Palladium-catalyzed tandem allylic substitution/cyclization and cascade hydrosilylated reduction: the influence of reaction parameters and hydrosilanes on the stereoselectivity

Iridium-Catalyzed Intramolecular Asymmetric Allylic Alkylation of Hydroxyquinolines: Simultaneous Weakening of the Aromaticity of Two Consecutive Aromatic Rings

(2018) Ze-Peng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and application of a new hexamethyl-1,1′-spirobiindane-based chiral bisphosphine (HMSI-PHOS) ligand in asymmetric allylic alkylation

(2018) Shirui Chang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Three-Component Tandem Process: One-Pot Assembly of Quinazolines

(2018) Kun Hu et al.   ORGANIC LETTERS

New phosphine-imine and phosphine-amine ligands derived from d -gluco-, d -galacto- and d -allosamine in Pd-catalysed asymmetric allylic alkylation

(2018) Izabela Szulc et al.   TETRAHEDRON

Pd-Catalyzed Asymmetric Cyclopropanation Reaction of Acyclic Amides with Allyl and Polyenyl Carbonates. Experimental and Computational Studies for the Origin of Cyclopropane Formation

(2018) Jian-Qiang Huang et al.   ACS Catalysis

Indium-mediated Palladium-catalyzed Allylic Alkylation of Isatins with Alkynes

(2018) Zijun Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Efficient synthesis of isoquinolines in water by a Pd-catalyzed tandem reaction of functionalized alkylnitriles with arylboronic acids

(2017) Kun Hu et al.   GREEN CHEMISTRY

Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates

(2017) Pavel Starkov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Palladium and Isothiourea Relay Catalysis: Enantioselective Synthesis of α-Amino Acid Derivatives via Allylic Amination and [2,3]-Sigmatropic Rearrangement

(2017) Stéphanie S. M. Spoehrle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Construction of Tertiary C–O Bond via Allylic Substitution of Vinylethylene Carbonates with Water and Alcohols

(2017) Ajmal Khan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Chiral α,β-Unsaturated γ-Amino Esters via Pd-Catalyzed Asymmetric Allylic Amination

(2017) Chao Xia et al.   ORGANIC LETTERS

Palladium-Catalyzed Asymmetric Allylic Alkylation of Alkyl-Substituted Allyl Reagents with Acyclic Amides

(2017) Yang-Jie Jiang et al.   ORGANIC LETTERS

Transfer of Chirality in the Rhodium-Catalyzed Chemoselective and Regioselective Allylic Alkylation of Hydroxyarenes with Vinyl Aziridines

(2017) Tao-Yan Lin et al.   ORGANIC LETTERS

Nickel-Mediated Asymmetric Allylic Alkylation between Nitroallylic Acetates and Acyl Imidazoles

(2017) Jie Wang et al.   ORGANIC LETTERS

Enantioselective Pd-Catalyzed Decarboxylative Allylic Alkylation of Thiopyranones. Access to Acyclic, Stereogenic α-Quaternary Ketones

(2017) Eric J. Alexy et al.   ORGANIC LETTERS

Enantioselective Iridium-Catalyzed Allylic Cyclizations

(2017) Michael A. Schafroth et al.   ORGANIC LETTERS

Catalytic Enantioselective Vinylogous Allylic Alkylation of Coumarins

(2017) Satavisha Kayal et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Allenylation of Sulfonylimines and Application to the Stereospecific Allylic Allenylation

(2016) Joshua D. Sieber et al.   ADVANCED SYNTHESIS & CATALYSIS

Iron-Based Imidazolium Salts as Versatile Catalysts for the Synthesis of Quinolines and 2- and 4-Allylanilines by Allylic Substitution of Alcohols

(2016) Paz Trillo et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Tricyclic Isoquinoline Derivatives via Palladium- Catalyzed Tandem Reactions of 2,7-Alkadiynylic Carbonates with 2,3-Allenyl Sulfamides

(2016) Xin Huang et al.   ADVANCED SYNTHESIS & CATALYSIS

Tandem Addition/Cyclization for Access to Isoquinolines and Isoquinolones via Catalytic Carbopalladation of Nitriles

(2016) Linjun Qi et al.   ORGANIC LETTERS

Aromatic Amide-Derived Non-Biaryl Atropisomers as Highly Efficient Ligands in Silver-Catalyzed Asymmetric Cycloaddition Reactions

(2015) Xing-Feng Bai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Theoretical and Experimental Optimization of a New Amino Phosphite Ligand Library for Asymmetric Palladium-Catalyzed Allylic Substitution

(2015) Marc Magre et al.   ChemCatChem

Generating Active “L-Pd(0)” via Neutral or Cationic π-Allylpalladium Complexes Featuring Biaryl/Bipyrazolylphosphines: Synthetic, Mechanistic, and Structure–Activity Studies in Challenging Cross-Coupling Reactions

(2015) A. J. DeAngelis et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective conjugate addition of cyanide to chalcones catalyzed by a magnesium-Py-BINMOL complex

(2015) Cheng Dong et al.   Catalysis Science & Technology

Modular Synthesis of Ar-BINMOL-Phos for Catalytic Asymmetric Alkynylation of Aromatic Aldehydes with Unexpected Reversal of Enantioselectivity

(2014) Tao Song et al.   ADVANCED SYNTHESIS & CATALYSIS

Multistereogenic Phosphine Ligand-promoted Palladium-Catalyzed Allylic Alkylation of Cyanoesters

(2014) Wen-Hui Deng et al.   ChemCatChem

Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

(2014) Bin Feng et al.   CHEMICAL COMMUNICATIONS

Enantioselective Copper-Catalyzed Azide-Alkyne Click Cycloaddition to Desymmetrization of Maleimide-Based Bis(alkynes)

(2014) Tao Song et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Versatile Pd–Thioether–Phosphite Catalytic Systems for Asymmetric Allylic Alkylation, Amination, and Etherification Reactions

(2014) Mercè Coll et al.   ORGANIC LETTERS

Mechanistic Investigations of Palladium-Catalyzed Allylic Fluorination

(2014) Matthew H. Katcher et al.   ORGANOMETALLICS

P,N ligands in asymmetric catalysis

(2013) Michael P. Carroll et al.   CHEMICAL SOCIETY REVIEWS

A New Modular Phosphite-Pyridine Ligand Library for Asymmetric Pd-Catalyzed Allylic Substitution Reactions: A Study of the Key Pd-π-Allyl Intermediates

(2013) Javier Mazuela et al.   CHEMISTRY-A EUROPEAN JOURNAL

Development of a Novel Multifunctional N,P Ligand for Highly Enantioselective Palladium-Catalyzed Asymmetric Allylic Etherification of Alcohols and Silanols

(2013) Fei Ye et al.   CHEMISTRY-A EUROPEAN JOURNAL

Modulation of Multifunctional N,O,P Ligands for Enantioselective Copper-Catalyzed Conjugate Addition of Diethylzinc and Trapping of the Zinc Enolate

(2013) Fei Ye et al.   Chemistry-An Asian Journal

New silver(I)–monophosphine complex derived from chiral Ar-BINMOL: synthesis and catalytic activity in asymmetric vinylogous Mannich reaction

(2013) Long-Sheng Zheng et al.   TETRAHEDRON

Aromatic-Amide-Derived Olefins as a Springboard: Isomerization-Initiated Palladium-Catalyzed Hydrogenation of Olefins and Reductive Decarbonylation of Acyl Chlorides with Hydrosilane

(2012) Xing-Feng Bai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium(II)-Catalyzed Enantioselective Synthesis of 2-Vinyl Oxygen Heterocycles

(2012) Jeffrey S. Cannon et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Allylic Etherification: Selective Coupling of Two Unactivated Alcohols

(2011) Markus Roggen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine−Phosphinite and Phosphine−Phosphite Ligands: Preparation and Applications in Asymmetric Catalysis

(2011) Héctor Fernández-Pérez et al.   CHEMICAL REVIEWS

Neighboring Lithium-Assisted [1,2]-Wittig Rearrangement: Practical Access to Diarylmethanol-Based 1,4-Diols and Optically Active BINOL Derivatives with Axial and sp3-Central Chirality

(2011) Guang Gao  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Antiangiogenic Activity of New Silybin Galloyl Esters

(2011) Radek Gažák et al.   JOURNAL OF MEDICINAL CHEMISTRY

Recent Advances in the Application of Chiral Phosphine Ligands in Pd-Catalysed Asymmetric Allylic Alkylation

(2011) Itzel Guerrero Rios et al.   MOLECULES

Ionic-salt-tagged ferrocenyl diphosphine–imine ligands and their application to palladium-catalyzed asymmetric allylic etherification

(2011) Li Dai et al.   TETRAHEDRON-ASYMMETRY

(Cyclopentadienyl)ruthenium-Catalyzed Regio- and Enantioselective Decarboxylative Allylic Etherification of Allyl Aryl and Alkyl Carbonates

(2010) Martina Austeri et al.   ADVANCED SYNTHESIS & CATALYSIS

Phosphinite Thioethers Derived from Chiral Epoxides. ModularP,S-Ligands for Pd-Catalyzed Asymmetric Allylic Substitutions

(2010) Xisco Caldentey et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of Chiral Terminal-Alkene−Phosphine Hybrid Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions

(2010) Zhaoqun Liu et al.   ORGANIC LETTERS

Pd-catalyzed asymmetric reactions using resorcinol- and hydroquinone-based P∗,P∗-bidentate diamidophosphites

(2010) Konstantin N. Gavrilov et al.   TETRAHEDRON LETTERS

Palladium-catalyzed regio- and enantio-selective allylic substitution reaction of monosubstituted allyl substrates with benzyl alcohols

(2010) Ping Fang et al.   TETRAHEDRON-ASYMMETRY

Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation

(2010) Barry M. Trost et al.   Chemical Science

Synthesis of Novel Ferrocenyl-Based P,S Ligands (ThioClickFerrophos) and Their Use in Pd-Catalyzed Asymmetric Allylic Substitutions

(2009) Minoru Kato et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Structure-Based Rationale for Selectivity in the Asymmetric Allylic Alkylation of Cycloalkenyl Esters Employing the Trost ‘Standard Ligand’ (TSL): Isolation, Analysis and Alkylation of the Monomeric form of the Cationic η3-Cyclohexenyl Complex [(η3-c-C6H9)Pd(TSL)]+

(2009) Craig P. Butts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium–(S,pR)-FerroNPS-Catalyzed Asymmetric Allylic Etherification: Electronic Effect of Nonconjugated Substituents on Benzylic Alcohols on Enantioselectivity

(2008) Fuk Loi Lam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Counterintuitive Kinetics in Tsuji-Trost Allylation: Ion-Pair Partitioning and Implications for Asymmetric Catalysis

(2008) Louise A. Evans et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION