic Substitution Reactions: Scope and Limitations—Origin of Enantioselectivity
- (2008) Montserrat Diéguez et al. CHEMISTRY-A EUROPEAN JOURNAL
- Synthesis of novel chiral phosphine-triazine ligand derived from α-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation
- (2008) Jia Di Huang et al. CHINESE CHEMICAL LETTERS
- Synthesis, Resolution, and Application of Cyclobutyl- and Adamantyl-Quinazolinap Ligands
- (2008) Tomasz Fekner et al. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- [3]Ferrocenophane Ligands with an Inserted Methylene Group
- (2008) Radovan Šebesta et al. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- A new, efficient heterogeneous Pd catalyst for enantioselective allylic substitution
- (2008) S REIMANN et al. JOURNAL OF CATALYSIS
- The Many Roles for Fluorine in Medicinal Chemistry
- (2008) William K. Hagmann JOURNAL OF MEDICINAL CHEMISTRY
- [2.2]Paracyclophane-Derived Chiral P,N-Ligands: Design, Synthesis, and Application in Palladium-Catalyzed Asymmetric Allylic Alkylation
- (2008) Biao Jiang et al. JOURNAL OF ORGANIC CHEMISTRY
- (N,N) vs. (N,S) chelation of palladium in asymmetric allylic substitution using bis(thiazoline) ligands: A theoretical and experimental study
- (2008) Alexander Betz et al. JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Self-Adaptable Catalysts: Substrate-Dependent Ligand Configuration
- (2008) Raivis Zalubovskis et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Strategy for Employing Unstabilized Nucleophiles in Palladium-Catalyzed Asymmetric Allylic Alkylations
- (2008) Barry M. Trost et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Asymmetric Cycloadditions of Palladium-Polarized Aza-o-xylylenes
- (2008) Chao Wang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalytic Asymmetric Allylic and Homoallylic Diamination of Terminal Olefins via Formal C−H Activation
- (2008) Haifeng Du et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Intra/Intermolecular Direct Allylic Alkylation via Pd(II)-Catalyzed Allylic C−H Activation
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- Catalytic Intermolecular Allylic CH Alkylation
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